PMID- 33918359 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20210502 IS - 1996-1944 (Print) IS - 1996-1944 (Electronic) IS - 1996-1944 (Linking) VI - 14 IP - 7 DP - 2021 Apr 2 TI - LDPE and HDPE Microplastics Differently Affect the Transport of Tetracycline in Saturated Porous Media. LID - 10.3390/ma14071757 [doi] LID - 1757 AB - The accumulation of microplastics (MPs) in soil and sediments may influence the penetration of contaminants into subsurface environments. However, little attention has been paid to comparing the different roles of two common polyethylene (PE) types-low-density polyethylene (LDPE) and high-density polyethylene (HDPE). In this study, the transport behaviors of tetracycline in saturated quartz sand columns in the presence and absence of these two MPs were investigated, respectively. The results showed that both types of PE MPs restrained the mobility of tetracycline at neutral conditions, while such detrimental effects were weak at acid and alkaline conditions. The degree of nonequilibrium adsorption was higher, and tetracycline transferred easier to the kinetic site for the existence of LDPE than of HDPE. The increased roughness and Brunauer-Emmett-Teller (BET) surface areas, more negative zeta potentials and the formation of oxygen function groups on the surface of MPs after UV-weathering intensified the retardation of tetracycline transport. This study revealed that the PE type and weathering should be taken into account in risk assessment, along with the solution chemistry. FAU - Hu, Enzhu AU - Hu E AUID- ORCID: 0000-0002-1514-6577 AD - Institute of Resources and Environmental Sciences, School of Metallurgy, Northeastern University, Shenyang 110819, China. FAU - Yuan, Hongbo AU - Yuan H AD - Institute of Resources and Environmental Sciences, School of Metallurgy, Northeastern University, Shenyang 110819, China. FAU - Du, Yichun AU - Du Y AD - Shaanxi Key Laboratory of Land Consolidation, Shaanxi Provincial Land Engineering Construction Group Co., Ltd., Chang'an University, Xi'an 710054, China. FAU - Chen, Xijuan AU - Chen X AUID- ORCID: 0000-0001-5856-6849 AD - Key Laboratory of Pollution Ecology and Environmental Engineering, Institute of Applied Ecology, Chinese Academy of Sciences, Shenyang 110016, China. LA - eng GR - 2018YFC1801200/National Key Research and Development Program of China/ GR - 2019-ZD02/Fund Project of Shaanxi Key Laboratory of Land Consolidation, China/ GR - N2025008/Fundamental Research Funds for the Central Universities/ PT - Journal Article DEP - 20210402 PL - Switzerland TA - Materials (Basel) JT - Materials (Basel, Switzerland) JID - 101555929 PMC - PMC8038232 OTO - NOTNLM OT - UV-weathering OT - microplastics OT - polyethylene OT - tetracycline OT - transport COIS- The authors declare no conflict of interest. EDAT- 2021/05/01 06:00 MHDA- 2021/05/01 06:01 PMCR- 2021/04/02 CRDT- 2021/04/30 01:09 PHST- 2021/03/07 00:00 [received] PHST- 2021/03/25 00:00 [revised] PHST- 2021/03/30 00:00 [accepted] PHST- 2021/04/30 01:09 [entrez] PHST- 2021/05/01 06:00 [pubmed] PHST- 2021/05/01 06:01 [medline] PHST- 2021/04/02 00:00 [pmc-release] AID - ma14071757 [pii] AID - materials-14-01757 [pii] AID - 10.3390/ma14071757 [doi] PST - epublish SO - Materials (Basel). 2021 Apr 2;14(7):1757. doi: 10.3390/ma14071757.