PMID- 33396060
OWN - NLM
STAT- MEDLINE
DCOM- 20210114
LR  - 20210114
IS  - 1090-2414 (Electronic)
IS  - 0147-6513 (Linking)
VI  - 208
DP  - 2021 Jan 15
TI  - Carboxyl-functionalized hollow polymer microspheres for detection of trace metal 
      elements in complex food matrixes by ICP-MS assisted with solid-phase extraction.
PG  - 111729
LID - S0147-6513(20)31566-9 [pii]
LID - 10.1016/j.ecoenv.2020.111729 [doi]
AB  - In this work, carboxyl-functionalized hollow polymer microspheres (CHPMs) was 
      successfully fabricated using poly (styrene-itaconic anhydride) particles as the 
      core template and itaconic anhydride and trans-anethole cross-linked with 
      divinylbenzene as the shell. The desirable microspheres and hollow structure of 
      CHPMs were demonstrated by scanning and transmission electron microscopies, 
      respectively. The characterized CHPMs as an adsorbent was packed into a solid 
      phase extraction column to simultaneously detect the V(V), Cr(III), Cu(II), 
      Cd(II), and Pb(II) in digested food samples by inductively coupled plasma-mass 
      spectrometry (ICP-MS). A series of experimental parameters of solid-phase 
      extraction (SPE) were investigated through vast experiments to improve 
      sensitivity of the proposed method in metal ions detection. The detection limits 
      of the method reached 0.8-3.2 ng L(-1) for the target elements, and the relative 
      standard deviations (RSDs) ranging from 1.2% to 3.5% were obtained from eleven 
      parallel experiments using a 1.0 mug L(-1) sample solution. The stability allowed 
      the material to withstand more than 15 cycling while the recoveries remained 
      above 88%. In food samples, the detection limits were at 0.20-0.80 mug kg(-1), and 
      satisfactory recoveries of 85-104% were obtained in spike tests of laver, fish as 
      well as chicken.
CI  - Copyright (c) 2020 The Authors. Published by Elsevier Inc. All rights reserved.
FAU - Qin, Jiaxing
AU  - Qin J
AD  - State Key Laboratory of Food Nutrition and Safety, Tianjin University of Science 
      and Technology, Tianjin 300457, China.
FAU - Su, Zheng
AU  - Su Z
AD  - State Key Laboratory of Food Nutrition and Safety, Tianjin University of Science 
      and Technology, Tianjin 300457, China.
FAU - Mao, Yuehui
AU  - Mao Y
AD  - State Key Laboratory of Food Nutrition and Safety, Tianjin University of Science 
      and Technology, Tianjin 300457, China.
FAU - Liu, Cuicui
AU  - Liu C
AD  - College of Food Science and Bioengineering, Tianjin Agricultural University, 
      Tianjin 300384, China.
FAU - Qi, Bin
AU  - Qi B
AD  - College of Food Science and Bioengineering, Tianjin Agricultural University, 
      Tianjin 300384, China.
FAU - Fang, Guozhen
AU  - Fang G
AD  - State Key Laboratory of Food Nutrition and Safety, Tianjin University of Science 
      and Technology, Tianjin 300457, China. Electronic address: 
      fangguozhen@tust.edu.cn.
FAU - Wang, Shuo
AU  - Wang S
AD  - State Key Laboratory of Food Nutrition and Safety, Tianjin University of Science 
      and Technology, Tianjin 300457, China; Research Center of Food Science and Human 
      Health, School of Medicine, Nankai University, Tianjin 300071, China. Electronic 
      address: s.wang@tust.edu.cn.
LA  - eng
PT  - Journal Article
DEP - 20201208
PL  - Netherlands
TA  - Ecotoxicol Environ Saf
JT  - Ecotoxicology and environmental safety
JID - 7805381
RN  - 0 (Polymers)
RN  - 0 (Trace Elements)
SB  - IM
MH  - Food Analysis/*methods
MH  - Hydrogen-Ion Concentration
MH  - Microspheres
MH  - Polymers/chemistry
MH  - Solid Phase Extraction/*methods
MH  - Spectrum Analysis
MH  - Trace Elements/*analysis
OTO - NOTNLM
OT  - Carboxyl-functionalized hollow polymer microspheres
OT  - Digested food samples
OT  - ICP-MS
OT  - Metal ions detection
OT  - Solid-phase extraction
EDAT- 2021/01/06 06:00
MHDA- 2021/01/15 06:00
CRDT- 2021/01/05 01:08
PHST- 2020/08/31 00:00 [received]
PHST- 2020/11/21 00:00 [revised]
PHST- 2020/11/25 00:00 [accepted]
PHST- 2021/01/05 01:08 [entrez]
PHST- 2021/01/06 06:00 [pubmed]
PHST- 2021/01/15 06:00 [medline]
AID - S0147-6513(20)31566-9 [pii]
AID - 10.1016/j.ecoenv.2020.111729 [doi]
PST - ppublish
SO  - Ecotoxicol Environ Saf. 2021 Jan 15;208:111729. doi: 
      10.1016/j.ecoenv.2020.111729. Epub 2020 Dec 8.