PMID- 33992004
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20210702
IS  - 1873-3336 (Electronic)
IS  - 0304-3894 (Linking)
VI  - 417
DP  - 2021 Sep 5
TI  - GO-Ti(3)C(2) two-dimensional heterojunction nanomaterial for anticorrosion 
      enhancement of epoxy zinc-rich coatings.
PG  - 126048
LID - S0304-3894(21)01012-8 [pii]
LID - 10.1016/j.jhazmat.2021.126048 [doi]
AB  - MXenes are a unique family of two-dimensional (2D) transition metal carbides 
      and/or nitrides, which have been proven useful for energy storage, water 
      purification, and biomedical applications. Herein, a kind of heterojunction 
      structure was designed by grafting highly conductive MXene (Ti(3)C(2)) on the 
      graphene oxide (GO) nanosheets， which was confirmed by Fourier transform infrared 
      (FT-IR) spectroscopy, X-ray photoelectronic spectroscopy (XPS) and Raman results. 
      Open circuit potential (OCP), electrochemical impedance spectroscopy (EIS) and 
      salt spray measurements corroborated that inclusion of 0.5 wt% Ti(3)C(2) or 
      GO-Ti(3)C(2) into epoxy zinc-rich coating (ZRC) effectively enhance the cathodic 
      protection capability. Additionally, superior corrosion resistance was achieved 
      by incorporation of GO-Ti(3)C(2) into ZRC since GO-Ti(3)C(2) in the coating 
      improved the utilization rate of zinc particles and GO provided barrier 
      protection for inhibiting the diffusion of corrosive agents. At the end of 
      immersion, R(c) value of ZRC/GO-Ti(3)C(2) coating was 3.047 x 10(4) Omega.cm(2), 
      which was one order of magnitude higher than that of ZRC coating. Scanning 
      electron microscope (SEM) and energy dispersive spectroscopy (EDS) measurements 
      demonstrated that ZRC/GO-Ti(3)C(2) coating exhibited lower speed of zinc 
      particles oxidation and intact steel substrate. Hence, ZRC/GO-Ti(3)C(2) coating 
      exhibited the optimal corrosion resistance among the four kinds of coatings.
CI  - Copyright (c) 2021 Elsevier B.V. All rights reserved.
FAU - Shen, Lu
AU  - Shen L
AD  - School of Materials Science and Engineering, Yancheng Institute of Technology, 
      Yancheng 224051, PR China.
FAU - Zhao, Wenjie
AU  - Zhao W
AD  - Key Laboratory of Marine Materials and Related Technologies, Ningbo Institute of 
      Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, 
      China. Electronic address: zhaowj@nimte.ac.cn.
FAU - Wang, Kui
AU  - Wang K
AD  - School of Materials Science and Engineering, Yancheng Institute of Technology, 
      Yancheng 224051, PR China.
FAU - Xu, Jianguang
AU  - Xu J
AD  - School of Materials Science and Engineering, Yancheng Institute of Technology, 
      Yancheng 224051, PR China.
LA  - eng
PT  - Journal Article
DEP - 20210507
PL  - Netherlands
TA  - J Hazard Mater
JT  - Journal of hazardous materials
JID - 9422688
SB  - IM
OTO - NOTNLM
OT  - Epoxy zinc-rich coating
OT  - GO-Ti(3)C(2)
OT  - Heterojunction nanomaterial
OT  - Synergistic enhancement
EDAT- 2021/05/16 06:00
MHDA- 2021/05/16 06:01
CRDT- 2021/05/15 20:27
PHST- 2021/02/01 00:00 [received]
PHST- 2021/05/01 00:00 [revised]
PHST- 2021/05/03 00:00 [accepted]
PHST- 2021/05/16 06:00 [pubmed]
PHST- 2021/05/16 06:01 [medline]
PHST- 2021/05/15 20:27 [entrez]
AID - S0304-3894(21)01012-8 [pii]
AID - 10.1016/j.jhazmat.2021.126048 [doi]
PST - ppublish
SO  - J Hazard Mater. 2021 Sep 5;417:126048. doi: 10.1016/j.jhazmat.2021.126048. Epub 
      2021 May 7.