PMID- 34578687 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20211001 IS - 2079-4991 (Print) IS - 2079-4991 (Electronic) IS - 2079-4991 (Linking) VI - 11 IP - 9 DP - 2021 Sep 12 TI - Intelligent Temperature-Control of Drilling Fluid in Natural Gas Hydrate Formation by Nano-Silica/Modified n-Alkane Microcapsules. LID - 10.3390/nano11092370 [doi] LID - 2370 AB - Inhibiting hydrate decomposition due to the friction heat generated by the drilling tools is one of the key factors for drilling hydrate formation. Since the existing method based on chemical inhibition technology can only delay the hydrate decomposition rate, a phase-change microcapsule was introduced in this paper to inhibit, by the intelligent control of the drilling fluid temperature, the decomposition of the formation hydrate, which was microencapsulated by modified n-alkane as the core material, and nano-silica was taken as the shell material. Scanning electron microscope (SEM), size distribution, X-ray diffraction (XRD), and Fourier transform infrared spectrometer (FT-IR) were utilized to characterize the structural properties of microcapsules. Differential scanning calorimetry (DSC) spectra displayed that the latent heat was 136.8 J/g in the case of melting enthalpy and 136.4 J/g in the case of solidification enthalpy, with an encapsulation efficiency of 62.6%. In addition, the prepared microcapsules also showed good thermal conductivity and reliability. By comparison, it was also proved that the microcapsules had good compatibility with drilling fluid, which can effectively control the temperature of drilling fluid for the inhibition of hydrate decomposition. FAU - Zhang, Yubin AU - Zhang Y AUID- ORCID: 0000-0003-3725-2351 AD - School of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, China. FAU - Qiu, Zhengsong AU - Qiu Z AD - School of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, China. FAU - Mu, Jiaxing AU - Mu J AD - School of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, China. FAU - Ma, Yongle AU - Ma Y AD - Drilling Technology Research and Development Center, Bo-Xing Division of CNPC Offshore Engineering Company Limited, Tianjin 300451, China. FAU - Zhao, Xin AU - Zhao X AD - School of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, China. FAU - Zhong, Hanyi AU - Zhong H AD - School of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, China. FAU - Huang, Weian AU - Huang W AD - School of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, China. FAU - Guo, Pengfei AU - Guo P AD - School of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, China. LA - eng GR - National Natural Science Foundation of China (Major Program, 51991363)/Zhengsong Qiu/ GR - CNPC's Major Science and Technology Projects (ZD2019-184-003)/Zhengsong Qiu/ GR - National Natural Science Foundation of China (51804331)/Xin Zhao/ GR - Postgraduate Innovation Projects (YCX2020030)/Yubin Zhang/ PT - Journal Article DEP - 20210912 PL - Switzerland TA - Nanomaterials (Basel) JT - Nanomaterials (Basel, Switzerland) JID - 101610216 PMC - PMC8465599 OTO - NOTNLM OT - hydrate formation OT - intelligent temperature-control OT - latent heat performance OT - microcapsule OT - modified n-alkane OT - nano-silica COIS- The authors declare no conflict of interest. EDAT- 2021/09/29 06:00 MHDA- 2021/09/29 06:01 PMCR- 2021/09/12 CRDT- 2021/09/28 01:27 PHST- 2021/08/19 00:00 [received] PHST- 2021/09/07 00:00 [revised] PHST- 2021/09/10 00:00 [accepted] PHST- 2021/09/28 01:27 [entrez] PHST- 2021/09/29 06:00 [pubmed] PHST- 2021/09/29 06:01 [medline] PHST- 2021/09/12 00:00 [pmc-release] AID - nano11092370 [pii] AID - nanomaterials-11-02370 [pii] AID - 10.3390/nano11092370 [doi] PST - epublish SO - Nanomaterials (Basel). 2021 Sep 12;11(9):2370. doi: 10.3390/nano11092370.