PMID- 34060191
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20210727
IS  - 1521-3773 (Electronic)
IS  - 1433-7851 (Linking)
VI  - 60
IP  - 32
DP  - 2021 Aug 2
TI  - [o-C(5) H(4) NHOH](2) [I(7) O(18) (OH)]⋅3 H(2) O: An Organic-Inorganic Hybrid SHG 
      Material Featuring an [I(7) O(18) (OH)] infinity2- Branched Polyiodate Chain.
PG  - 17426-17429
LID - 10.1002/anie.202106335 [doi]
AB  - An organic-inorganic hybrid polyiodate, namely, [o-C(5) H(4) NHOH](2) [I(7) O(18) 
      (OH)]⋅3 H(2) O (I), featuring a novel branched polyiodate chain has been obtained 
      by evaporation method. [o-C(5) H(4) NHOH](2) [I(7) O(18) (OH)]⋅3 H(2) O (I) 
      crystalizes in the polar space group Ia and features an [I(7) O(18) (OH)] infinity2- 
      branched polyiodate chain in which [I(3) O(9) ](3-) trimers are grafted on the 
      same side of the one-dimensional (1D) chain based on [I(4) O(11) (OH)](3-) 
      tetramers. The asymmetric organic amine groups are beneficial to the 
      polymerization of iodate groups and inducing the formation of the 
      non-centrosymmetric (NCS) structure. Compound I exhibits a rather large 
      Second-Harmonic- Generation (SHG) signal of 8.5xKH(2) PO(4) (KDP) upon 1064 nm 
      laser radiation, a moderate band gap of 3.90 eV and a high 
      laser-induced-damage-threshold (LIDT) of 182.34 MW cm(-2) , hence it is a 
      promising new SHG material. The relationship between the structures of the 
      organic amine groups and the overall structures has been also analyzed.
CI  - (c) 2021 Wiley-VCH GmbH.
FAU - Chen, Qian-Qian
AU  - Chen QQ
AD  - State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the 
      Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, P. R. China.
AD  - University of Chinese Academy of Sciences, Beijing, 100039, P. R. China.
FAU - Hu, Chun-Li
AU  - Hu CL
AD  - State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the 
      Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, P. R. China.
FAU - Chen, Jin
AU  - Chen J
AD  - State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the 
      Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, P. R. China.
FAU - Li, Yi-Lin
AU  - Li YL
AD  - State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the 
      Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, P. R. China.
FAU - Li, Bing-Xuan
AU  - Li BX
AD  - State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the 
      Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, P. R. China.
FAU - Mao, Jiang-Gao
AU  - Mao JG
AUID- ORCID: 0000-0002-5101-8898
AD  - State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the 
      Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, P. R. China.
LA  - eng
GR  - 22031009/National Natural Science Foundation of China/
GR  - 21875248/National Natural Science Foundation of China/
GR  - 21921001/National Natural Science Foundation of China/
GR  - 21975256/National Natural Science Foundation of China/
GR  - XDB20000000/Strategic Priority Research Program of the Chinese Academy of 
      Sciences/
PT  - Journal Article
DEP - 20210630
PL  - Germany
TA  - Angew Chem Int Ed Engl
JT  - Angewandte Chemie (International ed. in English)
JID - 0370543
SB  - IM
OTO - NOTNLM
OT  - SHG material
OT  - [I7O18(OH)] infinity 2 - branched chain
OT  - asymmetric organic amine group
OT  - organic-inorganic hybrid polyiodate
OT  - theoretical calculations
EDAT- 2021/06/02 06:00
MHDA- 2021/06/02 06:01
CRDT- 2021/06/01 06:55
PHST- 2021/05/11 00:00 [received]
PHST- 2021/06/02 06:00 [pubmed]
PHST- 2021/06/02 06:01 [medline]
PHST- 2021/06/01 06:55 [entrez]
AID - 10.1002/anie.202106335 [doi]
PST - ppublish
SO  - Angew Chem Int Ed Engl. 2021 Aug 2;60(32):17426-17429. doi: 
      10.1002/anie.202106335. Epub 2021 Jun 30.