PMID- 34166861
OWN - NLM
STAT- MEDLINE
DCOM- 20210719
LR  - 20221207
IS  - 1873-3778 (Electronic)
IS  - 0021-9673 (Linking)
VI  - 1651
DP  - 2021 Aug 16
TI  - Fabrication of magnetic polydopamine@naphthyl microporous organic network 
      nanosphere for efficient extraction of hydroxylated polycyclic aromatic 
      hydrocarbons and p-nitrophenol from wastewater samples.
PG  - 462347
LID - S0021-9673(21)00471-4 [pii]
LID - 10.1016/j.chroma.2021.462347 [doi]
AB  - Herein, we report the fabrication of a novel, well-defined 
      core-double-shell-structured magnetic Fe(3)O(4)@polydopamine@naphthyl microporous 
      organic network (MON), Fe(3)O(4)@PDA@NMON, for the efficient magnetic extraction 
      of hydroxylated polycyclic aromatic hydrocarbons (OH-PAHs) and p-nitrophenol 
      (p-Npn) from wastewater samples. The hierarchical nanospheres were designed and 
      constructed with the Fe(3)O(4) nanoparticle core, the inner shell of a 
      polydopamine (PDA) layer, and the outer shell of a porous naphthyl MON (NMON) 
      coating, allowing efficient and synergistic extraction of OH-PAHs and p-Npn via 
      hydrophobic, hydrogen bonding, and pi-pi interactions. The Fe(3)O(4)@PDA@NMON 
      nanospheres were well characterized and employed as an efficient sorbent for 
      magnetic solid-phase extraction (MSPE) coupled with high performance liquid 
      chromatography (HPLC) for analyzing of OH-PAHs and p-Npn. Under optimal 
      conditions, the Fe(3)O(4)@PDA@NMON-based-MSPE-HPLC-UV method afforded wide linear 
      range (0.18-500 mug L(-1)), low limits of detection (0.070 mug L(-1) for p-Npn, 
      0.090 mug L(-1) for 2-OH-Nap, 0.090 mug L(-1) for 9-OH-Fluo and 0.055 mug L(-1) for 
      9-OH-Phe, respectively), large enrichment factors (92.6-98.4), good precisions 
      (intra-day and inter-day relative standard deviations (RSDs); <6.4%, n=6) and 
      less consumption of the adsorbent. Furthermore, trace OH-PAHs and p-Npn with 
      concentrations of 0.29-0.80 mug L(-1) were successfully detected in various 
      wastewater samples. Fe(3)O(4)@PDA@NMON also functioned as a good adsorbent to 
      enrich a wide scope of trace contaminants containing hydrogen bonding sites and 
      aromatic structures, highlighting the potential of functional MONs in sample 
      pretreatment.
CI  - Copyright (c) 2021 Elsevier B.V. All rights reserved.
FAU - He, Xin-Qiao
AU  - He XQ
AD  - College of Chemistry, Research Center for Analytical Sciences, Tianjin Key 
      Laboratory of Biosensing and Molecular Recognition, Nankai University, Tianjin 
      300071, China.
FAU - Cui, Yuan-Yuan
AU  - Cui YY
AD  - College of Chemistry, Research Center for Analytical Sciences, Tianjin Key 
      Laboratory of Biosensing and Molecular Recognition, Nankai University, Tianjin 
      300071, China.
FAU - Zhang, Yan
AU  - Zhang Y
AD  - College of Chemistry, Research Center for Analytical Sciences, Tianjin Key 
      Laboratory of Biosensing and Molecular Recognition, Nankai University, Tianjin 
      300071, China.
FAU - Yang, Cheng-Xiong
AU  - Yang CX
AD  - College of Chemistry, Research Center for Analytical Sciences, Tianjin Key 
      Laboratory of Biosensing and Molecular Recognition, Nankai University, Tianjin 
      300071, China. Electronic address: cxyang@nankai.edu.cn.
LA  - eng
PT  - Journal Article
DEP - 20210615
PL  - Netherlands
TA  - J Chromatogr A
JT  - Journal of chromatography. A
JID - 9318488
RN  - 0 (Indoles)
RN  - 0 (Nitrophenols)
RN  - 0 (Polycyclic Aromatic Hydrocarbons)
RN  - 0 (Polymers)
RN  - 0 (Waste Water)
RN  - 0 (polydopamine)
RN  - Y92ZL45L4R (4-nitrophenol)
SB  - IM
MH  - Chromatography, High Pressure Liquid
MH  - Hydrophobic and Hydrophilic Interactions
MH  - Indoles/*chemistry
MH  - Limit of Detection
MH  - Magnetic Phenomena
MH  - Nanospheres/*chemistry
MH  - Nitrophenols/analysis/*isolation & purification
MH  - Polycyclic Aromatic Hydrocarbons/analysis/*isolation & purification
MH  - Polymers/*chemistry
MH  - Porosity
MH  - Solid Phase Extraction/*methods
MH  - Wastewater/*chemistry
OTO - NOTNLM
OT  - Hydroxylated polycyclic aromatic hydrocarbons
OT  - Magnetic solid phase extraction
OT  - Microporous organic network
OT  - Polydopamine
COIS- Declaration of Competing Interest The authors declare that they have no known 
      competing financial interests or personal relationships that could have appeared 
      to influence the work reported in this paper.
EDAT- 2021/06/25 06:00
MHDA- 2021/07/20 06:00
CRDT- 2021/06/24 20:14
PHST- 2021/03/24 00:00 [received]
PHST- 2021/05/28 00:00 [revised]
PHST- 2021/06/08 00:00 [accepted]
PHST- 2021/06/25 06:00 [pubmed]
PHST- 2021/07/20 06:00 [medline]
PHST- 2021/06/24 20:14 [entrez]
AID - S0021-9673(21)00471-4 [pii]
AID - 10.1016/j.chroma.2021.462347 [doi]
PST - ppublish
SO  - J Chromatogr A. 2021 Aug 16;1651:462347. doi: 10.1016/j.chroma.2021.462347. Epub 
      2021 Jun 15.