PMID- 34155496
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20210701
LR  - 20210701
IS  - 1463-9084 (Electronic)
IS  - 1463-9076 (Linking)
VI  - 23
IP  - 25
DP  - 2021 Jun 30
TI  - Entropic analysis of bistability and the general evolution criterion.
PG  - 14051-14063
LID - 10.1039/d1cp01236c [doi]
AB  - We present a detailed study of the entropy production, the entropy exchange and 
      the entropy balance for the Schlogl model of chemical bi-stability for both the 
      clamped and volumetric open-flow versions. The general evolution criterion (GEC) 
      is validated for the transitions from the unstable to the stable non-equilibrium 
      stationary states. The GEC is the sole theorem governing the temporal behavior of 
      the entropy production in non-equilibrium thermodynamics, and we find no evidence 
      for supporting a "principle" of maximum entropy production. We use stoichiometric 
      network analysis (SNA) to calculate the distribution of the entropy production 
      and the exchange entropy over the elementary flux modes of the clamped and 
      open-flow models, and aim to reveal the underlying mechanisms of dissipation and 
      entropy exchange.
FAU - Hochberg, David
AU  - Hochberg D
AUID- ORCID: 0000-0002-0411-019X
AD  - Department of Molecular Evolution, Centro de Astrobiologia (CSIC-INTA), Carretera 
      Ajalvir Kilometro 4, 28850 Torrejon de Ardoz, Madrid, Spain. 
      hochbergd@cab.inta-csic.es.
FAU - Ribo, Josep M
AU  - Ribo JM
AUID- ORCID: 0000-0001-6258-1726
AD  - Department of Organic and Inorganic Chemistry, Institute of Cosmos Science 
      (IEEC-UB), University of Barcelona, Barcelona, Catalonia, Spain. jmribo@ub.edu.
LA  - eng
PT  - Journal Article
PL  - England
TA  - Phys Chem Chem Phys
JT  - Physical chemistry chemical physics : PCCP
JID - 100888160
SB  - IM
EDAT- 2021/06/23 06:00
MHDA- 2021/06/23 06:01
CRDT- 2021/06/22 06:38
PHST- 2021/06/23 06:00 [pubmed]
PHST- 2021/06/23 06:01 [medline]
PHST- 2021/06/22 06:38 [entrez]
AID - 10.1039/d1cp01236c [doi]
PST - ppublish
SO  - Phys Chem Chem Phys. 2021 Jun 30;23(25):14051-14063. doi: 10.1039/d1cp01236c.