PMID- 33772891
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20210513
IS  - 1521-3765 (Electronic)
IS  - 0947-6539 (Linking)
VI  - 27
IP  - 27
DP  - 2021 May 12
TI  - Accelerating H(2) Evolution by Anodic Semi-dehydrogenation of 
      Tetrahydroisoquinolines in Water over Co(3) O(4) Nanoribbon Arrays Decorated 
      Nickel Foam.
PG  - 7502-7506
LID - 10.1002/chem.202100249 [doi]
AB  - Coupling the H(2) evolution reaction in water with thermodynamically favorable 
      organic oxidation reactions is highly desirable, because it can enhance the 
      energy conversion efficiency compared with electrocatalytic water splitting, and 
      produce value-added chemicals instead of O(2) in the anodic reaction. Herein, 
      Co(3) O(4) nanoribbon arrays in situ grown on nickel foam (Co(3) O(4) @NF) was 
      employed as an effective electrocatalyst for the selective oxidation of 
      tetrahydroisoquinolines (THIQs). Various value-added semi-dehydrogenation 
      products including dihydroisoquinolines with electro-deficient or -rich groups 
      could be obtained with moderate yields and faradaic efficiencies. Benefitting 
      from the rich surface active sites of Co(3) O(4) @NF, a two-electrode (Co(3) O(4) 
      @NF||Pt) electrolytic system drove a benchmark current density of 10 mA cm(-2) at 
      a cell voltage as low as 1.446 V in 1.0 M KOH aqueous solution containing 0.02 M 
      THIQ, which was reduced by 174 mV in comparison with that of overall water 
      splitting.
CI  - (c) 2021 Wiley-VCH GmbH.
FAU - Xiang, Ming
AU  - Xiang M
AD  - Key Laboratory of Optoelectronic Chemical Materials and Devices of Ministry of 
      Education, Jianghan University, Wuhan, 430056, P. R. China.
FAU - Xu, Zhihua
AU  - Xu Z
AD  - Key Laboratory of Optoelectronic Chemical Materials and Devices of Ministry of 
      Education, Jianghan University, Wuhan, 430056, P. R. China.
FAU - Wang, Jinghao
AU  - Wang J
AD  - CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for 
      Excellence in Nanoscience National Center for Nanoscience and Technology, 
      Beijing, 100190, P. R. China.
FAU - Yang, Xiaoqiu
AU  - Yang X
AD  - Key Laboratory of Optoelectronic Chemical Materials and Devices of Ministry of 
      Education, Jianghan University, Wuhan, 430056, P. R. China.
FAU - Yan, Zhaoxiong
AU  - Yan Z
AUID- ORCID: 0000-0001-8118-569X
AD  - Key Laboratory of Optoelectronic Chemical Materials and Devices of Ministry of 
      Education, Jianghan University, Wuhan, 430056, P. R. China.
LA  - eng
GR  - 21871111/National Natural Science Foundation of China/
GR  - 2019CFA078/Excellent Youth Foundation of Hubei Province of China/
GR  - JDGD-202012/Opening Project of Key Laboratory of Optoelectronic Chemical 
      Materials and Devices, Ministry of Education, Jianghan University/
PT  - Journal Article
DEP - 20210414
PL  - Germany
TA  - Chemistry
JT  - Chemistry (Weinheim an der Bergstrasse, Germany)
JID - 9513783
SB  - IM
OTO - NOTNLM
OT  - Co3O4 electrocatalyst
OT  - dihydroisoquinolines
OT  - energy-saving
OT  - hydrogen evolution reaction
OT  - semi-dehydrogenation
EDAT- 2021/03/28 06:00
MHDA- 2021/03/28 06:01
CRDT- 2021/03/27 17:32
PHST- 2021/01/21 00:00 [received]
PHST- 2021/03/28 06:00 [pubmed]
PHST- 2021/03/28 06:01 [medline]
PHST- 2021/03/27 17:32 [entrez]
AID - 10.1002/chem.202100249 [doi]
PST - ppublish
SO  - Chemistry. 2021 May 12;27(27):7502-7506. doi: 10.1002/chem.202100249. Epub 2021 
      Apr 14.