PMID- 33684732 OWN - NLM STAT- MEDLINE DCOM- 20210426 LR - 20210426 IS - 1873-6750 (Electronic) IS - 0160-4120 (Linking) VI - 152 DP - 2021 Jul TI - Environmental characteristics and formations of polybrominated dibenzo-p-dioxins and dibenzofurans. PG - 106450 LID - S0160-4120(21)00075-1 [pii] LID - 10.1016/j.envint.2021.106450 [doi] AB - Polybrominated dibenzo-p-dioxins and furans (PBDD/Fs) are emerging persistent organic pollutants (POPs) that have similar or higher toxicities than the notorious dioxins. Toxicities, formation mechanisms, and environmental fates of PBDD/Fs are lacking because accurate quantification, especially of higher brominated congeners, is challenging. PBDD/F analysis is difficult because of photolysis and thermal degradation and interference from polybrominated diphenyl ethers. Here, literatures on PBDD/F analysis and environmental occurrences are reviewed to improve our understanding of PBDD/F environmental pollution and human exposure levels. Although PBDD/Fs behave similarly to dioxins, different congener profiles between PBDD/Fs and dioxins in the environment indicates their different sources and formation mechanisms. Herein, potential sources and formation mechanisms of PBDD/Fs were critically discussed, and current knowledge gaps and future directions for PBDD/F research are highlighted. An understanding of PBDD/F formation pathways will allow for development of synergistic control strategies for PBDD/Fs, dioxins, and other dioxin-like POPs. CI - Copyright (c) 2021 The Author(s). Published by Elsevier Ltd.. All rights reserved. FAU - Yang, Lili AU - Yang L AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, P.O. Box 2871, Beijing 100085, China. FAU - Liu, Guorui AU - Liu G AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, P.O. Box 2871, Beijing 100085, China; School of Environment, Hangzhou Institute for Advanced Study, UCAS, Hangzhou 310000, China; College of Resource and Environment, University of Chinese Academy of Sciences, Beijing 100049, China. FAU - Shen, Jia AU - Shen J AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, P.O. Box 2871, Beijing 100085, China. FAU - Wang, Minxiang AU - Wang M AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, P.O. Box 2871, Beijing 100085, China. FAU - Yang, Qiuting AU - Yang Q AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, P.O. Box 2871, Beijing 100085, China. FAU - Zheng, Minghui AU - Zheng M AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, P.O. Box 2871, Beijing 100085, China; School of Environment, Hangzhou Institute for Advanced Study, UCAS, Hangzhou 310000, China; Institute of Environment and Health, Jianghan University, Wuhan 430056, China. Electronic address: zhengmh@rcees.ac.cn. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't PT - Review DEP - 20210305 PL - Netherlands TA - Environ Int JT - Environment international JID - 7807270 RN - 0 (Dibenzofurans) RN - 0 (Dioxins) RN - 0 (Polychlorinated Dibenzodioxins) RN - O1B5KJ235I (dibenzo(1,4)dioxin) SB - IM MH - Dibenzofurans/analysis MH - *Dioxins/analysis MH - Environmental Monitoring MH - Humans MH - *Polychlorinated Dibenzodioxins/analysis OTO - NOTNLM OT - Analysis method OT - Environmental characteristics OT - Formation mechanism OT - Polybrominated dibenzo-p-dioxins and dibenzofurans (PBDD/Fs) OT - Sources EDAT- 2021/03/09 06:00 MHDA- 2021/04/27 06:00 CRDT- 2021/03/08 20:14 PHST- 2020/09/16 00:00 [received] PHST- 2020/12/23 00:00 [revised] PHST- 2021/02/04 00:00 [accepted] PHST- 2021/03/09 06:00 [pubmed] PHST- 2021/04/27 06:00 [medline] PHST- 2021/03/08 20:14 [entrez] AID - S0160-4120(21)00075-1 [pii] AID - 10.1016/j.envint.2021.106450 [doi] PST - ppublish SO - Environ Int. 2021 Jul;152:106450. doi: 10.1016/j.envint.2021.106450. Epub 2021 Mar 5.