PMID- 34209678 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20210727 IS - 2079-4991 (Print) IS - 2079-4991 (Electronic) IS - 2079-4991 (Linking) VI - 11 IP - 7 DP - 2021 Jun 29 TI - Characterizing and Optimizing Piezoelectric Response of ZnO Nanowire/PMMA Composite-Based Sensor. LID - 10.3390/nano11071712 [doi] LID - 1712 AB - Due to the outstanding coupling between piezoelectric and semiconducting properties of zinc oxide nanowires, ZnO NW-based structures have been demonstrating promising potential with respect to their applicability in piezoelectric, piezotronic and piezo-phototronic devices. Particularly considering their biocompatibility and biosafety for applications regarding implantable medical detection, this paper proposed a new concept of piezoelectric composite, i.e., one consisting of vertically aligned ZnO NW arrays and an insulating polymer matrix. First, the finite element method (FEM) was employed to drive optimization strategies through adjustment of the key parameters such as Young's modules and the dielectric constant of the dielectric constituents, together with the density and dimension of nanowire (NW) itself. Second, to investigate the functionality of each individual layer of composite, different designed structures were fabricated and characterized in terms of electrical and piezoelectric properties. Next, experimental and simulation tests were performed, indicating that the decreasing thickness of the top poly(methyl methacrylate) layer (PMMA) can substantially enhance the piezoelectric sensitivity of the ZnO NW composite. Besides the further benefit of no polarization being needed, our material has a comparable charge coefficient (d(33)) with respect to other lead-free alternatives (e.g., BaTiO(3)), confirming the high sensing abilities of the developed structure based on vertically aligned ZnO NW arrays. Finally, a time-varying model combining piezoelectricity and electric circuit modules was investigated in detail, giving rise to an estimation of the d(33) coefficient for ZnO NWs. Based on this study, the developed material is revealed to be highly promising in medical applications, particularly regarding the FFR technique, where coronary pressure can be measured through a piezoelectric sensor. FAU - Zhang, Xiaoting AU - Zhang X AD - Electrical Department, Ladoua Campus, University Lyon, INSA-Lyon, LGEF, EA682, F-69621 Villeurbanne, France. FAU - Villafuerte, Jose AU - Villafuerte J AUID- ORCID: 0000-0003-0207-1083 AD - University Grenoble Alpes (iCampus), CNRS, Grenoble INP, LMGP, NanoMAT Team, F-38000 Grenoble, France. AD - University Grenoble Alpes (iCampus), CNRS, Grenoble INP, Institute NEEL, F-38000 Grenoble, France. FAU - Consonni, Vincent AU - Consonni V AUID- ORCID: 0000-0003-0171-8746 AD - University Grenoble Alpes (iCampus), CNRS, Grenoble INP, LMGP, NanoMAT Team, F-38000 Grenoble, France. FAU - Capsal, Jean-Fabien AU - Capsal JF AUID- ORCID: 0000-0003-2904-8422 AD - Electrical Department, Ladoua Campus, University Lyon, INSA-Lyon, LGEF, EA682, F-69621 Villeurbanne, France. FAU - Cottinet, Pierre-Jean AU - Cottinet PJ AD - Electrical Department, Ladoua Campus, University Lyon, INSA-Lyon, LGEF, EA682, F-69621 Villeurbanne, France. FAU - Petit, Lionel AU - Petit L AD - Electrical Department, Ladoua Campus, University Lyon, INSA-Lyon, LGEF, EA682, F-69621 Villeurbanne, France. FAU - Le, Minh-Quyen AU - Le MQ AUID- ORCID: 0000-0001-5907-159X AD - Electrical Department, Ladoua Campus, University Lyon, INSA-Lyon, LGEF, EA682, F-69621 Villeurbanne, France. LA - eng PT - Journal Article DEP - 20210629 PL - Switzerland TA - Nanomaterials (Basel) JT - Nanomaterials (Basel, Switzerland) JID - 101610216 PMC - PMC8305847 OTO - NOTNLM OT - ZnO nanowires composite OT - electrical and piezoelectric characterizations OT - finite element method OT - medical application OT - piezoelectric sensor COIS- The authors have no conflict of interest to declare. EDAT- 2021/07/03 06:00 MHDA- 2021/07/03 06:01 PMCR- 2021/06/29 CRDT- 2021/07/02 01:39 PHST- 2021/05/24 00:00 [received] PHST- 2021/06/16 00:00 [revised] PHST- 2021/06/25 00:00 [accepted] PHST- 2021/07/02 01:39 [entrez] PHST- 2021/07/03 06:00 [pubmed] PHST- 2021/07/03 06:01 [medline] PHST- 2021/06/29 00:00 [pmc-release] AID - nano11071712 [pii] AID - nanomaterials-11-01712 [pii] AID - 10.3390/nano11071712 [doi] PST - epublish SO - Nanomaterials (Basel). 2021 Jun 29;11(7):1712. doi: 10.3390/nano11071712.