PMID- 33671005 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20210317 IS - 2073-4360 (Electronic) IS - 2073-4360 (Linking) VI - 13 IP - 5 DP - 2021 Feb 28 TI - Study of the Synergetic Effect of Co-Pyrolysis of Lignite and High-Density Polyethylene Aiming to Improve Utilization of Low-Rank Coal. LID - 10.3390/polym13050759 [doi] LID - 759 AB - The mutual impact of low-quality lignite and high-density polyethylene (HDPE) during open system pyrolysis was investigated, aiming to improve utilization of lignite with simultaneous treatment of HDPE waste. Pyrolysis of lignite, HDPE, and their mixture (mass ratio, 1:1) was performed at temperatures 400, 450, 500, 550, and 600 degrees C. Initial substrates and pyrolysis products were characterized by thermogravimetric analysis (TGA), gas chromatography-mass spectrometry (GC-MS), specific carbon isotope analysis of individual hydrocarbons (delta(13)C), Rock-Eval pyrolysis, and elemental analysis. The positive synergetic effect during co-pyrolysis of lignite/HDPE mixture was observed at temperatures >/=450 degrees C, with the greatest being at 500 degrees C. The highest yield of liquid co-pyrolysis products with a similar composition to that of crude oils is also noticed at 500 degrees C. The yields of liquid and gaseous products and quality of pyrolytic products obtained by co-pyrolysis of lignite/HDPE mixture are notably improved compared with pyrolysis of lignite alone. On the other hand, data obtained from pyrolysis of HDPE alone indicate that it cannot be concurrent to well-developed catalytic thermal processes for polymer recycling. However, concerning the huge amount of produced HDPE, at least part of this plastic material can be reused for advanced thermal treatment of lignite, particularly in countries where this low-rank coal represents the main source of energy. FAU - Kojic, Ivan AU - Kojic I AUID- ORCID: 0000-0001-7737-1844 AD - Innovation Center of the Faculty of Chemistry, University of Belgrade, Studentski trg 12-16, 11000 Belgrade, Serbia. FAU - Bechtel, Achim AU - Bechtel A AD - Department of Applied Geosciences and Geophysics, Montanuniversitat Leoben, Peter-Tunner-Str. 5, A-8700 Leoben, Austria. FAU - Aleksic, Nikoleta AU - Aleksic N AD - Faculty of Mining and Geology, University of Belgrade, Dusina 7, 11000 Belgrade, Serbia. FAU - Zivotic, Dragana AU - Zivotic D AD - Faculty of Mining and Geology, University of Belgrade, Dusina 7, 11000 Belgrade, Serbia. FAU - Trifunovic, Snezana AU - Trifunovic S AD - Faculty of Chemistry, University of Belgrade, Studentski trg 12-16, 11000 Belgrade, Serbia. FAU - Gajica, Gordana AU - Gajica G AD - Institute of Chemistry, Technology and Metallurgy, Center of Chemistry, University of Belgrade, Studentski trg 12-16, 11000 Belgrade, Serbia. FAU - Stojanovic, Ksenija AU - Stojanovic K AUID- ORCID: 0000-0002-5566-2648 AD - Faculty of Chemistry, University of Belgrade, Studentski trg 12-16, 11000 Belgrade, Serbia. LA - eng GR - 451-03-68/2020-14/200168 and 451-03-01039/2015-09/05/Ministarstvo Prosvete, Nauke i Tehnoloskog Razvoja/ GR - SRB 18/2016/OeAD-GmbH/ GR - ICM-2017-06512/Ernst Mach Grant, Ernst Mach - worldwide/ PT - Journal Article DEP - 20210228 PL - Switzerland TA - Polymers (Basel) JT - Polymers JID - 101545357 PMC - PMC7957703 OTO - NOTNLM OT - HDPE OT - co-pyrolysis OT - lignite OT - synergetic effect COIS- The authors declare no conflict of interest. The funders had no role in the design of the study; in the collection, analyses, or interpretation of data; in the writing of the manuscript; or in the decision to publish the results. EDAT- 2021/03/07 06:00 MHDA- 2021/03/07 06:01 PMCR- 2021/02/28 CRDT- 2021/03/06 01:09 PHST- 2021/01/25 00:00 [received] PHST- 2021/02/19 00:00 [revised] PHST- 2021/02/19 00:00 [accepted] PHST- 2021/03/06 01:09 [entrez] PHST- 2021/03/07 06:00 [pubmed] PHST- 2021/03/07 06:01 [medline] PHST- 2021/02/28 00:00 [pmc-release] AID - polym13050759 [pii] AID - polymers-13-00759 [pii] AID - 10.3390/polym13050759 [doi] PST - epublish SO - Polymers (Basel). 2021 Feb 28;13(5):759. doi: 10.3390/polym13050759.