PMID- 33382601
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20210118
IS  - 1520-510X (Electronic)
IS  - 0020-1669 (Linking)
VI  - 60
IP  - 2
DP  - 2021 Jan 18
TI  - HPO(3) and WO(4) Simultaneously Induce the Assembly of 
      Tri-Ln(III)-Incorporated Antimonotungstates and Their Photoluminescence 
      Behaviors.
PG  - 1037-1044
LID - 10.1021/acs.inorgchem.0c03148 [doi]
AB  - A double template agent strategy has been adopted to prepare a group of 
      triacetate-adorned tri-Ln(III)-incorporated trimeric antimonotungstates (AMTs) 
      K(3)Na(21)H[Ln(3)(CH(3)COO)(3)(HPO(3))(WO(4))][B-alpha-SbW(9)O(33)](3).36H(2)O [Ln = 
      Eu(3+) (1), Dy(3+) (2), Ho(3+) (3), or Er(3+) (4)] in a CH(3)COOH-CH(3)COONa 
      buffer system. Therein, H(3)PO(3) and Na(2)WO(4).2H(2)O have been, respectively, 
      transformed into the capped HPO(3) and WO(4) tetrahedra during the assembly 
      process, which are situated at the center of polyoxoanions of 1-4 and 
      simultaneously perform as structure-directing templates to induce the assembly of 
      1-4. The hexahedral configuration supramolecular stacking is the same as the 
      shape of a crystal of 1, which illustrates that the supramolecular stacking mode 
      plays a significant role in forming the crystal shape of 1-4. Under the Ln(3+) 
      f-f excitation, the photoluminescence behaviors involving the emission 
      spectrograms and fluorescence decay curves of 1-4 were systematically researched. 
      The modulation of the excitation wavelength has realized the emission color 
      tuning from blue to red, blue to green, blue to yellow, and green to yellow for 
      1-4. On the basis of the excitation of O --> W charge transfer (OWCT), the 
      energy-transfer procedure from AMT units to Eu(3+) centers in 1 is mainly 
      accomplished in the form of energy reabsorption. This work proposes a typical 
      case for the construction of a new type of AMT clusters by using the double 
      template agent strategy and confirms the great potential of Ln-containing AMTs in 
      optic applications.
FAU - Xu, Xin
AU  - Xu X
AD  - Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and 
      Chemical Engineering, Henan University, Kaifeng, Henan 475004, China.
FAU - Liu, Xiaoyi
AU  - Liu X
AD  - Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and 
      Chemical Engineering, Henan University, Kaifeng, Henan 475004, China.
FAU - Wang, Dan
AU  - Wang D
AD  - Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and 
      Chemical Engineering, Henan University, Kaifeng, Henan 475004, China.
FAU - Liu, Xuejun
AU  - Liu X
AD  - Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and 
      Chemical Engineering, Henan University, Kaifeng, Henan 475004, China.
FAU - Chen, Lijuan
AU  - Chen L
AD  - Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and 
      Chemical Engineering, Henan University, Kaifeng, Henan 475004, China.
FAU - Zhao, Junwei
AU  - Zhao J
AUID- ORCID: 0000-0002-7685-1309
AD  - Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and 
      Chemical Engineering, Henan University, Kaifeng, Henan 475004, China.
LA  - eng
PT  - Journal Article
DEP - 20201231
PL  - United States
TA  - Inorg Chem
JT  - Inorganic chemistry
JID - 0366543
SB  - IM
EDAT- 2021/01/01 06:00
MHDA- 2021/01/01 06:01
CRDT- 2020/12/31 17:08
PHST- 2021/01/01 06:00 [pubmed]
PHST- 2021/01/01 06:01 [medline]
PHST- 2020/12/31 17:08 [entrez]
AID - 10.1021/acs.inorgchem.0c03148 [doi]
PST - ppublish
SO  - Inorg Chem. 2021 Jan 18;60(2):1037-1044. doi: 10.1021/acs.inorgchem.0c03148. Epub 
      2020 Dec 31.