PMID- 33676716
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20210317
LR  - 20210317
IS  - 1873-3573 (Electronic)
IS  - 0039-9140 (Linking)
VI  - 226
DP  - 2021 May 1
TI  - A fully automated system with an optical immersion probe (OIP) for high-precision 
      spectrophotometric measurements.
PG  - 122185
LID - S0039-9140(21)00106-5 [pii]
LID - 10.1016/j.talanta.2021.122185 [doi]
AB  - A new and fully automated system with the interconnection of an Optical Immersion 
      Probe (OIP) - pH meter - peristaltic pump was used to study the spectral and 
      protolytic properties of carbocyanine the dyes 
      1,1',3,3,3',3'-hexamethylindocarbocyanine chloride (HIC); 
      1,1',3,3,3',3'-hexamethylindodicarbocyanine iodide (HIDC); and 
      3,3'-diethyloxadicarbocyanine iodide (DODC). This system can measure a large 
      number of experimental points in a short time period. The effect of 32 various 
      organic solvents on the UV-ViS spectra of the dyes was studied. The 
      solvatochromic behaviour of studied dyes was characterized by positive 
      solvatochromism for HIDC and negative solvatochromism for HIC and DODC. Through 
      the application of a large number of experimental points, the protonation and 
      hydrolysis constants of dyes were determined with high precision, where the 
      confidence interval of the small er, CyrillicK values is +/-(0.001-0.005), compared with a 
      confidence interval of +/-(0.04-0.10) for standard procedures. The fully automated 
      system presented is accurate, fast, environmentally friendly and promising for 
      multiple analytical applications.
CI  - Copyright (c) 2021 Elsevier B.V. All rights reserved.
FAU - Toth, J
AU  - Toth J
AD  - Department of Analytical Chemistry, Institute of Chemistry, Faculty of Science, 
      University of Pavol Jozef Safarik in Kosice, Moyzesova 11, 040 01, Kosice, Slovak 
      Republic. Electronic address: jan.toth@student.upjs.sk.
FAU - Bazel, Y
AU  - Bazel Y
AD  - Department of Analytical Chemistry, Institute of Chemistry, Faculty of Science, 
      University of Pavol Jozef Safarik in Kosice, Moyzesova 11, 040 01, Kosice, Slovak 
      Republic.
FAU - Balogh, I
AU  - Balogh I
AD  - Department of Chemistry, College of Nyiregyhaza, HU-4400, Nyiregyhaza, Hungary.
LA  - eng
PT  - Journal Article
DEP - 20210205
PL  - Netherlands
TA  - Talanta
JT  - Talanta
JID - 2984816R
SB  - IM
OTO - NOTNLM
OT  - Carbocyanine dyes
OT  - Measurement automation
OT  - Optical immersion probe
OT  - Spectral properties
EDAT- 2021/03/08 06:00
MHDA- 2021/03/08 06:01
CRDT- 2021/03/07 20:27
PHST- 2020/12/10 00:00 [received]
PHST- 2021/01/28 00:00 [revised]
PHST- 2021/01/31 00:00 [accepted]
PHST- 2021/03/07 20:27 [entrez]
PHST- 2021/03/08 06:00 [pubmed]
PHST- 2021/03/08 06:01 [medline]
AID - S0039-9140(21)00106-5 [pii]
AID - 10.1016/j.talanta.2021.122185 [doi]
PST - ppublish
SO  - Talanta. 2021 May 1;226:122185. doi: 10.1016/j.talanta.2021.122185. Epub 2021 Feb 
      5.