PMID- 34420742
OWN - NLM
STAT- MEDLINE
DCOM- 20220106
LR  - 20220106
IS  - 1879-1344 (Electronic)
IS  - 0144-8617 (Linking)
VI  - 272
DP  - 2021 Nov 15
TI  - Graft copolymer of sodium carboxymethyl cellulose and polyether polyol 
      (CMC-g-TMN-450) improves the crosslinking degree of polyurethane for coated 
      fertilizers with enhanced controlled release characteristics.
PG  - 118483
LID - S0144-8617(21)00870-5 [pii]
LID - 10.1016/j.carbpol.2021.118483 [doi]
AB  - Novel superhydrophobic sodium carboxymethyl cellulose (CMC) modified polyurethane 
      (MPU) was developed as the membrane material for controlled-release fertilizer 
      (CRF) by cross-linking polymerization of 4,4'-diphenylmethane diisocyanate (MDI) 
      and CMC-based modified polyol (CMP) which was made by grafting CMC onto polyether 
      polyol (TMN-450). The modified polyurethane coated fertilizer (MPUCF) was 
      prepared by using MPU as the membrane material through a fluidized bed device. 
      Analysis results of (13)C NMR showed that the coatings of PUCF and MPUCF were 
      prepared by connecting hydroxyl to isocyanate groups to form a carbamate. MPU had 
      lower water absorption rates than PU, and MPUCF coating showed excellent 
      hydrophobicity. Scanning electron microscope (SEM) revealed that MPUCF coating 
      surface was much more smooth and flat than that of PUCF. Furthermore, the 
      nitrogen (N) release longevity of MPUCF can increased to 140 days when the 
      coating rate was 5%. It is concluded that MPU was an excellent superhydrophobic 
      coating material for CRF.
CI  - Copyright (c) 2021 Elsevier Ltd. All rights reserved.
FAU - Wang, Yang
AU  - Wang Y
AD  - Department of Basic Courses, Shanxi Agricultural University (Shanxi Academy of 
      Agricultural Sciences), Taigu, Shanxi 030801, China.
FAU - Sun, Mingxue
AU  - Sun M
AD  - Key Laboratory of Plant Nutrition and Fertilizer, Ministry of Agriculture and 
      Rural Affairs/Institute of Agricultural Resources and Regional Planning, Chinese 
      Academy of Agricultural Sciences, Beijing 100081, China.
FAU - Qiao, Dan
AU  - Qiao D
AD  - Key Laboratory of Plant Nutrition and Fertilizer, Ministry of Agriculture and 
      Rural Affairs/Institute of Agricultural Resources and Regional Planning, Chinese 
      Academy of Agricultural Sciences, Beijing 100081, China.
FAU - Li, Juan
AU  - Li J
AD  - Key Laboratory of Plant Nutrition and Fertilizer, Ministry of Agriculture and 
      Rural Affairs/Institute of Agricultural Resources and Regional Planning, Chinese 
      Academy of Agricultural Sciences, Beijing 100081, China.
FAU - Wang, Yajing
AU  - Wang Y
AD  - Key Laboratory of Plant Nutrition and Fertilizer, Ministry of Agriculture and 
      Rural Affairs/Institute of Agricultural Resources and Regional Planning, Chinese 
      Academy of Agricultural Sciences, Beijing 100081, China.
FAU - Liu, Weiyi
AU  - Liu W
AD  - Faculty of Agriculture and Life Sciences, Lincoln University, PO Box 85084, 
      Lincoln 7608, New Zealand.
FAU - Bunt, Craig
AU  - Bunt C
AD  - Faculty of Agriculture and Life Sciences, Lincoln University, PO Box 85084, 
      Lincoln 7608, New Zealand.
FAU - Liu, Hongxia
AU  - Liu H
AD  - Department of Basic Courses, Shanxi Agricultural University (Shanxi Academy of 
      Agricultural Sciences), Taigu, Shanxi 030801, China.
FAU - Liu, Jinlong
AU  - Liu J
AD  - Department of Basic Courses, Shanxi Agricultural University (Shanxi Academy of 
      Agricultural Sciences), Taigu, Shanxi 030801, China. Electronic address: 
      liujinlong@sxau.edu.cn.
FAU - Yang, Xiangdong
AU  - Yang X
AD  - Key Laboratory of Plant Nutrition and Fertilizer, Ministry of Agriculture and 
      Rural Affairs/Institute of Agricultural Resources and Regional Planning, Chinese 
      Academy of Agricultural Sciences, Beijing 100081, China. Electronic address: 
      yangxiangdong@caas.cn.
LA  - eng
PT  - Journal Article
DEP - 20210730
PL  - England
TA  - Carbohydr Polym
JT  - Carbohydrate polymers
JID - 8307156
RN  - 0 (Fertilizers)
RN  - 0 (Isocyanates)
RN  - 0 (Polymers)
RN  - 0 (Polyurethanes)
RN  - 0 (polyol)
RN  - 059QF0KO0R (Water)
RN  - B0LO6BBS8C (4,4'-diphenylmethane diisocyanate)
RN  - K679OBS311 (Carboxymethylcellulose Sodium)
SB  - IM
MH  - Carboxymethylcellulose Sodium
MH  - *Fertilizers
MH  - Hydrophobic and Hydrophilic Interactions
MH  - Isocyanates
MH  - *Polymers
MH  - Polyurethanes
MH  - Water/chemistry
OTO - NOTNLM
OT  - Controlled-release fertilizer
OT  - Modified polyurethane
OT  - Release characteristics
OT  - Sodium carboxymethyl cellulose
OT  - Superhydrophobic coating material
EDAT- 2021/08/24 06:00
MHDA- 2022/01/07 06:00
CRDT- 2021/08/23 05:37
PHST- 2021/05/31 00:00 [received]
PHST- 2021/07/16 00:00 [revised]
PHST- 2021/07/21 00:00 [accepted]
PHST- 2021/08/23 05:37 [entrez]
PHST- 2021/08/24 06:00 [pubmed]
PHST- 2022/01/07 06:00 [medline]
AID - S0144-8617(21)00870-5 [pii]
AID - 10.1016/j.carbpol.2021.118483 [doi]
PST - ppublish
SO  - Carbohydr Polym. 2021 Nov 15;272:118483. doi: 10.1016/j.carbpol.2021.118483. Epub 
      2021 Jul 30.