PMID- 33576193 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20210325 LR - 20210325 IS - 1864-564X (Electronic) IS - 1864-5631 (Linking) VI - 14 IP - 6 DP - 2021 Mar 22 TI - Catalytic Conversion of Biomass to Furanic Derivatives with Deep Eutectic Solvents. PG - 1496-1506 LID - 10.1002/cssc.202100001 [doi] AB - Biomass is the only renewable organic carbon resource in nature, and the transformation of abundant biomass into various chemicals has received immense spotlight. As a novel generation of designer solvents, deep eutectic solvents (DESs) have been widely used in biorefinery due to their excellent properties including low cost, easy preparation, and biodegradability. Although there have been some reports summarizing the performance of DESs for the transformation of biomass into various chemicals, few Reviews illuminate the relationship between the functional structure of DESs and catalytic conversion of biomass. Hence, this Minireview comprehensively summarizes the effects of the types of functional groups in DESs on catalytic conversion of biomass into furanic derivatives, such as carboxylic acid-based hydrogen-bond donors (HBDs), carbohydrate-based HBDs, polyalcohol-based HBDs, amine/amide-based HBDs, spatial structure of HBDs, and various hydrogen-bond acceptors (HBAs). It also further summarizes the effects of adding different additives into the DESs on the synthesis of high value-added chemicals, including water, liquid inorganic acids, Lewis acids, heteropoly acids, and typical solid acids. Moreover, current challenges and prospects for the application of DESs in biomass conversion are provided. CI - (c) 2021 Wiley-VCH GmbH. FAU - Chen, Binglin AU - Chen B AD - College of Energy, Xiamen University, Xiamen, 361102, P.R. China. FAU - Peng, Zhiqing AU - Peng Z AD - College of Energy, Xiamen University, Xiamen, 361102, P.R. China. FAU - Li, Chuang AU - Li C AD - College of Energy, Xiamen University, Xiamen, 361102, P.R. China. FAU - Feng, Yunchao AU - Feng Y AD - College of Energy, Xiamen University, Xiamen, 361102, P.R. China. FAU - Sun, Yong AU - Sun Y AD - College of Energy, Xiamen University, Xiamen, 361102, P.R. China. AD - Fujian Engineering and Research Centre of Clean and High-valued Technologies for Biomass, Xiamen, 361102, P.R. China. AD - Xiamen Key Laboratory of Clean and High-valued Utilization for Biomass, Xiamen, 361102, P.R. China. FAU - Tang, Xing AU - Tang X AD - College of Energy, Xiamen University, Xiamen, 361102, P.R. China. AD - Fujian Engineering and Research Centre of Clean and High-valued Technologies for Biomass, Xiamen, 361102, P.R. China. AD - Xiamen Key Laboratory of Clean and High-valued Utilization for Biomass, Xiamen, 361102, P.R. China. FAU - Zeng, Xianhai AU - Zeng X AUID- ORCID: 0000-0002-5441-3164 AD - College of Energy, Xiamen University, Xiamen, 361102, P.R. China. AD - Fujian Engineering and Research Centre of Clean and High-valued Technologies for Biomass, Xiamen, 361102, P.R. China. AD - Xiamen Key Laboratory of Clean and High-valued Utilization for Biomass, Xiamen, 361102, P.R. China. FAU - Lin, Lu AU - Lin L AD - College of Energy, Xiamen University, Xiamen, 361102, P.R. China. AD - Fujian Engineering and Research Centre of Clean and High-valued Technologies for Biomass, Xiamen, 361102, P.R. China. AD - Xiamen Key Laboratory of Clean and High-valued Utilization for Biomass, Xiamen, 361102, P.R. China. LA - eng GR - 21978248/National Natural Science Foundation of China/ GR - 2019 J06005/Natural Science Foundation of Fujian Province of China/ PT - Journal Article PT - Review DEP - 20210212 PL - Germany TA - ChemSusChem JT - ChemSusChem JID - 101319536 SB - IM OTO - NOTNLM OT - biomass OT - catalysts OT - catalytic conversion OT - deep eutectic solvents OT - furanic derivatives EDAT- 2021/02/13 06:00 MHDA- 2021/02/13 06:01 CRDT- 2021/02/12 06:16 PHST- 2021/02/01 00:00 [revised] PHST- 2021/01/01 00:00 [received] PHST- 2021/02/13 06:00 [pubmed] PHST- 2021/02/13 06:01 [medline] PHST- 2021/02/12 06:16 [entrez] AID - 10.1002/cssc.202100001 [doi] PST - ppublish SO - ChemSusChem. 2021 Mar 22;14(6):1496-1506. doi: 10.1002/cssc.202100001. Epub 2021 Feb 12.