PMID- 33525697 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20210210 IS - 2073-4360 (Electronic) IS - 2073-4360 (Linking) VI - 13 IP - 3 DP - 2021 Jan 28 TI - Enhanced Water Resistance of Recycled Newspaper/High Density Polyethylene Composite Laminates via Hydrophobic Modification of Newspaper Laminas. LID - 10.3390/polym13030421 [doi] LID - 421 AB - A high strength recycled newspaper (NP)/high density polyethylene (HDPE) laminated composite was developed using NP laminas as reinforcement and HDPE film as matrix. Herein, NP fiber was modified with stearic acid (SA) to enhance the water resistance of the NP laminas and NP/HDPE composite. The effects of heat treatment and SA concentration on the water resistance and tensile property of NP and composite samples were investigated. The chemical structure of the NP was characterized with X-ray diffractometer, X-ray photoelectron spectroscopy and attenuated total reflectance Fourier transform infrared spectra techniques. The surface and microstructure of the NP sheets were observed by scanning electron microscopy. An expected high-water resistance of NP sheets was achieved due to a chemical bonding that low surface energy SA were grafted onto the modified NP fibers. Results showed that the hydrophobicity of NP increased with increasing the stearic acid concentration. The water resistance of the composite laminates was depended on the hydrophobicity of the NP sheets. The lowest value of 2 h water absorption rate (3.3% +/- 0.3%) and thickness swelling rate (2.2% +/- 0.4%) of composite were obtained when the SA concentration was 0.15 M. In addition, the introduction of SA can not only enhance the water resistance of the composite laminates, but also reduce the loss of tensile strength in wet conditions, which shows potential in outdoor applications. FAU - Zheng, Binwei AU - Zheng B AD - College of Materials and Energy, South China Agricultural University, Guangzhou 510642, China. FAU - Zhang, Weiwei AU - Zhang W AD - College of Materials and Energy, South China Agricultural University, Guangzhou 510642, China. FAU - Guan, Litao AU - Guan L AD - College of Materials and Energy, South China Agricultural University, Guangzhou 510642, China. FAU - Gu, Jin AU - Gu J AD - College of Materials and Energy, South China Agricultural University, Guangzhou 510642, China. FAU - Tu, Dengyun AU - Tu D AD - College of Materials and Energy, South China Agricultural University, Guangzhou 510642, China. FAU - Hu, Chuanshuang AU - Hu C AD - College of Materials and Energy, South China Agricultural University, Guangzhou 510642, China. LA - eng GR - 2017B020238003/Guangdong Science and Technology Department/ GR - 2018A030313233/Guangdong Science and Technology Department/ PT - Journal Article DEP - 20210128 PL - Switzerland TA - Polymers (Basel) JT - Polymers JID - 101545357 PMC - PMC7865505 OTO - NOTNLM OT - composite laminates OT - high strength OT - recycled newspaper OT - water resistance COIS- The authors declare no conflict of interest. EDAT- 2021/02/03 06:00 MHDA- 2021/02/03 06:01 PMCR- 2021/01/28 CRDT- 2021/02/02 01:04 PHST- 2020/12/22 00:00 [received] PHST- 2021/01/21 00:00 [revised] PHST- 2021/01/22 00:00 [accepted] PHST- 2021/02/02 01:04 [entrez] PHST- 2021/02/03 06:00 [pubmed] PHST- 2021/02/03 06:01 [medline] PHST- 2021/01/28 00:00 [pmc-release] AID - polym13030421 [pii] AID - polymers-13-00421 [pii] AID - 10.3390/polym13030421 [doi] PST - epublish SO - Polymers (Basel). 2021 Jan 28;13(3):421. doi: 10.3390/polym13030421.