PMID- 33713266 OWN - NLM STAT- MEDLINE DCOM- 20210727 LR - 20210727 IS - 1614-7499 (Electronic) IS - 0944-1344 (Linking) VI - 28 IP - 28 DP - 2021 Jul TI - Development of highly efficient and reusable magnetic nitrogen-doped carbon nanotubes for chlorophenol removal. PG - 37424-37434 LID - 10.1007/s11356-021-13302-0 [doi] AB - Nitrogen-doped carbon nanotubes (N-CNTs) were synthesized via a hydrothermal method and further modified with magnetic Co(0.5)Cu(0.5)Fe(2)O(4) nanoparticles following a one-pot solvothermal method. The characterization data show that the distribution of the magnetic materials and the adsorption characteristics of the CNTs can be tailored as a function of the N doping amount. The N-CNT adsorption isotherms as a function of N content and chlorophenol uptake show that a N doping level of 6% is optimum. After loading the N-CNTs with the magnetic Co(0.5)Cu(0.5)Fe(2)O(4) nanoparticles (M-N-CNTs), the resulting materials were easily dispersed in aqueous media with specific surface area reaching 95.64 m(2)/g. The M-N-CNTs exhibit high affinities toward the adsorption of different chlorophenols following the order: Pentachlorophenol (PCP) > 2,4,6-trichlorophenol (2,4,6-TCP) > 2,4-dichlorophenol (2,4-DCP) > 2,4-dichlorophenoxyacetic acid (2,4-D) > phenol. Additionally, the M-N-CNTs exhibit good microwave absorption performance and can be regenerated by microwave irradiation with high efficiencies (> 90%) maintained with high stabilities. CI - (c) 2021. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature. FAU - Zhang, Xue AU - Zhang X AD - Qingdao Engineering Research Center for Rural Environment, College of Resource and Environment, Qingdao Agricultural University, Qingdao City, 266109, Shandong Province, China. FAU - Cui, Chunyue AU - Cui C AD - Qingdao Engineering Research Center for Rural Environment, College of Resource and Environment, Qingdao Agricultural University, Qingdao City, 266109, Shandong Province, China. cuichunyue1977@163.com. FAU - Zheng, Qingzhu AU - Zheng Q AD - Qingdao Engineering Research Center for Rural Environment, College of Resource and Environment, Qingdao Agricultural University, Qingdao City, 266109, Shandong Province, China. FAU - Wang, Ying AU - Wang Y AD - Qingdao Engineering Research Center for Rural Environment, College of Resource and Environment, Qingdao Agricultural University, Qingdao City, 266109, Shandong Province, China. FAU - Chang, Jing AU - Chang J AD - Qingdao Engineering Research Center for Rural Environment, College of Resource and Environment, Qingdao Agricultural University, Qingdao City, 266109, Shandong Province, China. FAU - Wang, Shuxian AU - Wang S AD - Qingdao Engineering Research Center for Rural Environment, College of Resource and Environment, Qingdao Agricultural University, Qingdao City, 266109, Shandong Province, China. LA - eng GR - ZR2017MEE013/Natural Science Foundation of Shandong Province/ PT - Journal Article DEP - 20210313 PL - Germany TA - Environ Sci Pollut Res Int JT - Environmental science and pollution research international JID - 9441769 RN - 0 (Chlorophenols) RN - 0 (Nanotubes, Carbon) RN - N762921K75 (Nitrogen) SB - IM MH - Adsorption MH - *Chlorophenols MH - Microwaves MH - *Nanotubes, Carbon MH - Nitrogen OTO - NOTNLM OT - Adsorption OT - Carbon nanotubes OT - Chlorophenol OT - Magnetic nanoparticles OT - Microwave regeneration OT - Nitrogen EDAT- 2021/03/14 06:00 MHDA- 2021/07/28 06:00 CRDT- 2021/03/13 12:11 PHST- 2020/10/26 00:00 [received] PHST- 2021/03/01 00:00 [accepted] PHST- 2021/03/14 06:00 [pubmed] PHST- 2021/07/28 06:00 [medline] PHST- 2021/03/13 12:11 [entrez] AID - 10.1007/s11356-021-13302-0 [pii] AID - 10.1007/s11356-021-13302-0 [doi] PST - ppublish SO - Environ Sci Pollut Res Int. 2021 Jul;28(28):37424-37434. doi: 10.1007/s11356-021-13302-0. Epub 2021 Mar 13.