PMID- 34138139
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20210624
IS  - 2150-5551 (Electronic)
IS  - 2311-6706 (Print)
IS  - 2150-5551 (Linking)
VI  - 12
IP  - 1
DP  - 2020 Jun 25
TI  - A Novel Strategy of In Situ Trimerization of Cyano Groups Between the 
      Ti(3)C(2)T(x) (MXene) Interlayers for High-Energy and High-Power Sodium-Ion 
      Capacitors.
PG  - 135
LID - 10.1007/s40820-020-00473-7 [doi]
LID - 135
AB  - 2D MXenes are attractive for energy storage applications because of their high 
      electronic conductivity. However, it is still highly challenging for improving 
      the sluggish sodium (Na)-ion transport kinetics within the MXenes interlayers. 
      Herein, a novel nitrogen-doped Ti(3)C(2)T(x) MXene was synthesized by introducing 
      the in situ polymeric sodium dicyanamide (Na-dca) to tune the complex 
      terminations and then utilized as intercalation-type pseudocapacitive anode of 
      Na-ion capacitors (NICs). The Na-dca can intercalate into the interlayers of 
      Ti(3)C(2)T(x) nanosheets and simultaneously form sodium tricyanomelaminate 
      (Na(3)TCM) by the catalyst-free trimerization. The as-prepared 
      Ti(3)C(2)T(x)/Na(3)TCM exhibits a high N-doping of 5.6 at.% in the form of strong 
      Ti-N bonding and stabilized triazine ring structure. Consequently, coupling 
      Ti(3)C(2)T(x)/Na(3)TCM anode with different mass of activated carbon cathodes, 
      the asymmetric MXene//carbon NICs are assembled. It is able to deliver high 
      energy density (97.6 Wh kg(-1)), high power output (16.5 kW kg(-1)), and 
      excellent cycling stability ( approximately  82.6% capacitance retention after 8000 cycles).
FAU - Liu, Siyang
AU  - Liu S
AD  - School of Materials Science and Engineering, State Key Laboratory of Fine 
      Chemicals, Key Laboratory of Energy Materials and Devices (Liaoning Province), 
      Dalian University of Technology, Dalian, 116024, People's Republic of China.
FAU - Hu, Fangyuan
AU  - Hu F
AD  - School of Materials Science and Engineering, State Key Laboratory of Fine 
      Chemicals, Key Laboratory of Energy Materials and Devices (Liaoning Province), 
      Dalian University of Technology, Dalian, 116024, People's Republic of China. 
      hufangyuan@dlut.edu.cn.
FAU - Shao, Wenlong
AU  - Shao W
AD  - State Key Laboratory of Fine Chemicals, Department of Polymer Science and 
      Engineering, Dalian University of Technology, Dalian, 116024, People's Republic 
      of China.
FAU - Zhang, Wenshu
AU  - Zhang W
AD  - School of Materials Science and Engineering, State Key Laboratory of Fine 
      Chemicals, Key Laboratory of Energy Materials and Devices (Liaoning Province), 
      Dalian University of Technology, Dalian, 116024, People's Republic of China.
FAU - Zhang, Tianpeng
AU  - Zhang T
AD  - School of Materials Science and Engineering, State Key Laboratory of Fine 
      Chemicals, Key Laboratory of Energy Materials and Devices (Liaoning Province), 
      Dalian University of Technology, Dalian, 116024, People's Republic of China.
FAU - Song, Ce
AU  - Song C
AD  - School of Mathematical Sciences, Dalian University of Technology, Dalian, 116024, 
      People's Republic of China.
FAU - Yao, Man
AU  - Yao M
AD  - School of Materials Science and Engineering, State Key Laboratory of Fine 
      Chemicals, Key Laboratory of Energy Materials and Devices (Liaoning Province), 
      Dalian University of Technology, Dalian, 116024, People's Republic of China.
FAU - Huang, Hao
AU  - Huang H
AD  - School of Materials Science and Engineering, State Key Laboratory of Fine 
      Chemicals, Key Laboratory of Energy Materials and Devices (Liaoning Province), 
      Dalian University of Technology, Dalian, 116024, People's Republic of China.
FAU - Jian, Xigao
AU  - Jian X
AD  - School of Materials Science and Engineering, State Key Laboratory of Fine 
      Chemicals, Key Laboratory of Energy Materials and Devices (Liaoning Province), 
      Dalian University of Technology, Dalian, 116024, People's Republic of China. 
      jian4616@dlut.edu.cn.
AD  - State Key Laboratory of Fine Chemicals, Department of Polymer Science and 
      Engineering, Dalian University of Technology, Dalian, 116024, People's Republic 
      of China. jian4616@dlut.edu.cn.
AD  - School of Mathematical Sciences, Dalian University of Technology, Dalian, 116024, 
      People's Republic of China. jian4616@dlut.edu.cn.
LA  - eng
PT  - Journal Article
DEP - 20200625
PL  - Germany
TA  - Nanomicro Lett
JT  - Nano-micro letters
JID - 101727940
PMC - PMC7770942
OTO - NOTNLM
OT  - Fast kinetics
OT  - MXene
OT  - Nitrogen doping
OT  - Sodium-ion capacitors
OT  - Triazine polymerization
EDAT- 2021/06/18 06:00
MHDA- 2021/06/18 06:01
PMCR- 2020/06/25
CRDT- 2021/06/17 12:44
PHST- 2020/03/31 00:00 [received]
PHST- 2020/06/08 00:00 [accepted]
PHST- 2021/06/17 12:44 [entrez]
PHST- 2021/06/18 06:00 [pubmed]
PHST- 2021/06/18 06:01 [medline]
PHST- 2020/06/25 00:00 [pmc-release]
AID - 10.1007/s40820-020-00473-7 [pii]
AID - 473 [pii]
AID - 10.1007/s40820-020-00473-7 [doi]
PST - epublish
SO  - Nanomicro Lett. 2020 Jun 25;12(1):135. doi: 10.1007/s40820-020-00473-7.