PMID- 33624413
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20210423
IS  - 1864-564X (Electronic)
IS  - 1864-5631 (Linking)
VI  - 14
IP  - 8
DP  - 2021 Apr 22
TI  - Organic Multiple Redox Semi-Solid-Liquid Suspension for Li-Based Hybrid Flow 
      Battery.
PG  - 1913-1920
LID - 10.1002/cssc.202100094 [doi]
AB  - Li-based hybrid flow batteries are very promising in the energy storage market 
      for their high cell voltage and scale-up flexibility. However, the low volumetric 
      capacity of catholyte has limited their practical application. A novel concept of 
      organic multiple redox semi-solid-liquid (MRSSL) suspension was proposed and 
      demonstrated by taking advantage of active materials in both liquid and solid 
      phases in the suspension. In this study, high solubility of 
      2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) in the liquid phase and high 
      reversibility of 10-methylphenothiazine (MPT) composite in the solid phase were 
      employed to develop a high-performance and low-cost organic MRSSL Li-based hybrid 
      flow battery. It achieved a small voltage gap (<0.1 V) between liquid and solid 
      phase, high cell voltage ( approximately 3.4 V) and high energy density (260 Wh L(-1) ). Due to 
      the synergistic interactions between the liquid-phase TEMPO and the solid-phase 
      MPT, the viscosity of the MRSSL suspension was significantly reduced. An 
      intermittent-flow-mode test of TEMPO-MPT MRSSL suspension was conducted, which 
      proved that the suspension had an applicable cycling performance with high 
      volumetric capacity (50 Ah L(-1) ). The organic MRSSL suspension concept offers a 
      new approach to increase the volumetric capacity and energy density of Li-based 
      hybrid flow batteries by combining various low-cost solid and liquid organic 
      active materials.
CI  - (c) 2021 Wiley-VCH GmbH.
FAU - Zhang, Xuefeng
AU  - Zhang X
AD  - Chemical Hybrid Energy Novel Laboratory, College of Chemistry and Environmental 
      Engineering, Shenzhen University, Shenzhen, 518055, Guangdong, P.R. China.
FAU - Zhang, Peiyao
AU  - Zhang P
AD  - Chemical Hybrid Energy Novel Laboratory, College of Chemistry and Environmental 
      Engineering, Shenzhen University, Shenzhen, 518055, Guangdong, P.R. China.
FAU - Chen, Hongning
AU  - Chen H
AUID- ORCID: 0000-0003-4030-7771
AD  - Chemical Hybrid Energy Novel Laboratory, College of Chemistry and Environmental 
      Engineering, Shenzhen University, Shenzhen, 518055, Guangdong, P.R. China.
LA  - eng
GR  - 21908147/National Natural Science Foundation of China/
GR  - 000002110234/Natural Science Foundation of SZU/
PT  - Journal Article
DEP - 20210307
PL  - Germany
TA  - ChemSusChem
JT  - ChemSusChem
JID - 101319536
SB  - IM
OTO - NOTNLM
OT  - Li battery
OT  - electrochemistry
OT  - energy storage
OT  - flow battery
OT  - semi-solid-liquid
EDAT- 2021/02/25 06:00
MHDA- 2021/02/25 06:01
CRDT- 2021/02/24 05:50
PHST- 2021/02/16 00:00 [revised]
PHST- 2021/01/14 00:00 [received]
PHST- 2021/02/25 06:00 [pubmed]
PHST- 2021/02/25 06:01 [medline]
PHST- 2021/02/24 05:50 [entrez]
AID - 10.1002/cssc.202100094 [doi]
PST - ppublish
SO  - ChemSusChem. 2021 Apr 22;14(8):1913-1920. doi: 10.1002/cssc.202100094. Epub 2021 
      Mar 7.