PMID- 33887272 OWN - NLM STAT- MEDLINE DCOM- 20210630 LR - 20210630 IS - 1096-0953 (Electronic) IS - 0013-9351 (Linking) VI - 197 DP - 2021 Jun TI - Comprehensive determination of polychlorinated biphenyls and brominated flame retardants in surface sediment samples from Hanoi urban area, Vietnam: Contamination status, accumulation profiles, and potential ecological risks. PG - 111158 LID - S0013-9351(21)00452-7 [pii] LID - 10.1016/j.envres.2021.111158 [doi] AB - Comprehensive and updated information about polychlorinated biphenyls (PCBs) and brominated flame retardants (BFRs) in surface sediments from Hanoi, the capital city of Vietnam, is rather scarce. In this study, concentrations and profiles of 209 PCBs, 41 polybrominated diphenyl ethers (PBDEs), 2,2',4,4',5,5'-hexabromobiphenyl (BB-153), hexabromocyclododecane (HBCD), pentabromoethylbenzene (PBEB), 1,2-bis(2,4,6-tribromophenoxy)ethane (BTBPE), and decabromodiphenyl ethane (DBDPE) were determined in sediment samples collected from the Red River and some inner-city rivers of Hanoi. Concentrations (ng/g dry weight, median and range) of pollutants decreased in the order: DBDPE (28; not detected ND - 59) approximately PCBs (27; 1.7-50) > PBDEs (23; 0.20-61) > HBCD (1.2; ND - 5.2) > BTBPE (0.46; ND - 3.6) > BB-153 (0.004; ND - 0.014) > PBEB (ND). Pollutant levels in the inner-city river sediments were about one to two orders of magnitude higher than those measured in the Red River main stream sediments. Tri-to hexa-CBs are major homologs but detailed profiles vary between individual samples, reflecting source and/or seasonal variations. CB-11 and CB-209 were found at higher proportions in sediments than in technical PCB mixtures, suggesting their novel sources from pigments. Deca-BDE and DBDPE are the most predominant BFRs with an increasing trend predicted for DBDPE. A preliminary ecological risk assessment was conducted for these pollutants in sediments. Total PCBs and deca-BDE in a few inner-city river sediments may exhibit adverse effects on benthic organisms, but no serious risk was estimated in general. CI - Copyright (c) 2021 Elsevier Inc. All rights reserved. FAU - Hoang, Anh Quoc AU - Hoang AQ AD - Center of Advanced Technology for the Environment, Graduate School of Agriculture, Ehime University, 3-5-7 Tarumi, Matsuyama, 790-8566, Japan; Faculty of Chemistry, University of Science, Vietnam National University, Hanoi, 19 Le Thanh Tong, Hanoi, 10000, Viet Nam. Electronic address: hoangquocanh1990@gmail.com. FAU - Takahashi, Shin AU - Takahashi S AD - Center of Advanced Technology for the Environment, Graduate School of Agriculture, Ehime University, 3-5-7 Tarumi, Matsuyama, 790-8566, Japan. FAU - Da Le, Nhu AU - Da Le N AD - Laboratory of Environmental Chemistry, Institute of Natural Product Chemistry, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Hanoi, 10000, Viet Nam; Graduate University of Science and Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Hanoi, 10000, Viet Nam. FAU - Duong, Thi Thuy AU - Duong TT AD - Institute of Environmental Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Hanoi, 10000, Viet Nam. FAU - Huong Pham, Thi Mai AU - Huong Pham TM AD - Hanoi University of Industry, 298 Cau Dien, Hanoi, 10000, Viet Nam. FAU - Mai Pham, Thi Ngoc AU - Mai Pham TN AD - Faculty of Chemistry, University of Science, Vietnam National University, Hanoi, 19 Le Thanh Tong, Hanoi, 10000, Viet Nam. FAU - Huong Nguyen, Thi Anh AU - Huong Nguyen TA AD - Faculty of Chemistry, University of Science, Vietnam National University, Hanoi, 19 Le Thanh Tong, Hanoi, 10000, Viet Nam. FAU - Tran, Tri Manh AU - Tran TM AD - Faculty of Chemistry, University of Science, Vietnam National University, Hanoi, 19 Le Thanh Tong, Hanoi, 10000, Viet Nam. FAU - Tu, Minh Binh AU - Tu MB AD - Faculty of Chemistry, University of Science, Vietnam National University, Hanoi, 19 Le Thanh Tong, Hanoi, 10000, Viet Nam. FAU - Quynh Le, Thi Phuong AU - Quynh Le TP AD - Laboratory of Environmental Chemistry, Institute of Natural Product Chemistry, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Hanoi, 10000, Viet Nam; Graduate University of Science and Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Hanoi, 10000, Viet Nam. Electronic address: quynhltp@gmail.com. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20210420 PL - Netherlands TA - Environ Res JT - Environmental research JID - 0147621 RN - 0 (Flame Retardants) RN - 0 (Halogenated Diphenyl Ethers) RN - DFC2HB4I0K (Polychlorinated Biphenyls) SB - IM MH - Environmental Monitoring MH - *Flame Retardants/analysis MH - Halogenated Diphenyl Ethers/analysis MH - *Polychlorinated Biphenyls MH - Vietnam OTO - NOTNLM OT - BFRs OT - Developing country OT - PCBs OT - Sediment OT - Urban rivers EDAT- 2021/04/23 06:00 MHDA- 2021/07/01 06:00 CRDT- 2021/04/22 20:12 PHST- 2021/03/06 00:00 [received] PHST- 2021/04/04 00:00 [revised] PHST- 2021/04/07 00:00 [accepted] PHST- 2021/04/23 06:00 [pubmed] PHST- 2021/07/01 06:00 [medline] PHST- 2021/04/22 20:12 [entrez] AID - S0013-9351(21)00452-7 [pii] AID - 10.1016/j.envres.2021.111158 [doi] PST - ppublish SO - Environ Res. 2021 Jun;197:111158. doi: 10.1016/j.envres.2021.111158. Epub 2021 Apr 20.