PMID- 33550432 OWN - NLM STAT- MEDLINE DCOM- 20211220 LR - 20211220 IS - 1436-5073 (Electronic) IS - 0026-3672 (Linking) VI - 188 IP - 3 DP - 2021 Feb 6 TI - An eco-friendly low-temperature synthetic approach towards micro-pebble-structured GO@SrTiO(3) nanocomposites for the detection of 2,4,6-trichlorophenol in environmental samples. PG - 72 LID - 10.1007/s00604-021-04729-w [doi] AB - The low-temperature synthesis of the graphene oxide-wrapped perovskite-type strontium titanate nanocomposites (GO@SrTiO(3)-NC) is reported for the electrochemical sensing of organochlorine pesticide 2,4,6-trichlorophenol (TCP) detection. The as-prepared GO@SrTiO(3) nanocomposites provide a large surface area, excellent conductivity, and active sites, which are more favorable to the catalysis of TCP. The synergistic effect between the GO and the perovskite SrTiO(3) results in the extended working range of 0.01 to 1.47 and 1.47 to 434.4 muM with a very low detection limit of 3.21 nM towards TCP detection. Moreover, the prepared sensor possessed good selectivity and long-term stability. Finally, the practical applicability of the sensor was tested in environmental samples of river water and soil, exhibiting adequate recovery values. FAU - Akilarasan, Muthumariappan AU - Akilarasan M AD - Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, No.1, Section 3, Chung-Hsiao East Road, Taipei, 106, Taiwan. FAU - Tamilalagan, Elayappan AU - Tamilalagan E AD - Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, No.1, Section 3, Chung-Hsiao East Road, Taipei, 106, Taiwan. FAU - Chen, Shen-Ming AU - Chen SM AUID- ORCID: 0000-0002-3749-1224 AD - Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, No.1, Section 3, Chung-Hsiao East Road, Taipei, 106, Taiwan. smchen1957@gmail.com. FAU - Maheshwaran, Selvarasu AU - Maheshwaran S AD - Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, No.1, Section 3, Chung-Hsiao East Road, Taipei, 106, Taiwan. FAU - Chen, Tse-Wei AU - Chen TW AD - Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, No.1, Section 3, Chung-Hsiao East Road, Taipei, 106, Taiwan. AD - Research and Development Center for Smart Textile Technology, National Taipei University of Technology, No.1, Section 3, Chung-Hsiao East Road, Taipei, 106, Taiwan. AD - Department of Materials, Imperial College London, London, SW72AZ, UK. FAU - Al-Mohaimeed, Amal M AU - Al-Mohaimeed AM AD - Department of Chemistry, College of Science, King Saud University, P.O. Box 22452, Riyadh, 11495, Saudi Arabia. FAU - Al-Onazi, Wedad A AU - Al-Onazi WA AD - Department of Chemistry, College of Science, King Saud University, P.O. Box 22452, Riyadh, 11495, Saudi Arabia. FAU - Elshikh, Mohamed Soliman AU - Elshikh MS AD - Department of Botany and Microbiology, College of Science, King Saud University, P.O. Box 22452, Riyadh, 11495, Saudi Arabia. LA - eng GR - MOST 107-2113-M-027 -005 -MY3/Ministry of Science and Technology, Taiwan/ PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20210206 PL - Austria TA - Mikrochim Acta JT - Mikrochimica acta JID - 7808782 RN - 0 (Chlorophenols) RN - 0 (Oxides) RN - 0 (Pesticides) RN - 0 (Soil Pollutants) RN - 0 (Water Pollutants, Chemical) RN - 0 (graphene oxide) RN - 7782-42-5 (Graphite) RN - D1JT611TNE (Titanium) RN - MHS8C5BAUZ (2,4,6-trichlorophenol) RN - OLH4I98373 (strontium titanium oxide) RN - YZS2RPE8LE (Strontium) SB - IM MH - Chlorophenols/*analysis MH - Cold Temperature MH - Electrochemical Techniques MH - Graphite/chemistry MH - Green Chemistry Technology MH - Limit of Detection MH - Nanocomposites/*chemistry MH - Oxides/chemistry MH - Pesticides/*analysis MH - Rivers/chemistry MH - Soil Pollutants/*analysis MH - Strontium/chemistry MH - Titanium/chemistry MH - Water Pollutants, Chemical/*analysis OTO - NOTNLM OT - Electrochemical sensor OT - Environmental samples OT - GO@SrTiO3 nanocomposites OT - Organochlorine pesticides OT - TCP detection EDAT- 2021/02/08 06:00 MHDA- 2021/12/21 06:00 CRDT- 2021/02/07 20:52 PHST- 2020/10/18 00:00 [received] PHST- 2021/01/22 00:00 [accepted] PHST- 2021/02/07 20:52 [entrez] PHST- 2021/02/08 06:00 [pubmed] PHST- 2021/12/21 06:00 [medline] AID - 10.1007/s00604-021-04729-w [pii] AID - 10.1007/s00604-021-04729-w [doi] PST - epublish SO - Mikrochim Acta. 2021 Feb 6;188(3):72. doi: 10.1007/s00604-021-04729-w.