PMID- 33379121
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20210108
LR  - 20210108
IS  - 1873-3573 (Electronic)
IS  - 0039-9140 (Linking)
VI  - 224
DP  - 2021 Mar 1
TI  - First study of passive sampling to monitor short-chain chlorinated paraffins in 
      water: Comparing capabilities of Chemcatcher(R) and silicone rubber samplers.
PG  - 121920
LID - S0039-9140(20)31211-X [pii]
LID - 10.1016/j.talanta.2020.121920 [doi]
AB  - Short-chain chlorinated paraffins (SCCPs) are high-volume chemicals raising 
      concerns because of their classification as priority hazardous substances by the 
      European Water Framework Directive (WFD) and their recent inclusion in the 
      persistent organic pollutants' (POPs) list by the Stockholm convention. As this 
      group cover up to 5000 isomers, their measurement is still challenging. Hence the 
      SCCPs occurrence in the environment is poorly documented in comparison with other 
      POPs, especially in matrices where they are present at ultratrace levels such as 
      waters. In the two-past decades, passive sampling has been increasingly used as 
      it overcomes some major drawbacks associated to the conventional grab sampling. 
      This study constitutes the first work aiming to examine the passive sampling's 
      applicability for the monitoring of such complex analytes' mixtures in waters. 
      Optimization and calibration of two proven passive samplers, namely silicone 
      rubbers and Chemcatcher(R), were performed through batch and laboratory pilot 
      experiments. Despite the thousands of molecules present in the SCCPs mixture, the 
      resulting global kinetic uptakes fitted well with the theorical model, for both 
      samplers. Sampling rates of 8.0 L d(-1) for silicone rubbers and 0.53 L d(-1) for 
      Chemcatcher(R) were found, and logK(sw) determined for silicone rubbers equaled 
      4.24 to 4.95. These values are in complete agreement with published data for 
      other HOCs. A field trial carried out in marine coastal environments provided 
      further evidence to demonstrate the applicability of the passive samplers to 
      measure CPs amounts in water bodies. All these results unveil that passive 
      sampling using silicone rubbers or Chemcatcher(R) can be a relevant approach to 
      track traces of such complex mixtures in water.
CI  - Copyright (c) 2020 Elsevier B.V. All rights reserved.
FAU - Godere, Mathilde
AU  - Godere M
AD  - Aix Marseille Universite, CNRS, Laboratoire Chimie Environnement, France.
FAU - Mondange, Stella
AU  - Mondange S
AD  - Aix Marseille Universite, CNRS, Laboratoire Chimie Environnement, France; 
      Laboratoire de Genie de L'Environnement Industriel, IMT Mines Ales, 6 Avenue de 
      Clavieres, 30319, Ales, France.
FAU - Doumenq, Pierre
AU  - Doumenq P
AD  - Aix Marseille Universite, CNRS, Laboratoire Chimie Environnement, France.
FAU - Gonzalez, Catherine
AU  - Gonzalez C
AD  - Laboratoire de Genie de L'Environnement Industriel, IMT Mines Ales, 6 Avenue de 
      Clavieres, 30319, Ales, France.
FAU - Malleret, Laure
AU  - Malleret L
AD  - Aix Marseille Universite, CNRS, Laboratoire Chimie Environnement, France; 
      Laboratoire de Genie de L'Environnement Industriel, IMT Mines Ales, 6 Avenue de 
      Clavieres, 30319, Ales, France. Electronic address: laure.malleret@univ-amu.fr.
LA  - eng
PT  - Journal Article
DEP - 20201126
PL  - Netherlands
TA  - Talanta
JT  - Talanta
JID - 2984816R
SB  - IM
OTO - NOTNLM
OT  - Chemcatcher(R)
OT  - Chlorinated paraffins
OT  - Complex mixtures
OT  - European water framework directive
OT  - Passive sampling
OT  - Silicone rubber
EDAT- 2021/01/01 06:00
MHDA- 2021/01/01 06:01
CRDT- 2020/12/31 01:01
PHST- 2020/08/02 00:00 [received]
PHST- 2020/11/17 00:00 [revised]
PHST- 2020/11/23 00:00 [accepted]
PHST- 2020/12/31 01:01 [entrez]
PHST- 2021/01/01 06:00 [pubmed]
PHST- 2021/01/01 06:01 [medline]
AID - S0039-9140(20)31211-X [pii]
AID - 10.1016/j.talanta.2020.121920 [doi]
PST - ppublish
SO  - Talanta. 2021 Mar 1;224:121920. doi: 10.1016/j.talanta.2020.121920. Epub 2020 Nov 
      26.