PMID- 33504707 OWN - NLM STAT- MEDLINE DCOM- 20210129 LR - 20210129 IS - 0273-1223 (Print) IS - 0273-1223 (Linking) VI - 83 IP - 2 DP - 2021 Jan TI - Selective adsorption behavior of Cd(2+) imprinted acrylamide-crosslinked-poly(alginic acid) magnetic polymers: fabrication, characterization, adsorption performance and mechanism. PG - 449-462 LID - 10.2166/wst.2020.593 [doi] AB - Poly(acrylamide) grafted and glutaraldehyde-crosslinked alginic acid nano-magnetic adsorbent (AAMA) was prepared by selecting Cd(2+) as a template ion. Scanning electron microscope (SEM), thermo-gravimetric analyzer (TGA), vibrating sample magnetometer (VSM) and infrared spectroscopy (IR) were used to characterize the morphology and structure of AAMA. The adsorption of AAMA for different metal ions was compared and the impact of various factors for adsorption of Cd(2+) was systematically investigated. These results suggested that the AAMA was the aggregates of Fe(3)O(4) nanoparticles with a diameter of about 50-100 nm and had selectivity for Cd(2+) adsorption. The maximum adsorption capacity for Cd(2+) is 175 mg/g at pH 5.0 and 303 K. The experimental data were well described by the Langmuir isotherm model and pseudo-second-order model. The parameters of adsorption thermodynamics concluded that the adsorption progress is spontaneous and endothermic in nature. The parameters of adsorption activation energy suggested that there is physical adsorption and chemisorption on the adsorption of metal ions. AAMA could be regenerated by EDTA and still keep 71% adsorption capacity in the fifth consecutive adsorption-regeneration cycle. Therefore, AAMA would be useful as a selective and high adsorption capacity nano-magnetic adsorbent in the removal of Cd(2+) from wastewater. FAU - Li, Zuyu AU - Li Z AD - College of Environmental Science and Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353, China E-mail: guosz@qlu.edu.cn. FAU - Guo, Shuangzhen AU - Guo S AD - College of Environmental Science and Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353, China E-mail: guosz@qlu.edu.cn. FAU - Li, Da AU - Li D AD - College of Environmental Science and Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353, China E-mail: guosz@qlu.edu.cn. FAU - Zang, Lihua AU - Zang L AD - College of Environmental Science and Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353, China E-mail: guosz@qlu.edu.cn. LA - eng PT - Journal Article PL - England TA - Water Sci Technol JT - Water science and technology : a journal of the International Association on Water Pollution Research JID - 9879497 RN - 0 (Polymers) RN - 0 (Water Pollutants, Chemical) RN - 00BH33GNGH (Cadmium) RN - 20R035KLCI (Acrylamide) RN - 8C3Z4148WZ (Alginic Acid) SB - IM MH - Acrylamide MH - Adsorption MH - Alginic Acid MH - Cadmium MH - Kinetics MH - Magnetic Phenomena MH - *Polymers MH - *Water Pollutants, Chemical EDAT- 2021/01/29 06:00 MHDA- 2021/01/30 06:00 CRDT- 2021/01/28 05:34 PHST- 2021/01/28 05:34 [entrez] PHST- 2021/01/29 06:00 [pubmed] PHST- 2021/01/30 06:00 [medline] AID - 10.2166/wst.2020.593 [doi] PST - ppublish SO - Water Sci Technol. 2021 Jan;83(2):449-462. doi: 10.2166/wst.2020.593.