PMID- 33538006 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20210310 IS - 1521-4095 (Electronic) IS - 0935-9648 (Linking) VI - 33 IP - 10 DP - 2021 Mar TI - Intermediate-Adduct-Assisted Growth of Stable CsPbI(2) Br Inorganic Perovskite Films for High-Efficiency Semitransparent Solar Cells. PG - e2006745 LID - 10.1002/adma.202006745 [doi] AB - Thanks to the tunable bandgap and excellent photoelectric characteristics, perovskites have been widely used in semitransparent solar cells (ST-SCs). Most works present unsatisfactory power conversion efficiencies (PCEs) through reducing the thickness of the perovskite films because there is a trade-off between PCE and average visible transmittance (AVT). As a consequence, most PCEs are less than 12% when the AVT is higher than 20% due to the limited voltage (V(oc) ) and short-circuit current (J(sc) ). Herein, a strategy of intermediate adduct (IMAT) engineering is developed to improve the film quality of the inorganic perovskite CsPbI(2) Br, which is a challenging issue to limit its performance of efficiency and stability. A normal n-i-p-structured PSC based on the optimal CsPbI(2) Br film delivers a PCE of 16.02% with excellent stability. Furthermore, through optimizing the electrode type and interface, the ST-PSC shows a high V(oc) larger than 1.2 V and the PCE reaches 14.01% and 10.36% under an AVT of 31.7% and 40.9%, respectively. This is the first demonstration of a CsPbI(2) Br ST-PSC, and it outperforms most of other types of perovskites. CI - (c) 2021 Wiley-VCH GmbH. FAU - Wang, Min AU - Wang M AD - School of Physical Science and Technology, Jiangsu Key Laboratory of Thin Films, Center for Energy Conversion Materials & Physics (CECMP), Soochow University, Suzhou, 215006, P. R. China. FAU - Cao, Fengren AU - Cao F AD - School of Physical Science and Technology, Jiangsu Key Laboratory of Thin Films, Center for Energy Conversion Materials & Physics (CECMP), Soochow University, Suzhou, 215006, P. R. China. FAU - Wang, Meng AU - Wang M AD - School of Physical Science and Technology, Jiangsu Key Laboratory of Thin Films, Center for Energy Conversion Materials & Physics (CECMP), Soochow University, Suzhou, 215006, P. R. China. FAU - Deng, Kaimo AU - Deng K AD - School of Physical Science and Technology, Jiangsu Key Laboratory of Thin Films, Center for Energy Conversion Materials & Physics (CECMP), Soochow University, Suzhou, 215006, P. R. China. FAU - Li, Liang AU - Li L AUID- ORCID: 0000-0003-0708-7762 AD - School of Physical Science and Technology, Jiangsu Key Laboratory of Thin Films, Center for Energy Conversion Materials & Physics (CECMP), Soochow University, Suzhou, 215006, P. R. China. LA - eng GR - 52025028/National Natural Science Foundation of China/ GR - 51972218/National Natural Science Foundation of China/ GR - 52002258/National Natural Science Foundation of China/ GR - 51772197/National Natural Science Foundation of China/ GR - 17KJA430013/Natural Science Foundation of the Jiangsu Higher Education Institutions of China/ GR - Priority Academic Program Development/ PT - Journal Article DEP - 20210203 PL - Germany TA - Adv Mater JT - Advanced materials (Deerfield Beach, Fla.) JID - 9885358 SB - IM OTO - NOTNLM OT - inorganic perovskites OT - semitransparent materials OT - solar cells EDAT- 2021/02/05 06:00 MHDA- 2021/02/05 06:01 CRDT- 2021/02/04 05:56 PHST- 2020/10/05 00:00 [received] PHST- 2020/12/06 00:00 [revised] PHST- 2021/02/05 06:00 [pubmed] PHST- 2021/02/05 06:01 [medline] PHST- 2021/02/04 05:56 [entrez] AID - 10.1002/adma.202006745 [doi] PST - ppublish SO - Adv Mater. 2021 Mar;33(10):e2006745. doi: 10.1002/adma.202006745. Epub 2021 Feb 3.