PMID- 33964657 OWN - NLM STAT- MEDLINE DCOM- 20210616 LR - 20210616 IS - 1873-7072 (Electronic) IS - 0308-8146 (Linking) VI - 359 DP - 2021 Oct 15 TI - The dissipation behavior, household processing factor and risk assessment for cyenopyrafen residues in strawberry and mandarin fruits. PG - 129925 LID - S0308-8146(21)00931-6 [pii] LID - 10.1016/j.foodchem.2021.129925 [doi] AB - A modified QuEChERS method for determining cyenopyrafen in strawberries, mandarins and their processed products was established with a good linearity (R(2) > 0.9981), accuracy (recoveries of 83% to 111%) and precision (relative standard deviations of 0.9% to 14%). The limit of quantification (LOQ) was 0.01 mg/kg. Field results showed that the half-lives of cyenopyrafen were 6.8 and 11.8 d in strawberry and mandarin respectively, and that the final residues were within established maximum residue limits (MRLs). The household processing factors (PFs) for cyenopyrafen residues in strawberry and mandarin fruits were also studied: residues increased in strawberry jam (PF 1.51) and mandarin juice (1.31) but decreased in strawberries (0.58) and mandarin pulp (<0.17) after washing and peeling, respectively. A risk assessment showed that the risk from long-term dietary exposures to cyenopyrafen was 73.73%, indicating that consuming these products was unlikely to present a public health concern. CI - Copyright (c) 2021 Elsevier Ltd. All rights reserved. FAU - Li, Yanjie AU - Li Y AD - Ministry of Agriculture and Rural Affairs Key Laboratory for Pesticide Residue Detection, Institute of Agro-Products Safety and Nutrition, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021, China. FAU - Xu, Jiabin AU - Xu J AD - Ministry of Agriculture and Rural Affairs Key Laboratory for Pesticide Residue Detection, Institute of Agro-Products Safety and Nutrition, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021, China. FAU - Zhao, Xueping AU - Zhao X AD - Ministry of Agriculture and Rural Affairs Key Laboratory for Pesticide Residue Detection, Institute of Agro-Products Safety and Nutrition, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021, China. FAU - He, Hongmei AU - He H AD - Ministry of Agriculture and Rural Affairs Key Laboratory for Pesticide Residue Detection, Institute of Agro-Products Safety and Nutrition, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021, China. FAU - Zhang, Changpeng AU - Zhang C AD - Ministry of Agriculture and Rural Affairs Key Laboratory for Pesticide Residue Detection, Institute of Agro-Products Safety and Nutrition, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021, China. Electronic address: cpzhang1215@126.com. FAU - Zhang, Zhiheng AU - Zhang Z AD - Ministry of Agriculture and Rural Affairs Key Laboratory for Pesticide Residue Detection, Institute of Agro-Products Safety and Nutrition, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021, China. Electronic address: zhihengest@126.com. LA - eng PT - Journal Article DEP - 20210422 PL - England TA - Food Chem JT - Food chemistry JID - 7702639 RN - 0 (Pesticide Residues) RN - 0 (Pyrazoles) RN - 1S67W8BOU3 (cyenopyrafen) RN - MP1U0D42PE (Acrylonitrile) SB - IM MH - Acrylonitrile/*analogs & derivatives/analysis/chemistry MH - Citrus sinensis/*chemistry MH - Dietary Exposure MH - Fragaria/*chemistry MH - Fruit/*chemistry MH - Pesticide Residues/analysis/*chemistry MH - Pyrazoles/analysis/*chemistry MH - Risk Assessment OTO - NOTNLM OT - Cyenopyrafen OT - Cyenopyrafen (PubChem CID: 18772482). OT - Dissipation behavior OT - Mandarin OT - Processing factor OT - Risk assessment OT - Strawberry EDAT- 2021/05/09 06:00 MHDA- 2021/06/17 06:00 CRDT- 2021/05/08 20:21 PHST- 2020/10/29 00:00 [received] PHST- 2021/04/16 00:00 [revised] PHST- 2021/04/19 00:00 [accepted] PHST- 2021/05/09 06:00 [pubmed] PHST- 2021/06/17 06:00 [medline] PHST- 2021/05/08 20:21 [entrez] AID - S0308-8146(21)00931-6 [pii] AID - 10.1016/j.foodchem.2021.129925 [doi] PST - ppublish SO - Food Chem. 2021 Oct 15;359:129925. doi: 10.1016/j.foodchem.2021.129925. Epub 2021 Apr 22.