PMID- 34337251 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20240403 IS - 2470-1343 (Electronic) IS - 2470-1343 (Linking) VI - 6 IP - 29 DP - 2021 Jul 27 TI - Deep-Sintered Copper Tracks for Thermal Oxidation Resistance Using Large Pulsed Electron Beam. PG - 19134-19143 LID - 10.1021/acsomega.1c02475 [doi] AB - Thermal oxidation resistance is an important property in printed electronics for sustaining electrical conductivity for long time and/or under harsh environments such as high temperature. This study reports the fabrication of copper nanoparticles (CuNPs)-based conductive tracks using large pulsed electron beam (LPEB) by irradiation on CuNPs to be sintered. With an acceleration voltage of 11 kV, the LPEB irradiation induced deep-sintering of CuNPs so that the sintered CuNPs exhibited bulk-like electrical conductivity. Consequently, the sintered Cu tracks maintained high electrical conductivity at 220 degrees C without using any thermal oxidation protection additive, such as silver, carbon nanotube, and graphene. In contrast, the films irradiated with an acceleration voltage of 8 kV and irradiated by intense pulsed light (IPL) showed fast oxidation characteristics and a corresponding reduction of electrical conductivities under high temperatures owing to a thin sintered layer. The performance of highly thermal oxidation-resistant Cu films sintered by LPEB irradiations was demonstrated through the device performance of a Joule heater. CI - (c) 2021 The Authors. Published by American Chemical Society. FAU - Hwang, Yunjae AU - Hwang Y AD - School of Mechanical and Nuclear Engineering, Ulsan National Institute of Science and Technology (UNIST), UNIST-gil 50, Eonyang-eup, Ulju-gun, Ulsan 44919, Republic of Korea. FAU - Kim, Jisoo AU - Kim J AUID- ORCID: 0000-0001-9540-2800 AD - Department of Advanced Science and Technology Convergence, Kyungpook National University (KNU), 2559, Gyeongsang-daero, Sangju-si, Gyeongsangbuk-do 37224, Republic of Korea. AD - Department of Precision Mechanical Engineering, Kyungpook National University (KNU), 2559, Gyeongsang-daero, Sangju-si, Gyeongsangbuk-do 37224, Republic of Korea. FAU - Yim, Changyong AU - Yim C AUID- ORCID: 0000-0001-5987-9580 AD - Department of Advanced Science and Technology Convergence, Kyungpook National University (KNU), 2559, Gyeongsang-daero, Sangju-si, Gyeongsangbuk-do 37224, Republic of Korea. AD - School of Nano & Materials Science and Engineering, Kyungpook National University (KNU), 2559, Gyeongsang-daero, Sangju-si, Gyeongsangbuk-do 37224, Republic of Korea. FAU - Park, Hyung Wook AU - Park HW AUID- ORCID: 0000-0002-7751-1402 AD - School of Mechanical and Nuclear Engineering, Ulsan National Institute of Science and Technology (UNIST), UNIST-gil 50, Eonyang-eup, Ulju-gun, Ulsan 44919, Republic of Korea. LA - eng PT - Journal Article DEP - 20210713 PL - United States TA - ACS Omega JT - ACS omega JID - 101691658 PMC - PMC8320104 COIS- The authors declare no competing financial interest. EDAT- 2021/08/03 06:00 MHDA- 2021/08/03 06:01 PMCR- 2021/07/13 CRDT- 2021/08/02 06:12 PHST- 2021/05/11 00:00 [received] PHST- 2021/07/01 00:00 [accepted] PHST- 2021/08/02 06:12 [entrez] PHST- 2021/08/03 06:00 [pubmed] PHST- 2021/08/03 06:01 [medline] PHST- 2021/07/13 00:00 [pmc-release] AID - 10.1021/acsomega.1c02475 [doi] PST - epublish SO - ACS Omega. 2021 Jul 13;6(29):19134-19143. doi: 10.1021/acsomega.1c02475. eCollection 2021 Jul 27.