PMID- 33821354 OWN - NLM STAT- MEDLINE DCOM- 20210407 LR - 20210407 IS - 1573-2959 (Electronic) IS - 0167-6369 (Linking) VI - 193 IP - 5 DP - 2021 Apr 5 TI - Levels of polybrominated diphenyl ethers (PBDEs) in water and sediment from open city drains in Makurdi Metropolitan Area, North Central Nigeria. PG - 244 LID - 10.1007/s10661-021-09038-6 [doi] AB - Polybrominated diphenyl ethers (PBDEs) have been classified as persistent organic pollutants (POPs) as well as endocrine-disrupting compounds (EDCs). This study determined the concentrations of six PBDE congeners (BDE 47, BDE 99, BDE 100, BDE 153, BDE 154, and BDE 183) in water and sediment samples from open city drains, in the Makurdi Metropolitan Area, North Central Nigeria, using gas chromatogragh-mass spectrometer. These congeners are components of the penta- and octa-BDE formulations that have been banned by the European Union. The samples were collected from the drains, bi-monthly, for 1 year across dry and wet seasons. All the congeners considered were found to be present in both water and sediment. The levels of Sigma(6)PBDEs in water ranged from 0.05 to 0.28 ng L(-1) during dry season and 0.02 to 0.36 ng L(-1) during wet season, while their levels in sediment during dry and wet seasons ranged from 3.22 to 26.26 ng g(-1) and 7.51 to 27.41 ng g(-1), respectively. The percentage recoveries from solid phase and Soxhlet extractions ranged from 69 to 104% and 70 to 112%, respectively. It was concluded that the presence of all the congeners in both water and sediment posed a pollution risk to the river in which the drains discharge and require further monitoring and necessary preventive measures. FAU - Tongu, Sylvester M AU - Tongu SM AUID- ORCID: 0000-0003-4486-9149 AD - Department of Chemistry, Federal University of Agriculture Makurdi, PMB 2373, Benue State, Makurdi, Nigeria. tongusyl@gmail.com. FAU - Sha'Ato, Rufus AU - Sha'Ato R AD - Department of Chemistry, Federal University of Agriculture Makurdi, PMB 2373, Benue State, Makurdi, Nigeria. FAU - Okonkwo, Jonathan O AU - Okonkwo JO AD - Department of Environmental, Water and Earth Sciences, Tshwane University of Technology, Pretoria, 0001, South Africa. FAU - Olukunle, Olubiyi I AU - Olukunle OI AD - School of Public and Environmental Affairs , Indiana University, 702 N Walnut Grove Avenue, 47405, Bloomington, IN, USA. FAU - Tor-Anyiin, Terrumun A AU - Tor-Anyiin TA AD - Department of Chemistry, Federal University of Agriculture Makurdi, PMB 2373, Benue State, Makurdi, Nigeria. FAU - Eneji, Ishaq S AU - Eneji IS AD - Department of Chemistry, Federal University of Agriculture Makurdi, PMB 2373, Benue State, Makurdi, Nigeria. LA - eng GR - UAM/TETFund/IBR/VOL.1/Federal University of Agriculture, Makurdi, Nigeria/ PT - Journal Article DEP - 20210405 PL - Netherlands TA - Environ Monit Assess JT - Environmental monitoring and assessment JID - 8508350 RN - 0 (Halogenated Diphenyl Ethers) RN - 0 (Water Pollutants, Chemical) RN - 059QF0KO0R (Water) SB - IM MH - China MH - Cities MH - Environmental Monitoring MH - Geologic Sediments MH - *Halogenated Diphenyl Ethers/analysis MH - Nigeria MH - Water MH - *Water Pollutants, Chemical/analysis OTO - NOTNLM OT - City drains OT - Gas chromatograph-mass spectrometer OT - Polybrominated diphenyl ethers OT - Sediment EDAT- 2021/04/07 06:00 MHDA- 2021/04/10 06:00 CRDT- 2021/04/06 05:57 PHST- 2020/01/14 00:00 [received] PHST- 2021/03/29 00:00 [accepted] PHST- 2021/04/06 05:57 [entrez] PHST- 2021/04/07 06:00 [pubmed] PHST- 2021/04/10 06:00 [medline] AID - 10.1007/s10661-021-09038-6 [pii] AID - 10.1007/s10661-021-09038-6 [doi] PST - epublish SO - Environ Monit Assess. 2021 Apr 5;193(5):244. doi: 10.1007/s10661-021-09038-6.