PMID- 34082205 OWN - NLM STAT- MEDLINE DCOM- 20210722 LR - 20210722 IS - 1879-1026 (Electronic) IS - 0048-9697 (Linking) VI - 789 DP - 2021 Oct 1 TI - Simultaneous sorption behaviors of UV filters on the virgin and aged micro-high-density polyethylene under environmental conditions. PG - 147979 LID - S0048-9697(21)03050-3 [pii] LID - 10.1016/j.scitotenv.2021.147979 [doi] AB - The simultaneous sorption behaviors of four analytes from the UV filters group, benzophenone (BPh), 4-methylbenzylidene camphor (4MBC), benzophenone 3 (BPh3), and benzophenone 2 (BPh2) on virgin and aged high-density polyethylene (HDPE) with a particle size of 125 mum in milliQ and river water were examined in this study. The aging processes of HDPE particles were carried out with the use of simulated sunlight. Conducted research revealed that the sorption of UV filters on HDPE particles follows pseudo-second-order kinetics. A Temkin isothermal model best described the adsorption process for 4BMC, BPh, BPh3, BPh2 on aged HDPE in river water, and 4MBC, BPh, BPh3 on virgin HDPE in milliQ water. The adsorption of BPh2 onto virgin MPs in milliQ water was consistent with the Langmuir isothermal model. Environmental conditions and physicochemical properties of analytes influenced the sorption mechanism between UV filters and MPs particles. It was observed that the main mechanisms responsible for the sorption of BPh, 4MBC, BPh3, and BPh2 on the surface of HDPE are hydrophobic interactions, that may change through the involvement of electrostatic interactions. CI - Copyright (c) 2021 The Author(s). Published by Elsevier B.V. All rights reserved. FAU - Kapelewska, Justyna AU - Kapelewska J AD - Department of Analytical and Inorganic Chemistry, Faculty of Chemistry, University of Bialystok, Ciolkowskiego 1K Street, 15-245 Bialystok, Poland. Electronic address: j.kapelewska@uwb.edu.pl. FAU - Klekotka, Urszula AU - Klekotka U AD - Department of Physical Chemistry, Faculty of Chemistry, University of Bialystok, Ciolkowskiego 1K Street, 15-245 Bialystok, Poland. FAU - Zadzilko, Ewa AU - Zadzilko E AD - Department of Analytical and Inorganic Chemistry, Faculty of Chemistry, University of Bialystok, Ciolkowskiego 1K Street, 15-245 Bialystok, Poland. FAU - Karpinska, Joanna AU - Karpinska J AD - Department of Analytical and Inorganic Chemistry, Faculty of Chemistry, University of Bialystok, Ciolkowskiego 1K Street, 15-245 Bialystok, Poland. LA - eng PT - Journal Article DEP - 20210524 PL - Netherlands TA - Sci Total Environ JT - The Science of the total environment JID - 0330500 RN - 0 (Plastics) RN - 0 (Water Pollutants, Chemical) RN - 9002-88-4 (Polyethylene) SB - IM MH - Adsorption MH - Hydrophobic and Hydrophilic Interactions MH - Plastics MH - *Polyethylene MH - *Water Pollutants, Chemical/analysis OTO - NOTNLM OT - Aged OT - Emerging contaminants OT - Kinetic OT - Micro-HDPE OT - Microplastics OT - Sorption OT - UV filters COIS- Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. EDAT- 2021/06/04 06:00 MHDA- 2021/07/23 06:00 CRDT- 2021/06/03 20:19 PHST- 2021/03/31 00:00 [received] PHST- 2021/05/14 00:00 [revised] PHST- 2021/05/19 00:00 [accepted] PHST- 2021/06/04 06:00 [pubmed] PHST- 2021/07/23 06:00 [medline] PHST- 2021/06/03 20:19 [entrez] AID - S0048-9697(21)03050-3 [pii] AID - 10.1016/j.scitotenv.2021.147979 [doi] PST - ppublish SO - Sci Total Environ. 2021 Oct 1;789:147979. doi: 10.1016/j.scitotenv.2021.147979. Epub 2021 May 24.