PMID- 34204423 OWN - NLM STAT- MEDLINE DCOM- 20210713 LR - 20210713 IS - 1420-3049 (Electronic) IS - 1420-3049 (Linking) VI - 26 IP - 12 DP - 2021 Jun 17 TI - Application of Nano-Hydroxyapatite Derived from Oyster Shell in Fabricating Superhydrophobic Sponge for Efficient Oil/Water Separation. LID - 10.3390/molecules26123703 [doi] LID - 3703 AB - The exploration of nonhazardous nanoparticles to fabricate a template-driven superhydrophobic surface is of great ecological importance for oil/water separation in practice. In this work, nano-hydroxyapatite (nano-HAp) with good biocompatibility was easily developed from discarded oyster shells and well incorporated with polydimethylsiloxane (PDMS) to create a superhydrophobic surface on a polyurethane (PU) sponge using a facile solution-immersion method. The obtained nano-HAp coated PU (nano-HAp/PU) sponge exhibited both excellent oil/water selectivity with water contact angles of over 150 degrees and higher absorption capacity for various organic solvents and oils than the original PU sponge, which can be assigned to the nano-HAp coating surface with rough microstructures. Moreover, the superhydrophobic nano-HAp/PU sponge was found to be mechanically stable with no obvious decrease of oil recovery capacity from water in 10 cycles. This work presented that the oyster shell could be a promising alternative to superhydrophobic coatings, which was not only beneficial to oil-containing wastewater treatment, but also favorable for sustainable aquaculture. FAU - Liu, Chao AU - Liu C AD - Key Laboratory of Jiangxi Province for Persistant Pollutants Control and Resources Recycle, Nanchang Hangkong University, Nanchang 330063, China. FAU - Chen, Su-Hua AU - Chen SH AD - Key Laboratory of Jiangxi Province for Persistant Pollutants Control and Resources Recycle, Nanchang Hangkong University, Nanchang 330063, China. FAU - Yang-Zhou, Chi-Hao AU - Yang-Zhou CH AD - Key Laboratory of Jiangxi Province for Persistant Pollutants Control and Resources Recycle, Nanchang Hangkong University, Nanchang 330063, China. FAU - Zhang, Qiu-Gen AU - Zhang QG AD - Key Laboratory of Jiangxi Province for Persistant Pollutants Control and Resources Recycle, Nanchang Hangkong University, Nanchang 330063, China. FAU - Michael, Ruby N AU - Michael RN AUID- ORCID: 0000-0002-6478-8672 AD - School of Engineering and Built Environment, Griffith University, Nathan, QLD 4111, Australia. LA - eng GR - YC2019-S331/Graduate Innovation Foundation of Jiangxi Province, China/ GR - 20181BCB24006/Innovation Team Program of Jiangxi Province/ PT - Journal Article DEP - 20210617 PL - Switzerland TA - Molecules JT - Molecules (Basel, Switzerland) JID - 100964009 RN - 0 (Dimethylpolysiloxanes) RN - 0 (Oils) RN - 0 (Solvents) RN - 059QF0KO0R (Water) RN - 63148-62-9 (baysilon) RN - 91D9GV0Z28 (Durapatite) RN - H0G9379FGK (Calcium Carbonate) SB - IM MH - Animal Shells/*chemistry/metabolism MH - Animals MH - Calcium Carbonate/chemistry MH - Dimethylpolysiloxanes/chemistry MH - Durapatite/*chemistry/isolation & purification MH - Environmental Restoration and Remediation/*methods MH - Hydrophobic and Hydrophilic Interactions MH - Nanoparticles/chemistry MH - Oils/chemistry MH - Ostreidae/metabolism MH - Petroleum Pollution/analysis/prevention & control MH - Solvents MH - Surface Properties MH - Water/chemistry MH - Water Purification/methods PMC - PMC8235077 OTO - NOTNLM OT - PDMS OT - nano hydroxyapatite OT - oil/water separation OT - oyster shell OT - superhydrophobic sponge COIS- All of the authors have approved to submit the final version of the manuscript to your journal and are aware of, and accept responsibility for, the manuscript. Additionally, all the authors declare that there are no conflict of interest in the whole manuscript. EDAT- 2021/07/03 06:00 MHDA- 2021/07/14 06:00 PMCR- 2021/06/17 CRDT- 2021/07/02 01:20 PHST- 2021/04/23 00:00 [received] PHST- 2021/06/02 00:00 [revised] PHST- 2021/06/05 00:00 [accepted] PHST- 2021/07/02 01:20 [entrez] PHST- 2021/07/03 06:00 [pubmed] PHST- 2021/07/14 06:00 [medline] PHST- 2021/06/17 00:00 [pmc-release] AID - molecules26123703 [pii] AID - molecules-26-03703 [pii] AID - 10.3390/molecules26123703 [doi] PST - epublish SO - Molecules. 2021 Jun 17;26(12):3703. doi: 10.3390/molecules26123703.