PMID- 33383477 OWN - NLM STAT- MEDLINE DCOM- 20210209 LR - 20210209 IS - 1095-8630 (Electronic) IS - 0301-4797 (Linking) VI - 281 DP - 2021 Mar 1 TI - Comparison of acoustic and hydrodynamic cavitation based hybrid AOPs for COD reduction of commercial effluent from CETP. PG - 111792 LID - S0301-4797(20)31717-5 [pii] LID - 10.1016/j.jenvman.2020.111792 [doi] AB - The present work investigates the treatment of commercial effluent obtained from Common Effluent Treatment Plants (CETP) using acoustic cavitation (AC) and hydrodynamic cavitation (HC) based hybrid AOPs. Comparison of different hybrid AOPs viz. H(2)O(2), Fe(2+)/H(2)O(2), Fe(2+)/H(2)O(2)/Air, Fe(2+)/H(2)O(2)/S(2)O(8)(2-) and Fe(2+)/H(2)O(2)/S(2)O(8)(2-)/Air in combination with both AC and HC has been performed in terms of extent of chemical oxygen demand (COD) reduction and kinetic rate constants. The best results of COD reduction as 95.2% and 97.28% were obtained for AC/Fe(2+)/H(2)O(2)/Air and HC/Fe(2+)/H(2)O(2)/Air systems respectively at Fe(2+)/H(2)O(2) ratio of 0.1 and pH of 2 within 60 min of treatment under conditions of ultrasonic power dissipation as 150 W, inlet pressure for HC as 4 bar (as applicable depending on process) and temperature of 30 +/- 2 degrees C. Slightly lower efficacy was established for the combination approach involving AC or HC coupled with Fe(2+)-activated S(2)O(8)(2-) and H(2)O(2) yielding COD reduction of 82.9% and 86.93% for the AC/Fe(2+)/H(2)O(2)/S(2)O(8)(2-)/Air and HC/Fe(2+)/H(2)O(2)/S(2)O(8)(2-)/Air systems respectively at Fe(2+)/H(2)O(2)/S(2)O(8)(2-) ratio of 1:40:17.5. Cost estimation on the basis of cavitational yield performed on the AC and HC based treatment systems revealed economical nature of HC based treatment. Kinetic studies were also performed by fitting the experimental data with pseudo first order kinetic model (PFOKM), generalized kinetic model (GKM) and Behnajady-Modirshahla-Ghanbery kinetic model (BMGKM). It was demonstrated that GKM provided best fitting for all the experiments whereas BMGKM was most suitable for Fenton based reactions. It was clearly established that complex CETP effluent can be effectively treated using the combined approaches based on HC with potential for larger scale operation. CI - Copyright (c) 2020 Elsevier Ltd. All rights reserved. FAU - Agarkoti, Chandrodai AU - Agarkoti C AD - Department of Chemical Engineering, Institute of Chemical Technology, Matunga, Mumbai, 40019, India. FAU - Gogate, Parag R AU - Gogate PR AD - Department of Chemical Engineering, Institute of Chemical Technology, Matunga, Mumbai, 40019, India. Electronic address: pr.gogate@ictmumbai.edu.in. FAU - Pandit, Aniruddha B AU - Pandit AB AD - Department of Chemical Engineering, Institute of Chemical Technology, Matunga, Mumbai, 40019, India. LA - eng PT - Journal Article DEP - 20201229 PL - England TA - J Environ Manage JT - Journal of environmental management JID - 0401664 RN - 0 (Water Pollutants, Chemical) RN - BBX060AN9V (Hydrogen Peroxide) SB - IM MH - Acoustics MH - Biological Oxygen Demand Analysis MH - *Hydrodynamics MH - Hydrogen Peroxide MH - Kinetics MH - Oxidation-Reduction MH - *Water Pollutants, Chemical OTO - NOTNLM OT - Acoustic cavitation OT - Advanced oxidation processes (AOPs) OT - CETP textile effluent OT - Hybrid treatment processes OT - Hydrodynamic cavitation OT - Kinetic model EDAT- 2021/01/01 06:00 MHDA- 2021/02/10 06:00 CRDT- 2020/12/31 20:15 PHST- 2020/05/16 00:00 [received] PHST- 2020/11/13 00:00 [revised] PHST- 2020/12/02 00:00 [accepted] PHST- 2021/01/01 06:00 [pubmed] PHST- 2021/02/10 06:00 [medline] PHST- 2020/12/31 20:15 [entrez] AID - S0301-4797(20)31717-5 [pii] AID - 10.1016/j.jenvman.2020.111792 [doi] PST - ppublish SO - J Environ Manage. 2021 Mar 1;281:111792. doi: 10.1016/j.jenvman.2020.111792. Epub 2020 Dec 29.