PMID- 34641029 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20211016 IS - 2073-4360 (Electronic) IS - 2073-4360 (Linking) VI - 13 IP - 19 DP - 2021 Sep 22 TI - Influence of Tire Rubber Particles Addition in Different Branching Degrees Polyethylene Matrix Composites on Physical and Structural Behavior. LID - 10.3390/polym13193213 [doi] LID - 3213 AB - Waste from pneumatic wheels is one of the major environmental problems, and the scientific community is looking for methods to recycle this type of waste. In this paper, ground tire rubber particles (GTR) from disused tires have been mixed with samples of low-density polyethylene (LDPE) and high-density polyethylene (HDPE), and morphological tests have been performed using scanning electron microscopy (SEM), as well as the dynamic electric analysis (DEA) dielectric characterization technique using impedance spectroscopy. From this experience, how GTR reinforcement influences polyethylene and what influence GTR particles have on the branched polyethylene has been detected. For pure LDPE samples, a Debye-type dielectric behavior is observed with an imperfect semicircle, which depends on the temperature, as it shows differences for the samples at 30 degrees C and 120 degrees C, unlike the HDPE samples, which do not show such a trend. The behavior in samples with Debye behavior is like an almost perfect dipole and is due to the crystalline behavior of polyethylene at high temperature and without any reinforcement. These have been obtained evidence that for branched PE (LPDE) the Maxwell Wagner Sillars (MWS) effect is highly remarkable and that this happens due to the intrachain polarization effect combined with MWS. This means that the permittivity and conductivity at LDPE/50%GTR are high than LDPE/70%GTR. However, it does not always occur that way with HDPE composites in which HDPE/70%GTR has the highest values of permittivity and conductivity, due to the presence of conductive fraction (Carbon Black-30%) in the GTR particles and their dielectric behavior. FAU - Marin-Genesca, Marc AU - Marin-Genesca M AUID- ORCID: 0000-0002-7204-4526 AD - Mechanical Engineering Department, Escola Tecnica Superior d'Enginyeria Quimica, Universitat Rovira i Virgili (ETSEQ-URV), 43007 Tarragona, Spain. FAU - Mujal Rosas, Ramon AU - Mujal Rosas R AD - Electrical Engineering Department, Escola d'Enginyeria de Terrassa, Universitat Politecnica de Catalunya (EET-UPC), 08222 Terrassa, Spain. FAU - Garcia Amoros, Jordi AU - Garcia Amoros J AUID- ORCID: 0000-0002-6548-5059 AD - Electrical Engineering Department, Escola Tecnica Superior d'Enginyeria Quimica, Universitat Rovira i Virgili (ETSE-URV), 43007 Tarragona, Spain. FAU - Massagues Vidal, Lluis AU - Massagues Vidal L AD - Electrical Engineering Department, Escola Tecnica Superior d'Enginyeria Quimica, Universitat Rovira i Virgili (ETSE-URV), 43007 Tarragona, Spain. FAU - Colom Fajula, Xavier AU - Colom Fajula X AUID- ORCID: 0000-0003-3511-852X AD - Chemical Engineering Department, Escola d'Enginyeria de Terrassa, Universitat Politecnica de Catalunya (EET-UPC), 08222 Terrassa, Spain. LA - eng PT - Journal Article DEP - 20210922 PL - Switzerland TA - Polymers (Basel) JT - Polymers JID - 101545357 PMC - PMC8512641 OTO - NOTNLM OT - composites OT - electrical modulus OT - electrical properties OT - ground tire rubber OT - polyethylene OT - recycling OT - structural features COIS- The authors declare no conflict of interest. EDAT- 2021/10/14 06:00 MHDA- 2021/10/14 06:01 PMCR- 2021/09/22 CRDT- 2021/10/13 01:12 PHST- 2021/08/26 00:00 [received] PHST- 2021/09/16 00:00 [revised] PHST- 2021/09/20 00:00 [accepted] PHST- 2021/10/13 01:12 [entrez] PHST- 2021/10/14 06:00 [pubmed] PHST- 2021/10/14 06:01 [medline] PHST- 2021/09/22 00:00 [pmc-release] AID - polym13193213 [pii] AID - polymers-13-03213 [pii] AID - 10.3390/polym13193213 [doi] PST - epublish SO - Polymers (Basel). 2021 Sep 22;13(19):3213. doi: 10.3390/polym13193213.