PMID- 33714461
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20210317
LR  - 20210317
IS  - 1873-3573 (Electronic)
IS  - 0039-9140 (Linking)
VI  - 227
DP  - 2021 May 15
TI  - Porous cage-like hollow magnetic carbon-doped CoO nanocomposite as an advanced 
      sorbent for magnetic solid-phase extraction of nine polycyclic aromatic 
      hydrocarbons.
PG  - 122149
LID - S0039-9140(21)00070-9 [pii]
LID - 10.1016/j.talanta.2021.122149 [doi]
AB  - In this study, porous cage-like hollow magnetic carbon-doped CoO nanocomposite 
      (CoO@C) was successfully synthesized using a metal-organic frameworks (MOFs) as 
      precursor by one-step calcination method in this work. The obtained nanoporous 
      composite showed excellent magnetic response by taking advantage of the magnetism 
      of CoO even without the Fe(3)O(4), making it an advanced sorbent for magnetic 
      solid-phase extraction (MSPE). The Co-MOF and CoO@C were characterized by XRD, 
      TGA, SEM, TEM, vibrating sample magnetometry, and FT-IR spectroscopy. Based on 
      this, a method using CoO@C for MSPE coupled with HPLC was established for the 
      analysis of nine polycyclic aromatic hydrocarbons (PAHs) from various real water 
      samples. The amount of sorbent, extraction times, extraction temperature, 
      desorption times, oscillation rate, and elution volume were optimized. Under the 
      optimal conditions, the method had good relative standard deviations (RSDs) of 
      1.1%-6.5% and a satisfying linearity range of 0.5-1000 mug L(-1). The low LOD and 
      LOQ for nine PAHs were found to be 0.06-1.30 mug L(-1) and 0.19-4.30 mug L(-1), 
      respectively. The experimental results indicated that the prepared nanocomposite 
      showed excellent adsorption capacity compared to other commercial sorbents and 
      has potential applications for the removal of hazardous pollutants from 
      environmental samples.
CI  - Copyright (c) 2021 Elsevier B.V. All rights reserved.
FAU - Huang, Pengfei
AU  - Huang P
AD  - Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, 
      College of Chemistry and Chemical Engineering, Northwest Normal University, 
      Lanzhou, 730070, PR China.
FAU - Kou, Haixia
AU  - Kou H
AD  - Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, 
      College of Chemistry and Chemical Engineering, Northwest Normal University, 
      Lanzhou, 730070, PR China.
FAU - Wang, Xuemei
AU  - Wang X
AD  - Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, 
      College of Chemistry and Chemical Engineering, Northwest Normal University, 
      Lanzhou, 730070, PR China. Electronic address: wangxuemei@nwnu.edu.cn.
FAU - Zhou, Zheng
AU  - Zhou Z
AD  - Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, 
      College of Chemistry and Chemical Engineering, Northwest Normal University, 
      Lanzhou, 730070, PR China.
FAU - Du, Xinzhen
AU  - Du X
AD  - Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, 
      College of Chemistry and Chemical Engineering, Northwest Normal University, 
      Lanzhou, 730070, PR China.
FAU - Lu, Xiaoquan
AU  - Lu X
AD  - Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, 
      College of Chemistry and Chemical Engineering, Northwest Normal University, 
      Lanzhou, 730070, PR China.
LA  - eng
PT  - Journal Article
DEP - 20210210
PL  - Netherlands
TA  - Talanta
JT  - Talanta
JID - 2984816R
SB  - IM
OTO - NOTNLM
OT  - Adsorbents
OT  - Magnetic solid-phase extraction (MSPE)
OT  - Metal-organic frameworks
OT  - Polycyclic aromatic hydrocarbons (PAHs)
EDAT- 2021/03/15 06:00
MHDA- 2021/03/15 06:01
CRDT- 2021/03/14 20:31
PHST- 2020/12/23 00:00 [received]
PHST- 2021/01/19 00:00 [revised]
PHST- 2021/01/24 00:00 [accepted]
PHST- 2021/03/14 20:31 [entrez]
PHST- 2021/03/15 06:00 [pubmed]
PHST- 2021/03/15 06:01 [medline]
AID - S0039-9140(21)00070-9 [pii]
AID - 10.1016/j.talanta.2021.122149 [doi]
PST - ppublish
SO  - Talanta. 2021 May 15;227:122149. doi: 10.1016/j.talanta.2021.122149. Epub 2021 
      Feb 10.