PMID- 34286975
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20210805
IS  - 1944-8252 (Electronic)
IS  - 1944-8244 (Linking)
VI  - 13
IP  - 30
DP  - 2021 Aug 4
TI  - Single-Metallic Thermoresponsive Coordination Network as a Dual-Parametric 
      Luminescent Thermometer.
PG  - 35905-35913
LID - 10.1021/acsami.1c07812 [doi]
AB  - The single-metallic coordination networks (CNs), simultaneously exhibiting 
      temperature-dependent lifetime (TDLT) and emission band shift (TDEBS), are 
      desirable for application in luminescent thermometers with high accuracy and 
      reliability in a large temperature range. Nonetheless, up to date, there are no 
      reports on such kinds of materials due to the lack of in-depth understanding of 
      the origin of TDLT and TDEBS at a molecule level, being critical for exploiting a 
      universal approach to design a dual-parametric CN phosphorescent thermometer 
      (CN-PT). Herein, we have constructed a thermoresponsive CN [Cu(2)(L1)Br(2)](infinity) 
      (IAM21-1, L1 = N(1),N(6)-di(pyridin-3-yl)adipamide) via a 
      flexible-ligand-implanted strategy. The TDLT and TDEBS properties of IAM21-1 
      enable it to be applied as a single-metallic dual-parametric CN-PT in 50-500 K, 
      which is the widest temperature range reported so far. The combination of 
      structure analysis and DFT calculations demonstrates that the redshift of the 
      emission band upon the decreasing temperature originates from the reversible 
      skeleton-shrinkage-triggered narrower band gap. This work has unveiled the origin 
      of TDLT and TDEBS properties and proposed an efficient strategy for designing 
      dual-parametric CN-PTs.
FAU - Thapa, Kedar Bahadur
AU  - Thapa KB
AUID- ORCID: 0000-0001-5252-6520
AD  - Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials 
      (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials 
      (SICAM), Nanjing Tech University (NanjingTech), 30 South Puzhu Road, Nanjing 
      211816, P.R. China.
FAU - Chen, Baojun
AU  - Chen B
AD  - Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials 
      (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials 
      (SICAM), Nanjing Tech University (NanjingTech), 30 South Puzhu Road, Nanjing 
      211816, P.R. China.
FAU - Bian, Li
AU  - Bian L
AD  - Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials 
      (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials 
      (SICAM), Nanjing Tech University (NanjingTech), 30 South Puzhu Road, Nanjing 
      211816, P.R. China.
FAU - Xu, Yixiu
AU  - Xu Y
AD  - Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials 
      (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials 
      (SICAM), Nanjing Tech University (NanjingTech), 30 South Puzhu Road, Nanjing 
      211816, P.R. China.
FAU - He, Jiangang
AU  - He J
AD  - Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials 
      (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials 
      (SICAM), Nanjing Tech University (NanjingTech), 30 South Puzhu Road, Nanjing 
      211816, P.R. China.
FAU - Huang, Wei
AU  - Huang W
AD  - Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials 
      (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials 
      (SICAM), Nanjing Tech University (NanjingTech), 30 South Puzhu Road, Nanjing 
      211816, P.R. China.
FAU - Ju, Qiang
AU  - Ju Q
AUID- ORCID: 0000-0002-8521-845X
AD  - Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials 
      (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials 
      (SICAM), Nanjing Tech University (NanjingTech), 30 South Puzhu Road, Nanjing 
      211816, P.R. China.
FAU - Fang, Zhenlan
AU  - Fang Z
AUID- ORCID: 0000-0001-5161-844X
AD  - Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials 
      (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials 
      (SICAM), Nanjing Tech University (NanjingTech), 30 South Puzhu Road, Nanjing 
      211816, P.R. China.
LA  - eng
PT  - Journal Article
DEP - 20210721
PL  - United States
TA  - ACS Appl Mater Interfaces
JT  - ACS applied materials & interfaces
JID - 101504991
SB  - IM
OTO - NOTNLM
OT  - coordination network
OT  - dual-parametric
OT  - luminescent thermometer
OT  - single-metallic
OT  - thermoresponsive
EDAT- 2021/07/22 06:00
MHDA- 2021/07/22 06:01
CRDT- 2021/07/21 12:32
PHST- 2021/07/22 06:00 [pubmed]
PHST- 2021/07/22 06:01 [medline]
PHST- 2021/07/21 12:32 [entrez]
AID - 10.1021/acsami.1c07812 [doi]
PST - ppublish
SO  - ACS Appl Mater Interfaces. 2021 Aug 4;13(30):35905-35913. doi: 
      10.1021/acsami.1c07812. Epub 2021 Jul 21.