PMID- 33611608 OWN - NLM STAT- MEDLINE DCOM- 20210826 LR - 20210826 IS - 1432-2099 (Electronic) IS - 0301-634X (Linking) VI - 60 IP - 2 DP - 2021 May TI - Thermoluminescence study of pellets prepared using NaCl from Khewra Salt Mines in Pakistan. PG - 365-375 LID - 10.1007/s00411-021-00894-x [doi] AB - In this study, the thermoluminescence characteristics of naturally occurring salt (NaCl) were assessed for the development of a radiation dosimeter. For this purpose, mined crystalline samples of salt were procured directly from Khewra salt mines in Pakistan. The samples were hand crushed, sieved, and compressed to pellets comparable in size to standard TLD chips, and irradiated to gamma radiation doses in the range of 5 mGy and 5000 mGy. Thermoluminescence (TL) response showed three main peaks in the glow curve around 115-130 degrees C, 150-170 degrees C, and 220-240 degrees C. A linear TL response was observed for the dose range of 5-100 mGy. The TL response became supra-linear for the dose ranges of 100-1000 mGy and 1000-5000 mGy. The T(m)-T(stop) method was applied to identify the overlapping peaks of the glow curve. Computerized glow curve deconvolution (CGCD) was then employed for the characterization of electron trap parameters such as frequency factor (s), activation energy (E), and the kinetic order (b), using General Order (GO) kinetics. The figure-of-merit (FOM) was found to be 1.08%, 0.94%, 0.77%, and 0.75%, at 500 mGy, 1 Gy, 2 Gy, and 5 Gy, respectively. The TL intensity faded by 20% within the first 24 h after irradiation and finally stabilized after two weeks. In addition, structural, morphological, and elemental analyses, were also performed using various analytical techniques. X-ray diffraction (XRD) showed that the salt crystallizes in a face-centered cubic structure. Scanning electron microscope (SEM) micrographs indicated that the crystallites are closely packed and cubic-shaped with non-uniform size, and mostly found in the agglomerated form. Similarly, the elemental analysis confirmed the presence of impurities such as Mg, Sr, S, K, O, and Ca, in the samples. The present study concludes that the pellets made from salt samples from Khewra mines have a potential for use as radiation dosimeters. FAU - Ahmad, Khalil AU - Ahmad K AD - Department of Physics & Applied Mathematics, Institute of Engineering and Applied Sciences (PIEAS), Islamabad, 45650, Pakistan. FAU - Kakakhel, M Basim AU - Kakakhel MB AUID- ORCID: 0000-0002-0644-9672 AD - Department of Physics & Applied Mathematics, Institute of Engineering and Applied Sciences (PIEAS), Islamabad, 45650, Pakistan. basim@pieas.edu.pk. FAU - Hayat, Sikander AU - Hayat S AD - Department of Physics & Applied Mathematics, Institute of Engineering and Applied Sciences (PIEAS), Islamabad, 45650, Pakistan. FAU - Wazir-Ud-Din, M AU - Wazir-Ud-Din M AD - Department of Physics & Applied Mathematics, Institute of Engineering and Applied Sciences (PIEAS), Islamabad, 45650, Pakistan. FAU - Mahmood, M Masood AU - Mahmood MM AD - Department of Physics & Applied Mathematics, Institute of Engineering and Applied Sciences (PIEAS), Islamabad, 45650, Pakistan. FAU - Ur Rehman, Shakeel AU - Ur Rehman S AD - Department of Physics & Applied Mathematics, Institute of Engineering and Applied Sciences (PIEAS), Islamabad, 45650, Pakistan. FAU - Siddique, M Tariq AU - Siddique MT AD - Department of Physics & Applied Mathematics, Institute of Engineering and Applied Sciences (PIEAS), Islamabad, 45650, Pakistan. FAU - Mirza, Sikander M AU - Mirza SM AD - Department of Physics & Applied Mathematics, Institute of Engineering and Applied Sciences (PIEAS), Islamabad, 45650, Pakistan. LA - eng PT - Journal Article DEP - 20210220 PL - Germany TA - Radiat Environ Biophys JT - Radiation and environmental biophysics JID - 0415677 RN - 451W47IQ8X (Sodium Chloride) SB - IM MH - Gamma Rays MH - Luminescent Measurements MH - Microscopy, Electron, Scanning MH - Mining MH - Pakistan MH - *Sodium Chloride MH - Temperature MH - *Thermoluminescent Dosimetry MH - X-Ray Diffraction OTO - NOTNLM OT - Glow curve OT - NaCl OT - Natural dosimeter OT - Thermoluminescence EDAT- 2021/02/22 06:00 MHDA- 2021/08/27 06:00 CRDT- 2021/02/21 20:42 PHST- 2020/07/13 00:00 [received] PHST- 2021/02/01 00:00 [accepted] PHST- 2021/02/22 06:00 [pubmed] PHST- 2021/08/27 06:00 [medline] PHST- 2021/02/21 20:42 [entrez] AID - 10.1007/s00411-021-00894-x [pii] AID - 10.1007/s00411-021-00894-x [doi] PST - ppublish SO - Radiat Environ Biophys. 2021 May;60(2):365-375. doi: 10.1007/s00411-021-00894-x. Epub 2021 Feb 20.