PMID- 33773319
OWN - NLM
STAT- MEDLINE
DCOM- 20210527
LR  - 20210527
IS  - 1879-1298 (Electronic)
IS  - 0045-6535 (Linking)
VI  - 277
DP  - 2021 Aug
TI  - A novel CNTs-Fe(3)O(4) synthetized via a ball-milling strategy as efficient 
      fenton-like catalyst for degradation of sulfonamides.
PG  - 130305
LID - S0045-6535(21)00775-X [pii]
LID - 10.1016/j.chemosphere.2021.130305 [doi]
AB  - A novel composite (CNTs-Fe(3)O(4)) was synthesized by a ball-milling strategy and 
      characterized by BET, SEM, FTIR, XRD and VSM. The as-fabricated CNTs-Fe(3)O(4) 
      was used to remove six sulfonamides by a Fenton degradation process, including 
      sulfanilamide (SAM), sulfamerazine (SMR), sulfadimethoxine (SMX), sulfadiazine 
      (SDZ), sulfamethazine (SMT) and sulfametoxydiazine (SMD). The degradation 
      behaviors of six sulfonamides in CNTs-Fe(3)O(4)/H(2)O(2) system and the 
      relationship between molecular structure of sulfonamides and their degradation 
      behaviors were investigated systematically. Batch experimental results showed 
      that the as-fabricated CNTs-Fe(3)O(4) had excellent Fenton catalytic activity for 
      the degradation of sulfonamides due to its unique porous structure and the good 
      combination mode of CNTs with Fe(3)O(4) particles. The first-order kinetic mode 
      could better describe the degradation behaviors of six sulfonamides in 
      CNTs-Fe(3)O(4)/H(2)O(2) system, and the degradation rate constant could be 
      ordered as: SAM < SMT < SDZ < SMR < SMD < SMX. The quantitative relationship 
      between the Mulliken charge of sulfonamides (x) and their degradation rate 
      constant (y) in CNTs-Fe(3)O(4)/H(2)O(2) system could be described as: y = - 
      28.719x + 15.67 (R(2) = 0.957). Finally, the possible synthesis mechanisms of 
      CNTs-Fe(3)O(4) and the degradation mechanisms of sulfonamides in 
      CNTs-Fe(3)O(4)/H(2)O(2) system was proposed.
CI  - Copyright (c) 2021 Elsevier Ltd. All rights reserved.
FAU - Liu, Yunbo
AU  - Liu Y
AD  - College of Chemistry and Materials Science, Sichuan Normal University, Chengdu, 
      610066, China.
FAU - Zhang, Xuemei
AU  - Zhang X
AD  - College of Chemistry and Materials Science, Sichuan Normal University, Chengdu, 
      610066, China.
FAU - Deng, Jinhua
AU  - Deng J
AD  - College of Chemistry and Materials Science, Sichuan Normal University, Chengdu, 
      610066, China.
FAU - Liu, Yong
AU  - Liu Y
AD  - College of Chemistry and Materials Science, Sichuan Normal University, Chengdu, 
      610066, China; Key Laboratory of Treatment for Special Wastewater of Sichuan 
      Province Higher Education System, Sichuan, Chengdu, 610066, China. Electronic 
      address: liuyong75@sicnu.edu.cn.
LA  - eng
PT  - Journal Article
DEP - 20210317
PL  - England
TA  - Chemosphere
JT  - Chemosphere
JID - 0320657
RN  - 0 (Sulfonamides)
RN  - 21240MF57M (Sulfanilamide)
RN  - 48U51W007F (Sulfamethazine)
RN  - BBX060AN9V (Hydrogen Peroxide)
SB  - IM
MH  - Catalysis
MH  - *Hydrogen Peroxide
MH  - Sulfamethazine
MH  - Sulfanilamide
MH  - *Sulfonamides
OTO - NOTNLM
OT  - Antibiotic
OT  - Ball-milling
OT  - Carbon nanotubes
OT  - Fenton-like oxidation
OT  - Magnetic Fe(3)O(4)
EDAT- 2021/03/28 06:00
MHDA- 2021/05/28 06:00
CRDT- 2021/03/27 20:16
PHST- 2021/01/30 00:00 [received]
PHST- 2021/03/11 00:00 [revised]
PHST- 2021/03/13 00:00 [accepted]
PHST- 2021/03/28 06:00 [pubmed]
PHST- 2021/05/28 06:00 [medline]
PHST- 2021/03/27 20:16 [entrez]
AID - S0045-6535(21)00775-X [pii]
AID - 10.1016/j.chemosphere.2021.130305 [doi]
PST - ppublish
SO  - Chemosphere. 2021 Aug;277:130305. doi: 10.1016/j.chemosphere.2021.130305. Epub 
      2021 Mar 17.