PMID- 34596928
OWN - NLM
STAT- MEDLINE
DCOM- 20211206
LR  - 20211214
IS  - 1521-3765 (Electronic)
IS  - 0947-6539 (Linking)
VI  - 27
IP  - 67
DP  - 2021 Dec 1
TI  - The Preparation of a Water-Soluble Phospholate-Based Macrocycle for Constructing 
      Artificial Light-Harvesting Systems.
PG  - 16601-16605
LID - 10.1002/chem.202102758 [doi]
AB  - On the basis of cyclotrixylohydroquinoylene (CTX), a novel water-soluble 
      phospholate-based CTX derivative (WPCTX) was prepared with facile synthetic 
      procedure and satisfying yield. Several model guest molecules were selected to 
      investigate WPCTX's host-guest properties. Based on the study of the host and 
      model guest complexation, a tetraphenylethylene derivative from model guest was 
      employed as a guest molecule (G) to form WPCTX supersetG nanoparticles (NPs) with WPCTX 
      through further supramolecular self-assembly in water. Moreover, a hydrophobic 
      fluorescent dye, Eosin Y(ESY) or Nile red (NiR), was encapsulated in WPCTX supersetG NPs 
      to construct two types of artificial light-harvesting systems. Their high antenna 
      effect demonstrated such NPs successfully mimicked light-harvesting systems in 
      nature.
CI  - (c) 2021 Wiley-VCH GmbH.
FAU - Jiao, Jianmin
AU  - Jiao J
AD  - Key Laboratory of Mesoscopic Chemistry of MOE, Jiangsu Key Laboratory of Advanced 
      Organic Materials, School of Chemistry and Chemical Engineering, Nanjing 
      University, Nanjing, 210023, P. R. China.
FAU - Sun, Guangping
AU  - Sun G
AD  - Key Laboratory of Mesoscopic Chemistry of MOE, Jiangsu Key Laboratory of Advanced 
      Organic Materials, School of Chemistry and Chemical Engineering, Nanjing 
      University, Nanjing, 210023, P. R. China.
FAU - Zhang, Jikun
AU  - Zhang J
AD  - Key Laboratory of Mesoscopic Chemistry of MOE, Jiangsu Key Laboratory of Advanced 
      Organic Materials, School of Chemistry and Chemical Engineering, Nanjing 
      University, Nanjing, 210023, P. R. China.
FAU - Lin, Chen
AU  - Lin C
AUID- ORCID: 0000-0002-4160-8077
AD  - Key Laboratory of Mesoscopic Chemistry of MOE, Jiangsu Key Laboratory of Advanced 
      Organic Materials, School of Chemistry and Chemical Engineering, Nanjing 
      University, Nanjing, 210023, P. R. China.
FAU - Jiang, Juli
AU  - Jiang J
AUID- ORCID: 0000-0001-5778-6380
AD  - Key Laboratory of Mesoscopic Chemistry of MOE, Jiangsu Key Laboratory of Advanced 
      Organic Materials, School of Chemistry and Chemical Engineering, Nanjing 
      University, Nanjing, 210023, P. R. China.
FAU - Wang, Leyong
AU  - Wang L
AUID- ORCID: 0000-0001-5775-3714
AD  - Key Laboratory of Mesoscopic Chemistry of MOE, Jiangsu Key Laboratory of Advanced 
      Organic Materials, School of Chemistry and Chemical Engineering, Nanjing 
      University, Nanjing, 210023, P. R. China.
LA  - eng
GR  - 22071104/national natural science foundation of china/
GR  - 21871135/national natural science foundation of china/
GR  - 21871136/national natural science foundation of china/
PT  - Journal Article
DEP - 20211015
PL  - Germany
TA  - Chemistry
JT  - Chemistry (Weinheim an der Bergstrasse, Germany)
JID - 9513783
RN  - 0 (Fluorescent Dyes)
RN  - 059QF0KO0R (Water)
SB  - IM
MH  - *Fluorescent Dyes
MH  - Hydrophobic and Hydrophilic Interactions
MH  - *Nanoparticles
MH  - Water
OTO - NOTNLM
OT  - CTX
OT  - FRET
OT  - artificial lighting harvesting
OT  - host-guest systems
OT  - supramolecular self-assembly
EDAT- 2021/10/02 06:00
MHDA- 2021/12/15 06:00
CRDT- 2021/10/01 12:36
PHST- 2021/07/29 00:00 [received]
PHST- 2021/10/02 06:00 [pubmed]
PHST- 2021/12/15 06:00 [medline]
PHST- 2021/10/01 12:36 [entrez]
AID - 10.1002/chem.202102758 [doi]
PST - ppublish
SO  - Chemistry. 2021 Dec 1;27(67):16601-16605. doi: 10.1002/chem.202102758. Epub 2021 
      Oct 15.