PMID- 33959329
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20230920
IS  - 2054-5703 (Print)
IS  - 2054-5703 (Electronic)
IS  - 2054-5703 (Linking)
VI  - 8
IP  - 3
DP  - 2021 Mar 10
TI  - Removal of bisphenol A from aqueous media using a highly selective adsorbent of 
      hybridization cyclodextrin with magnetic molecularly imprinted polymer.
PG  - 201604
LID - 10.1098/rsos.201604 [doi]
LID - 201604
AB  - In this study, a unique magnetic molecularly imprinted polymer (MMIP) adsorbent 
      towards bisphenol A (BPA) as a template molecule was developed by bulk 
      polymerization using beta-cyclodextrin (beta-CD) as a co-monomer with methacrylic acid 
      (MAA) to form MMIP MAA-betaCD as a new adsorbent. beta-CD was hybridized with MAA to 
      obtain water-compactible imprinting sites for the effective removal of BPA from 
      aqueous samples. Benzoyl peroxide and trimethylolpropane trimethacrylate were 
      used as the initiator and cross-linker, respectively. The adsorbents were 
      characterized by Fourier transform infrared spectroscopy, scanning electronic 
      microscopy, transmission electron microscopy, vibrating sample magnetometer, 
      Brunauer-Emmett-Teller and X-ray diffraction. (1)H nuclear magnetic resonance 
      spectroscopy was used to characterize the MAA-betaCD and BPA-MAA-betaCD complex. 
      Several parameters influencing the adsorption efficiency of BPA such as adsorbent 
      dosage, pH of sample solution, contact time, initial concentrations and 
      temperature as well as selectivity and reusability study have been evaluated. 
      MMIP MAA-betaCD showed significantly higher removal efficiency and selective binding 
      capacity towards BPA compared to MMIP MAA owing to its unique morphology with the 
      presence of beta-CD. The kinetics data can be well described by the pseudo 
      second-order kinetic and Freundlich isotherm and Halsey models best fitted the 
      isotherm data. The thermodynamic studies indicated that the adsorption reaction 
      was a spontaneous and exothermic process. Therefore, MMIP based on the hybrid 
      monomer of MAA-betaCD shows good potential of a new monomer in molecularly imprinted 
      polymer preparation and can be used as an effective adsorbent for the removal of 
      BPA from aqueous solutions.
CI  - (c) 2021 The Authors.
FAU - Mamman, S
AU  - Mamman S
AD  - School of Chemical Sciences, Universiti Sains Malaysia, 11800 Penang, Malaysia.
AD  - Faculty of Natural and Applied Sciences Department of Chemistry, Nasarawa State 
      University Keffi, PMB 1022 Keffi, Nasarawa, Nigeria.
FAU - Suah, F B M
AU  - Suah FBM
AD  - School of Chemical Sciences, Universiti Sains Malaysia, 11800 Penang, Malaysia.
FAU - Raaov, M
AU  - Raaov M
AD  - Department of Chemistry, Faculty of Science, Universiti Malaya, 50603 Kuala 
      Lumpur, Malaysia.
FAU - Mehamod, F S
AU  - Mehamod FS
AD  - Advanced Nano Materials (ANoMA) Research Group, School of Fundamental Science, 
      Universiti Malaysia Terengganu, 21030 Kuala Nerus, Terengganu, Malaysia.
FAU - Asman, S
AU  - Asman S
AD  - Department of Physics and Chemistry, Faculty of Applied Sciences and Technology, 
      Universiti Tun Hussein Onn Malaysia, UTHM Pagoh Campus, Pagoh Higher Education 
      Hub, 84600 Muar, Johor, Malaysia.
FAU - Zain, N N M
AU  - Zain NNM
AD  - Integrative Medicine Cluster, Advanced Medical and Dental Institute, Universiti 
      Sains Malaysia, 13200 Penang, Malaysia.
LA  - eng
SI  - figshare/10.6084/m9.figshare.c.5323499
SI  - Dryad/10.5061/dryad.8pk0p2nmc
PT  - Journal Article
DEP - 20210310
PL  - England
TA  - R Soc Open Sci
JT  - Royal Society open science
JID - 101647528
PMC - PMC8074973
OTO - NOTNLM
OT  - adsorption
OT  - bisphenol A
OT  - molecularly imprinted polymer
OT  - water samples
OT  - beta-cyclodextrin
EDAT- 2021/05/08 06:00
MHDA- 2021/05/08 06:01
PMCR- 2021/03/10
CRDT- 2021/05/07 07:12
PHST- 2021/05/07 07:12 [entrez]
PHST- 2021/05/08 06:00 [pubmed]
PHST- 2021/05/08 06:01 [medline]
PHST- 2021/03/10 00:00 [pmc-release]
AID - rsos201604 [pii]
AID - 10.1098/rsos.201604 [doi]
PST - epublish
SO  - R Soc Open Sci. 2021 Mar 10;8(3):201604. doi: 10.1098/rsos.201604.