PMID- 34443068 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20210831 IS - 1996-1944 (Print) IS - 1996-1944 (Electronic) IS - 1996-1944 (Linking) VI - 14 IP - 16 DP - 2021 Aug 13 TI - Functional and Antioxidant Properties of Plastic Bottle Caps Incorporated with BHA or BHT. LID - 10.3390/ma14164545 [doi] LID - 4545 AB - In this study, we prepared new antioxidant active plastic bottle caps by incorporating butylated hydroxyanisole (BHA) or butylated hydroxytoluene (BHT) and 2% (w/w) white masterbatch in high-density polyethylene (HDPE). Fourier-transform infrared (FT-IR) spectrometry revealed that the antioxidants and HDPE were uniformly mixed with noncovalent bonding. In addition, the differential scanning calorimetry (DSC) test revealed that the change in melting point and initial extrapolation temperature of the antioxidant active caps was not significant. Sensory evaluation and removal torque tests validated the suitability of the antioxidant active plastic bottle caps in industrial application. The antioxidant activity increased with a greater concentration of BHA and BHT incorporated in both antioxidant active caps (p < 0.05) and with more impact on the BHA cap compared to BHT cap in terms of antioxidant activity. Migration experiments for 10 days at 40 degrees C and 2 h at 70 degrees C showed that active antioxidants in the plastic bottle cap were more easily released into fatty foods and milk products that are highly sensitive to oxidation, and the migration of BHA and BHT did not exceed the maximum amount specified in (EC) No 1333/2008 (<200 mg/kg). As such, the antioxidant active plastic bottle caps inhibited oxidation, thereby ensuring higher food quality. FAU - Wang, Yu-Wen AU - Wang YW AD - Department of Mechanical Engineering, Wuhan Polytechnic University, Wuhan 430023, China. FAU - Li, Ya-Na AU - Li YN AD - Department of Mechanical Engineering, Wuhan Polytechnic University, Wuhan 430023, China. FAU - Lin, Qin-Bao AU - Lin QB AD - Packaging Engineering Institute, Jinan University, Zhuhai 519070, China. FAU - Wang, Xiao AU - Wang X AD - Department of Mechanical Engineering, Wuhan Polytechnic University, Wuhan 430023, China. FAU - Li, Zeng-Hui AU - Li ZH AD - Department of Mechanical Engineering, Wuhan Polytechnic University, Wuhan 430023, China. FAU - Wu, Kai-Xuan AU - Wu KX AD - Department of Mechanical Engineering, Wuhan Polytechnic University, Wuhan 430023, China. LA - eng PT - Journal Article DEP - 20210813 PL - Switzerland TA - Materials (Basel) JT - Materials (Basel, Switzerland) JID - 101555929 PMC - PMC8400316 OTO - NOTNLM OT - HPLC OT - antioxidant OT - high-density polyethylene OT - migration OT - plastic bottle caps COIS- The authors declare no conflict of interest. EDAT- 2021/08/28 06:00 MHDA- 2021/08/28 06:01 PMCR- 2021/08/13 CRDT- 2021/08/27 01:14 PHST- 2021/07/12 00:00 [received] PHST- 2021/08/08 00:00 [revised] PHST- 2021/08/09 00:00 [accepted] PHST- 2021/08/27 01:14 [entrez] PHST- 2021/08/28 06:00 [pubmed] PHST- 2021/08/28 06:01 [medline] PHST- 2021/08/13 00:00 [pmc-release] AID - ma14164545 [pii] AID - materials-14-04545 [pii] AID - 10.3390/ma14164545 [doi] PST - epublish SO - Materials (Basel). 2021 Aug 13;14(16):4545. doi: 10.3390/ma14164545.