PMID- 33715754 OWN - NLM STAT- MEDLINE DCOM- 20210628 LR - 20210628 IS - 1533-4899 (Electronic) IS - 1533-4880 (Linking) VI - 21 IP - 7 DP - 2021 Jul 1 TI - Isotherm, Kinetic and Thermodynamic Studies on Adsorption of Bromocresol Purple, Acid Red 66 and Acid Blue 40 Using Activated Carbon. PG - 4104-4109 LID - 10.1166/jnn.2021.19176 [doi] AB - This study was conducted with a batch reaction to equilibrium isotherm, kinetic and thermodynamic parameters on adsorption of bromocresol purple (BCP), acid red 66 (AR 66) and acid blue 40 (AB 40) from aqueous solution by using activated carbon with nanopores. Freundlich and Temkin isotherm models were used to evaluate the suitability of isotherm for adsorption equilibrium data. The adsorption equilibrium was best fitted by Temkin model. The Freundlich separation factor values indicated that adsorption on the nanoporous activated carbon could effectively treat three dyes. The kinetic analysis of the adsorption process confirmed that it was more consistent with the pseudo second order model. The intraparticle diffusion was rate limiting step. The adsorption process of three dyes were endothermic because they were positive enthalpy values. The free energy values of three dyes decreased with increasing temperature, so that the spontaneity becomes higher with temperature increase. The activation energy value of three dyes were confirmed the physical adsorption. FAU - Lee, Jong Jib AU - Lee JJ AD - Department of Chemical Engineering, Kongju National University, 1223-24 Cheonandaero, Subuk-gu, Cheonan, Chungnam 31080, Republic of Korea. FAU - Jeon, Jong Ki AU - Jeon JK AD - Department of Chemical Engineering, Kongju National University, 1223-24 Cheonandaero, Subuk-gu, Cheonan, Chungnam 31080, Republic of Korea. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't PL - United States TA - J Nanosci Nanotechnol JT - Journal of nanoscience and nanotechnology JID - 101088195 RN - 0 (Anthraquinones) RN - 0 (Rhodamines) RN - 0 (Water Pollutants, Chemical) RN - 16291-96-6 (Charcoal) RN - 201C22C3EC (Bromcresol Purple) RN - 2609-88-3 (lissamine rhodamine B) RN - WA81N3PV2R (Acid Blue 40) SB - IM MH - Adsorption MH - Anthraquinones MH - Bromcresol Purple MH - *Charcoal MH - Hydrogen-Ion Concentration MH - Kinetics MH - Rhodamines MH - Temperature MH - Thermodynamics MH - *Water Pollutants, Chemical EDAT- 2021/03/16 06:00 MHDA- 2021/06/29 06:00 CRDT- 2021/03/15 05:48 PHST- 2021/03/15 05:48 [entrez] PHST- 2021/03/16 06:00 [pubmed] PHST- 2021/06/29 06:00 [medline] AID - 10.1166/jnn.2021.19176 [doi] PST - ppublish SO - J Nanosci Nanotechnol. 2021 Jul 1;21(7):4104-4109. doi: 10.1166/jnn.2021.19176.