PMID- 33403266 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20210111 IS - 2470-1343 (Electronic) IS - 2470-1343 (Linking) VI - 5 IP - 51 DP - 2020 Dec 29 TI - Preparation of Cylindrical Janus Particles Using a Stirring Method. PG - 33047-33052 LID - 10.1021/acsomega.0c04538 [doi] AB - We previously discovered a novel method for the preparation of polymer particles that have a cylindrical shape. Polystyrene (PS) or poly methyl methacrylate (PMMA) spherical particles were deformed into a cylindrical shape by stirring with a magnetic stirrer in a polyvinylpyrrolidone (PVP) aqueous solution. In this study, cylindrical "Janus" particles consisting of PS and PMMA were prepared by this stirring method. In the case of spherical Janus particles, cylindrical particles were obtained after stirring; however, the direction of the interface between the PS and PMMA phases was random. However, in the case of snowman-like Janus particles, cylindrical Janus particles with the interface at the center of the long axis were successfully prepared. This indicated that the extension direction can be controlled owing to the anisotropic shape and supported the proposed deformation mechanism of the cylindrical particles. Moreover, amphiphilic cylindrical Janus particles were also successfully prepared by hydrolysis of only one phase to introduce carboxy groups. CI - (c) 2020 American Chemical Society. FAU - Onishi, Miku AU - Onishi M AD - Department of Chemical Science and Engineering, Graduate School of Engineering, Kobe University, Kobe 657-8501, Japan. FAU - Tsujishita, Yuya AU - Tsujishita Y AD - Department of Chemical Science and Engineering, Graduate School of Engineering, Kobe University, Kobe 657-8501, Japan. FAU - Li, Wei AU - Li W AD - Department of Chemical Science and Engineering, Graduate School of Engineering, Kobe University, Kobe 657-8501, Japan. FAU - Suzuki, Toyoko AU - Suzuki T AD - Department of Chemical Science and Engineering, Graduate School of Engineering, Kobe University, Kobe 657-8501, Japan. FAU - Minami, Hideto AU - Minami H AD - Department of Chemical Science and Engineering, Graduate School of Engineering, Kobe University, Kobe 657-8501, Japan. LA - eng PT - Journal Article DEP - 20201217 PL - United States TA - ACS Omega JT - ACS omega JID - 101691658 PMC - PMC7774087 COIS- The authors declare no competing financial interest. EDAT- 2021/01/07 06:00 MHDA- 2021/01/07 06:01 PMCR- 2020/12/17 CRDT- 2021/01/06 05:54 PHST- 2020/09/16 00:00 [received] PHST- 2020/12/07 00:00 [accepted] PHST- 2021/01/06 05:54 [entrez] PHST- 2021/01/07 06:00 [pubmed] PHST- 2021/01/07 06:01 [medline] PHST- 2020/12/17 00:00 [pmc-release] AID - 10.1021/acsomega.0c04538 [doi] PST - epublish SO - ACS Omega. 2020 Dec 17;5(51):33047-33052. doi: 10.1021/acsomega.0c04538. eCollection 2020 Dec 29.