PMID- 34096303
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20210623
LR  - 20210623
IS  - 1520-510X (Electronic)
IS  - 0020-1669 (Linking)
VI  - 60
IP  - 12
DP  - 2021 Jun 21
TI  - Zn(II)/Cd(II)-Based Metal-Organic Frameworks as Bifunctional Materials for Dye 
      Scavenging and Catalysis of Fructose/Glucose to 5-Hydroxymethylfurfural.
PG  - 9181-9191
LID - 10.1021/acs.inorgchem.1c01208 [doi]
AB  - Functional neutral metal-organic frameworks (MOFs) [M(5OH-IP)(L)](n) [M = 
      Zn(II) for ADES-4; Cd(II) for ADES-5; 5OH-IP = 5-hydroxyisophthalate; L = 
      (E)-N'-(pyridin-3-ylmethylene)nicotinohydrazide) have been synthesized by a 
      diffusion/conventional reflux/mechanochemical method and characterized by various 
      analytical techniques. Crystals were harvested by a diffusion method, and 
      single-crystal X-ray diffraction (SXRD) analysis revealed that an adjacent 
      [M(2)(COO)(2)](n) ladder chain generates isostructural two-dimensional network 
      motifs by doubly pillaring via L. The bulk-phase purity of ADES-4 and ADES-5 
      synthesized by a versatile synthetic approach has been recognized by the decent 
      match of powder X-ray diffraction patterns with the simulated one. Both ADES-4 
      and ADES-5 showed selective adsorption of cationic dyes methylene blue (MB), 
      methyl violet (MV), and rhodamine B (RhB) over anionic dye methyl orange (MO) 
      from water with good uptake and rapid adsorption. Utilization of ADES-4 as a 
      chromatographic column filler for adsorptive removal of individual cationic dyes 
      as well as a mixture of dyes has been demonstrated from the aqueous phase. 
      Interestingly, ADES-4 is reusable with good stability, and it showed a dye 
      desorption phenomenon in methanol. The probable mechanism of cationic dye removal 
      based on insight from structural information and plausible supramolecular 
      interactions has also been explored. Both MOFs also showed efficient catalytic 
      transformation of fructose and glucose into the high-value chemical intermediate 
      5-hydroxymethylfurfural of industrial significance.
FAU - Patel, Unnati
AU  - Patel U
AUID- ORCID: 0000-0002-9627-3921
AD  - Department of Chemical Sciences, P. D. Patel Institute of Applied Sciences, 
      Charotar University of Science and Technology (CHARUSAT), Changa 388 421, 
      Gujarat, India.
FAU - Parmar, Bhavesh
AU  - Parmar B
AUID- ORCID: 0000-0003-4263-7635
AD  - Analytical and Environmental Science Division and Centralized Instrument 
      Facility, CSIR-Central Salt and Marine Chemicals Research Institute, G. B. Marg, 
      Bhavnagar 364 002, Gujarat, India.
FAU - Dadhania, Abhishek
AU  - Dadhania A
AUID- ORCID: 0000-0003-4506-1125
AD  - Department of Chemical Sciences, P. D. Patel Institute of Applied Sciences, 
      Charotar University of Science and Technology (CHARUSAT), Changa 388 421, 
      Gujarat, India.
AD  - Analytical and Environmental Science Division and Centralized Instrument 
      Facility, CSIR-Central Salt and Marine Chemicals Research Institute, G. B. Marg, 
      Bhavnagar 364 002, Gujarat, India.
FAU - Suresh, Eringathodi
AU  - Suresh E
AUID- ORCID: 0000-0002-1934-6832
AD  - Analytical and Environmental Science Division and Centralized Instrument 
      Facility, CSIR-Central Salt and Marine Chemicals Research Institute, G. B. Marg, 
      Bhavnagar 364 002, Gujarat, India.
AD  - Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201 002, Uttar 
      Pradesh, India.
LA  - eng
PT  - Journal Article
DEP - 20210607
PL  - United States
TA  - Inorg Chem
JT  - Inorganic chemistry
JID - 0366543
SB  - IM
EDAT- 2021/06/08 06:00
MHDA- 2021/06/08 06:01
CRDT- 2021/06/07 08:44
PHST- 2021/06/08 06:00 [pubmed]
PHST- 2021/06/08 06:01 [medline]
PHST- 2021/06/07 08:44 [entrez]
AID - 10.1021/acs.inorgchem.1c01208 [doi]
PST - ppublish
SO  - Inorg Chem. 2021 Jun 21;60(12):9181-9191. doi: 10.1021/acs.inorgchem.1c01208. 
      Epub 2021 Jun 7.