PMID- 34517674
OWN - NLM
STAT- MEDLINE
DCOM- 20210915
LR  - 20210915
IS  - 1873-3573 (Electronic)
IS  - 0039-9140 (Linking)
VI  - 235
DP  - 2021 Dec 1
TI  - Fabrication of stable multivariate metal-organic frameworks with excellent 
      adsorption performance toward bisphenols from environmental samples.
PG  - 122818
LID - S0039-9140(21)00739-6 [pii]
LID - 10.1016/j.talanta.2021.122818 [doi]
AB  - As a type of environmental endocrine disrupting chemicals, bisphenols (BPs) have 
      a certain embryonic toxicity and teratogenicity, which can significantly increase 
      the risks of breast cancer, prostate cancer, leukemia and other cancers. In this 
      work, stable multivariate metal-organic frameworks (UiO-66-NH(2)/TCPP(x)) were 
      synthesized via in situ one-pot method and used as miniaturized dispersive 
      solid-phase extraction (dmuSPE) sorbents for extraction of trace BPs from 
      environmental samples. The phase purity, crystal morphology and physical 
      properties of UiO-66-NH(2)/TCPP(x) samples were varied by adjusting the mass 
      ratio of TCPP. The extraction performance of UiO-66-NH(2)/TCPP(x) samples were 
      investigated and UiO-66-NH(2)/TCPP(1.0) exhibited the highest adsorption 
      efficiency. Besides, UiO-66-NH(2)/TCPP(1.0) possessed excellent recycling 
      stability for the adsorption and desorption of BPs more than 20 cycles. The 
      experimental parameters including amount of adsorbent, adsorption time, sample 
      solution pH, temperature, desorption time and desorption solvents which affecting 
      the efficiency of dmuSPE were studied, respectively. Good linearity 
      (R(2) > 0.9992) in range of 0.1-200 ng mL(-1) was obtained. The detection limits 
      (S/N = 3) and quantification limits (S/N = 10) were achieved at 
      0.03-0.08 ng mL(-1) and 0.1-0.5 ng mL(-1), respectively. The relative standard 
      deviations (RSDs) of intra-day and inter-day ranged from 2.5 to 5.5% and 
      1.1-6.8%. Enrichment factors were calculated in the range of 303-338. The 
      obtained recoveries of bisphenol F (BPF), bisphenol A (BPA), bisphenol B (BPB) 
      and bisphenol AF (BPAF) were 81.26-91.03% (RSDs = 0.96-6.47%), 82.2-97.27% 
      (RSDs = 0.45-6.15%), 87.56-97.26% (RSDs = 1.1-6.22%) and 82.2-100.8% 
      (RSDs = 0.46-4.07%). The UiO-66-NH(2)/TCPP(1.0) can be employed as potential 
      dmuSPE sorbents for the enrichment of trace BPs in the environmental samples.
CI  - Copyright (c) 2021 Elsevier B.V. All rights reserved.
FAU - Han, Lizhen
AU  - Han L
AD  - College of Chemistry and Chemical Engineering, Henan University, Kaifeng, 475004, 
      Henan, China.
FAU - Zhang, Xiaowan
AU  - Zhang X
AD  - College of Chemistry and Chemical Engineering, Henan University, Kaifeng, 475004, 
      Henan, China.
FAU - Li, Dan
AU  - Li D
AD  - College of Chemistry and Chemical Engineering, Henan University, Kaifeng, 475004, 
      Henan, China.
FAU - Li, Mengyuan
AU  - Li M
AD  - College of Chemistry and Chemical Engineering, Henan University, Kaifeng, 475004, 
      Henan, China.
FAU - Qin, Peige
AU  - Qin P
AD  - College of Chemistry and Chemical Engineering, Henan University, Kaifeng, 475004, 
      Henan, China.
FAU - Tian, Shufang
AU  - Tian S
AD  - College of Chemistry and Chemical Engineering, Henan University, Kaifeng, 475004, 
      Henan, China. Electronic address: tianshufang@henu.edu.cn.
FAU - Wang, Youmei
AU  - Wang Y
AD  - College of Chemistry and Chemical Engineering, Henan University, Kaifeng, 475004, 
      Henan, China.
FAU - Lu, Minghua
AU  - Lu M
AD  - College of Chemistry and Chemical Engineering, Henan University, Kaifeng, 475004, 
      Henan, China. Electronic address: mhlu@henu.edu.cn.
FAU - Cai, Zongwei
AU  - Cai Z
AD  - State Key Laboratory of Environmental and Biological Analysis, Department of 
      Chemistry, Hong Kong Baptist University, Hong Kong, China.
LA  - eng
PT  - Journal Article
DEP - 20210821
PL  - Netherlands
TA  - Talanta
JT  - Talanta
JID - 2984816R
RN  - 0 (Benzhydryl Compounds)
RN  - 0 (Metal-Organic Frameworks)
RN  - 0 (Phenols)
RN  - 0 (Solvents)
RN  - MLT3645I99 (bisphenol A)
SB  - IM
MH  - Adsorption
MH  - Benzhydryl Compounds
MH  - Humans
MH  - Male
MH  - *Metal-Organic Frameworks
MH  - Phenols
MH  - Solid Phase Extraction
MH  - Solvents
OTO - NOTNLM
OT  - Bisphenols (BPs)
OT  - Metal-organic framework (MOF)
OT  - Miniaturized dispersive solid-phase extraction (dmuSPE)
OT  - Multivariate metal-organic frameworks
OT  - UiO-66-NH(2)/TCPP
EDAT- 2021/09/15 06:00
MHDA- 2021/09/16 06:00
CRDT- 2021/09/14 01:02
PHST- 2021/07/05 00:00 [received]
PHST- 2021/08/18 00:00 [revised]
PHST- 2021/08/19 00:00 [accepted]
PHST- 2021/09/14 01:02 [entrez]
PHST- 2021/09/15 06:00 [pubmed]
PHST- 2021/09/16 06:00 [medline]
AID - S0039-9140(21)00739-6 [pii]
AID - 10.1016/j.talanta.2021.122818 [doi]
PST - ppublish
SO  - Talanta. 2021 Dec 1;235:122818. doi: 10.1016/j.talanta.2021.122818. Epub 2021 Aug 
      21.