PMID- 33374381
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20210111
IS  - 1996-1944 (Print)
IS  - 1996-1944 (Electronic)
IS  - 1996-1944 (Linking)
VI  - 14
IP  - 1
DP  - 2020 Dec 24
TI  - Biodiesel Production on Monometallic Pt, Pd, Ru, and Ag Catalysts Supported on 
      Natural Zeolite.
LID - 10.3390/ma14010048 [doi]
LID - 48
AB  - Biodiesel production from rapeseed oil and methanol via transesterification 
      reaction facilitated by various monometallic catalyst supported on natural 
      zeolite (NZ) was investigated. The physicochemical characteristics of the 
      synthesized catalysts were studied by X-ray diffraction (XRD), 
      Brunauer-Emmett-Teller method (BET), temperature-programmed-reduction in hydrogen 
      (H(2)-TPR), temperature-programmed-desorption of ammonia (NH(3)-TPD), Scanning 
      Electron Microscope equipped with EDX detector (SEM-EDS), and X-ray photoelectron 
      spectroscopy (XPS) methods. The highest activity and methyl ester yields were 
      obtained for the Pt/NZ catalyst. This catalyst showed the highest triglycerides 
      conversion of 98.9% and fatty acids methyl esters yields of 94.6%. The activity 
      results also confirmed the high activity of the carrier material (NZ) itself in 
      the investigated reaction. Support material exhibited 90.5% of TG conversion and 
      the Fatty Acid Methyl Esters yield (FAME) of 67.2%. Introduction of noble metals 
      improves the TG conversion and FAME yield values. Increasing of the metal loading 
      from 0.5 to 2 wt.% improves the reactivity properties of the investigated 
      catalysts.
FAU - Mierczynski, Pawel
AU  - Mierczynski P
AUID- ORCID: 0000-0001-8359-2029
AD  - Institute of General and Ecological Chemistry, Faculty of Chemistry, Lodz 
      University of Technology, Zeromskiego 116, 90-924 Lodz, Poland.
FAU - Mosinska, Magdalena
AU  - Mosinska M
AD  - Institute of General and Ecological Chemistry, Faculty of Chemistry, Lodz 
      University of Technology, Zeromskiego 116, 90-924 Lodz, Poland.
FAU - Szkudlarek, Lukasz
AU  - Szkudlarek L
AUID- ORCID: 0000-0003-1847-9585
AD  - Institute of General and Ecological Chemistry, Faculty of Chemistry, Lodz 
      University of Technology, Zeromskiego 116, 90-924 Lodz, Poland.
FAU - Chalupka, Karolina
AU  - Chalupka K
AUID- ORCID: 0000-0002-4353-8156
AD  - Institute of General and Ecological Chemistry, Faculty of Chemistry, Lodz 
      University of Technology, Zeromskiego 116, 90-924 Lodz, Poland.
FAU - Tatsuzawa, Misa
AU  - Tatsuzawa M
AD  - Department of Chemistry, Graduate School of Science, Tokyo University of Science, 
      Tokyo 162-8601, Japan.
FAU - Al Maskari, Marwa
AU  - Al Maskari M
AD  - Petroleum and Chemical Engineering Department, Sultan Qaboos University, P.O. Box 
      33, Muscat P.C 123, Oman.
FAU - Maniukiewicz, Waldemar
AU  - Maniukiewicz W
AUID- ORCID: 0000-0001-6094-0748
AD  - Institute of General and Ecological Chemistry, Faculty of Chemistry, Lodz 
      University of Technology, Zeromskiego 116, 90-924 Lodz, Poland.
FAU - Wahono, Satriyo K
AU  - Wahono SK
AUID- ORCID: 0000-0001-8195-8066
AD  - Research Division for Natural Product Technology, Indonesian Institutes of 
      Sciences, Jl. Jogja-Wonosari km 32, Gading, Playen, Gunungkidul, Yogyakarta 
      55861, Indonesia.
FAU - Vasilev, Krasimir
AU  - Vasilev K
AD  - Academic Unit of STEM, University of South Australia, Mawson Lakes, Adelaide, SA 
      5095, Australia.
FAU - Szynkowska-Jozwik, Malgorzata I
AU  - Szynkowska-Jozwik MI
AUID- ORCID: 0000-0003-1959-3849
AD  - Institute of General and Ecological Chemistry, Faculty of Chemistry, Lodz 
      University of Technology, Zeromskiego 116, 90-924 Lodz, Poland.
LA  - eng
GR  - This work was also partially funded by the National Science Centre within the 
      ''OPUS'' Programme, Poland (Grant no. 2018/29/B/ST8/01317)/Narodowe Centrum 
      Nauki/
GR  - Pawel Mierczynski thanks the Lodz University of Technology for a scholarship 
      (Wlasny Fundusz Stypendialny PL programme No. RNN/WFS/1/2019)/Politechnika 
      Lodzka/
PT  - Journal Article
DEP - 20201224
PL  - Switzerland
TA  - Materials (Basel)
JT  - Materials (Basel, Switzerland)
JID - 101555929
PMC - PMC7796065
OTO - NOTNLM
OT  - FAME
OT  - biodiesel production
OT  - monometallic catalyst
OT  - zeolite
COIS- The authors declare no conflict of interest.
EDAT- 2020/12/31 06:00
MHDA- 2020/12/31 06:01
PMCR- 2020/12/24
CRDT- 2020/12/30 01:01
PHST- 2020/11/13 00:00 [received]
PHST- 2020/12/15 00:00 [revised]
PHST- 2020/12/18 00:00 [accepted]
PHST- 2020/12/30 01:01 [entrez]
PHST- 2020/12/31 06:00 [pubmed]
PHST- 2020/12/31 06:01 [medline]
PHST- 2020/12/24 00:00 [pmc-release]
AID - ma14010048 [pii]
AID - materials-14-00048 [pii]
AID - 10.3390/ma14010048 [doi]
PST - epublish
SO  - Materials (Basel). 2020 Dec 24;14(1):48. doi: 10.3390/ma14010048.