PMID- 34087558
OWN - NLM
STAT- MEDLINE
DCOM- 20210906
LR  - 20210906
IS  - 1879-1298 (Electronic)
IS  - 0045-6535 (Linking)
VI  - 282
DP  - 2021 Nov
TI  - Vanadium selenide decorated reduced graphene oxide nanocomposite: A co-active 
      catalyst for the detection of 2,4,6 - Trichlorophenol.
PG  - 130874
LID - S0045-6535(21)01345-X [pii]
LID - 10.1016/j.chemosphere.2021.130874 [doi]
AB  - Transition metal chalcogenides (TMCs) have great potential in diverse 
      electrochemical technologies owing to their unique characteristics. In the 
      present work, we portray the design and synthesis of Vanadium selenide 
      (V(2)Se(9))/reduced graphene oxide (rGO) forming a two-dimensional (2D) hybrid 
      nanocomposite via a simple hydrothermal method. The successfully synthesized 
      nanocomposite underwent in-depth surface and morphological characterizations by 
      XRD, Raman spectroscopy, XPS, TEM, STEM and its potential as an electro catalyst 
      was investigated by using glassy carbon electrode (GCE) for the detection of 
      2,4,6-trichlorophenol (TCP). The structural features favored a high charge 
      transfer ratio, high surface area as well as excellent conductivity and catalytic 
      activity. The V(2)Se(9)/rGO/GCE modified electrode showed a low charge transfer 
      resistance (R(ct)) of 54.057 Omega cm(2), a decent detection limit (LOD) of 35.07 nM 
      and a very high sensitivity of 22 muA muM(-1) cm(-2) in a working range of 
      0.001 muM-1150 muM. This is due to the active proton interaction, surface 
      enhancement, and positive synergistic effect between rGO and V(2)Se(9). The 
      proposed sensor has good detection potential in agricultural soil, river water, 
      fish, and beverage samples like wine and apple juice. The obtained results from 
      our investigation would elucidate the application of the catalyst in 
      electrochemical sensors.
CI  - Copyright (c) 2021 Elsevier Ltd. All rights reserved.
FAU - Hwa, Kuo-Yuan
AU  - Hwa KY
AD  - Graduate Institute of Organic and Polymeric Materials, National Taipei University 
      of Technology, Taipei, Taiwan; Department of Molecular Science and Engineering, 
      National Taipei University of Technology, Taipei, Taiwan; Center for Biomedical 
      Industry, National Taipei University of Technology, Taipei, Taiwan. Electronic 
      address: kyhwa@ntut.edu.tw.
FAU - Ganguly, Anindita
AU  - Ganguly A
AD  - Department of Molecular Science and Engineering, National Taipei University of 
      Technology, Taipei, Taiwan; International Graduate Program in Energy and 
      Optoelectronic Materials, National Taipei University of Technology, Taipei, 
      Taiwan.
FAU - Santhan, Aravindan
AU  - Santhan A
AD  - Department of Molecular Science and Engineering, National Taipei University of 
      Technology, Taipei, Taiwan; International Graduate Program in Energy and 
      Optoelectronic Materials, National Taipei University of Technology, Taipei, 
      Taiwan.
FAU - Kanna Sharma, Tata Sanjay
AU  - Kanna Sharma TS
AD  - Graduate Institute of Organic and Polymeric Materials, National Taipei University 
      of Technology, Taipei, Taiwan; Department of Molecular Science and Engineering, 
      National Taipei University of Technology, Taipei, Taiwan.
LA  - eng
PT  - Journal Article
DEP - 20210515
PL  - England
TA  - Chemosphere
JT  - Chemosphere
JID - 0320657
RN  - 0 (graphene oxide)
RN  - 00J9J9XKDE (Vanadium)
RN  - 7782-42-5 (Graphite)
SB  - IM
MH  - Animals
MH  - Electrodes
MH  - *Graphite
MH  - *Nanocomposites
MH  - Vanadium
OTO - NOTNLM
OT  - 2,4,6-Trichlorophenol
OT  - Hydrothermal synthesis
OT  - Reduced graphene oxide
OT  - Transition metal chalcogenides
EDAT- 2021/06/05 06:00
MHDA- 2021/09/07 06:00
CRDT- 2021/06/04 20:19
PHST- 2020/12/06 00:00 [received]
PHST- 2021/05/07 00:00 [revised]
PHST- 2021/05/10 00:00 [accepted]
PHST- 2021/06/05 06:00 [pubmed]
PHST- 2021/09/07 06:00 [medline]
PHST- 2021/06/04 20:19 [entrez]
AID - S0045-6535(21)01345-X [pii]
AID - 10.1016/j.chemosphere.2021.130874 [doi]
PST - ppublish
SO  - Chemosphere. 2021 Nov;282:130874. doi: 10.1016/j.chemosphere.2021.130874. Epub 
      2021 May 15.