PMID- 33893578 OWN - NLM STAT- MEDLINE DCOM- 20210826 LR - 20210826 IS - 1614-7499 (Electronic) IS - 0944-1344 (Linking) VI - 28 IP - 34 DP - 2021 Sep TI - Characteristics of tailpipe volatile halogenated hydrocarbon (VHC) emissions from in-use vehicles during real-world driving. PG - 47227-47238 LID - 10.1007/s11356-021-14078-z [doi] AB - Vehicular emissions have become a primary anthropogenic source of urban atmospheric volatile halogenated hydrocarbons (VHCs) with the rapid increase of vehicle population, while characteristics of the VHC emissions from different vehicles were rarely systematically investigated. In this study, the on-road tailpipe emissions were sampled from seven in-use vehicles, including two light-duty gasoline vehicles (LDGV), three light-duty diesel trucks (LDDT), one heavy-duty diesel truck (HDDT), and a liquefied petroleum gas-electric hybrid bus (LPGB), using a portable emission measurement system (PEMS) combined with summa canisters, and 35 individual VHC species were identified by a gas chromatography mass spectrometry detector (GC-MSD). Results showed that VHC emissions under urban driving conditions were much higher than those on the suburban roads and highways. The VHC emission factors of LDGV were 1.2 +/- 0.34 mg/km and 3.6 +/- 1.5, 6.8 +/- 0.89, and 1.6 +/- 0.28 mg/km for LDDT, HDDT, and LPGB, respectively. For the LDGV, chlorobenzene, 1,2-dichloroethane, and hexachlorobutadiene were the top three VHC species. 1,2-Dichloroethane, trichloromethane, and methyl chloride were the main VHC constituents in the LDDT. Chlorobenzene was the most abundant VOC species for the HDDT, followed by 1,2-dichloroethane and 1,4-dichlorobenzene. The major species for LPGB were 1,2,4-trichlorobenzene, carbon tetrachloride, and benzyl chloride. The major tailpipe VHC species obtained in this study were partial consistent with previous studies with different test methods. The results provide an initial evaluation of the tailpipe VHC emissions, which may provide experimental data support for the refined source apportionment of atmospheric VHCs and the control of vehicular VHCs. CI - (c) 2021. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature. FAU - Mei, Hui AU - Mei H AD - School of Ecology and Environment, Zhengzhou University, No. 100 Science Avenue, Zhengzhou, 450001, China. FAU - Wang, Menglei AU - Wang M AD - School of Ecology and Environment, Zhengzhou University, No. 100 Science Avenue, Zhengzhou, 450001, China. AD - School of Environment and Energy, South China University of Technology, Guangzhou, 510006, China. FAU - Jin, Boqiang AU - Jin B AD - School of Ecology and Environment, Zhengzhou University, No. 100 Science Avenue, Zhengzhou, 450001, China. FAU - Zhu, Rencheng AU - Zhu R AD - School of Ecology and Environment, Zhengzhou University, No. 100 Science Avenue, Zhengzhou, 450001, China. zhurc@zzu.edu.cn. FAU - Wang, Yunjing AU - Wang Y AD - State Environmental Protection Key Laboratory of Vehicle Emission Control and Simulation, Chinese Research Academy of Environmental Sciences, Beijing, 100012, China. FAU - Wang, Lulu AU - Wang L AD - School of Ecology and Environment, Zhengzhou University, No. 100 Science Avenue, Zhengzhou, 450001, China. FAU - Li, Shunyi AU - Li S AD - School of Ecology and Environment, Zhengzhou University, No. 100 Science Avenue, Zhengzhou, 450001, China. FAU - Zhang, Ruiqin AU - Zhang R AD - School of Ecology and Environment, Zhengzhou University, No. 100 Science Avenue, Zhengzhou, 450001, China. FAU - Bao, Xiaofeng AU - Bao X AD - State Environmental Protection Key Laboratory of Vehicle Emission Control and Simulation, Chinese Research Academy of Environmental Sciences, Beijing, 100012, China. LA - eng GR - 212102310524/Key Specialized Research and Development Program in Henan Province/ GR - 51808507/National Natural Science Foundation of China/ GR - 2017YFC0212400/National Key R&D Program of China/ GR - NELMS2018A16/National Engineering Laboratory for Mobile Source Emission Control Technology/ PT - Journal Article DEP - 20210423 PL - Germany TA - Environ Sci Pollut Res Int JT - Environmental science and pollution research international JID - 9441769 RN - 0 (Air Pollutants) RN - 0 (Gasoline) RN - 0 (Hydrocarbons, Halogenated) RN - 0 (Vehicle Emissions) SB - IM MH - *Air Pollutants/analysis MH - Environmental Monitoring MH - Gasoline/analysis MH - *Hydrocarbons, Halogenated MH - Motor Vehicles MH - Vehicle Emissions/analysis OTO - NOTNLM OT - Diesel vehicle OT - Emission factors OT - Gasoline vehicle OT - Liquefied petroleum gas-electric hybrid vehicle OT - Portable emission measurement system (PEMS) OT - Volatile halogenated hydrocarbons (VHCs) EDAT- 2021/04/25 06:00 MHDA- 2021/08/27 06:00 CRDT- 2021/04/24 06:13 PHST- 2020/11/05 00:00 [received] PHST- 2021/04/20 00:00 [accepted] PHST- 2021/04/25 06:00 [pubmed] PHST- 2021/08/27 06:00 [medline] PHST- 2021/04/24 06:13 [entrez] AID - 10.1007/s11356-021-14078-z [pii] AID - 10.1007/s11356-021-14078-z [doi] PST - ppublish SO - Environ Sci Pollut Res Int. 2021 Sep;28(34):47227-47238. doi: 10.1007/s11356-021-14078-z. Epub 2021 Apr 23.