PMID- 33573008 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20210228 IS - 2079-4991 (Print) IS - 2079-4991 (Electronic) IS - 2079-4991 (Linking) VI - 11 IP - 2 DP - 2021 Jan 29 TI - Temperature Dependence of Carrier Extraction Processes in GaSb/AlGaAs Quantum Nanostructure Intermediate-Band Solar Cells. LID - 10.3390/nano11020344 [doi] LID - 344 AB - From the viewpoint of band engineering, the use of GaSb quantum nanostructures is expected to lead to highly efficient intermediate-band solar cells (IBSCs). In IBSCs, current generation via two-step optical excitations through the intermediate band is the key to the operating principle. This mechanism requires the formation of a strong quantum confinement structure. Therefore, we focused on the material system with GaSb quantum nanostructures embedded in AlGaAs layers. However, studies involving crystal growth of GaSb quantum nanostructures on AlGaAs layers have rarely been reported. In our work, we fabricated GaSb quantum dots (QDs) and quantum rings (QRs) on AlGaAs layers via molecular-beam epitaxy. Using the Stranski-Krastanov growth mode, we demonstrated that lens-shaped GaSb QDs can be fabricated on AlGaAs layers. In addition, atomic force microscopy measurements revealed that GaSb QDs could be changed to QRs under irradiation with an As molecular beam even when they were deposited onto AlGaAs layers. We also investigated the suitability of GaSb/AlGaAs QDSCs and QRSCs for use in IBSCs by evaluating the temperature characteristics of their external quantum efficiency. For the GaSb/AlGaAs material system, the QDSC was found to have slightly better two-step optical excitation temperature characteristics than the QRSC. FAU - Shoji, Yasushi AU - Shoji Y AUID- ORCID: 0000-0003-4622-6649 AD - Global Zero Emission Research Center, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8568, Japan. AD - Research Center for Advanced Science and Technology (RCAST), The University of Tokyo, Meguro-ku, Tokyo 153-8904, Japan. FAU - Tamaki, Ryo AU - Tamaki R AD - Research Center for Advanced Science and Technology (RCAST), The University of Tokyo, Meguro-ku, Tokyo 153-8904, Japan. FAU - Okada, Yoshitaka AU - Okada Y AUID- ORCID: 0000-0002-1547-5477 AD - Research Center for Advanced Science and Technology (RCAST), The University of Tokyo, Meguro-ku, Tokyo 153-8904, Japan. LA - eng GR - 20K15183/Japan Society for the Promotion of Science/ PT - Journal Article DEP - 20210129 PL - Switzerland TA - Nanomaterials (Basel) JT - Nanomaterials (Basel, Switzerland) JID - 101610216 PMC - PMC7911294 OTO - NOTNLM OT - intermediate-band solar cell OT - molecular-beam epitaxy OT - quantum dot COIS- The authors declare no conflict of interest. EDAT- 2021/02/13 06:00 MHDA- 2021/02/13 06:01 PMCR- 2021/01/29 CRDT- 2021/02/12 01:03 PHST- 2020/12/28 00:00 [received] PHST- 2021/01/19 00:00 [revised] PHST- 2021/01/25 00:00 [accepted] PHST- 2021/02/12 01:03 [entrez] PHST- 2021/02/13 06:00 [pubmed] PHST- 2021/02/13 06:01 [medline] PHST- 2021/01/29 00:00 [pmc-release] AID - nano11020344 [pii] AID - nanomaterials-11-00344 [pii] AID - 10.3390/nano11020344 [doi] PST - epublish SO - Nanomaterials (Basel). 2021 Jan 29;11(2):344. doi: 10.3390/nano11020344.