PMID- 34641161 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20211016 IS - 2073-4360 (Electronic) IS - 2073-4360 (Linking) VI - 13 IP - 19 DP - 2021 Sep 29 TI - Effect of Processing Techniques on the Microstructure and Mechanical Performance of High-Density Polyethylene. LID - 10.3390/polym13193346 [doi] LID - 3346 AB - The versatility of high-density polyethylene (HDPE) makes it one of the most used polymers for vast applications ranging from food packaging to human implants. However, there still is confusion regarding the proper selection of processing techniques to produce HDPE specimens for high-end applications. Herein, we compare the processing of HDPE by two relevant techniques: compression and injection molding. The fabricated samples were studied using uniaxial tensile testing to determine their mechanical performance. Furthermore, the microstructure of samples was analyzed using different characterization techniques. Compression-molded specimens recorded a higher degree of crystallinity (DC) using two different characterization techniques such as differential scanning calorimetry (DSC) and X-ray diffraction (XRD). With this information, critical processing factors were determined, and a general structure-property relationship was established. It was demonstrated that having a higher DC resulted in higher yield strength and Young's modulus. Furthermore, premature failure was observed in the injection-molded specimens, resulting in lower mechanical performance. This premature failure was caused due to flow marks observed using scanning electron microscopy (SEM). Therefore, it is concluded that compression molding produces superior samples compared to injection molding. FAU - Mejia, Edgar AU - Mejia E AD - Mechanical Engineering Department, College of Engineering, United Arab Emirate University, Al Ain 15551, United Arab Emirates. FAU - Cherupurakal, Nizamudeen AU - Cherupurakal N AUID- ORCID: 0000-0002-8819-4027 AD - Mechanical Engineering Department, College of Engineering, United Arab Emirate University, Al Ain 15551, United Arab Emirates. FAU - Mourad, Abdel-Hamid I AU - Mourad AI AUID- ORCID: 0000-0002-8356-0542 AD - Mechanical Engineering Department, College of Engineering, United Arab Emirate University, Al Ain 15551, United Arab Emirates. AD - National Eater and Energy Center, United Arab Emirate University, Al Ain 15551, United Arab Emirates. AD - Mechanical Design Department, Faculty of Engineering, Helwan University, Cairo 11795, Egypt. FAU - Al Hassanieh, Sultan AU - Al Hassanieh S AUID- ORCID: 0000-0001-7276-7460 AD - Mechanical Engineering Department, College of Engineering, United Arab Emirate University, Al Ain 15551, United Arab Emirates. FAU - Rabia, Mohamed AU - Rabia M AD - Polymer Research Laboratory, Chemistry Department, Faculty of Science, Beni-Suef University, Beni-Suef 62514, Egypt. LA - eng GR - 31N392/United Arab Emirates University/ PT - Journal Article DEP - 20210929 PL - Switzerland TA - Polymers (Basel) JT - Polymers JID - 101545357 PMC - PMC8512384 OTO - NOTNLM OT - compression molding OT - high-density polyethylene OT - injection molding OT - mechanical properties OT - microstructure COIS- The authors declare no conflict of interest. EDAT- 2021/10/14 06:00 MHDA- 2021/10/14 06:01 PMCR- 2021/09/29 CRDT- 2021/10/13 01:13 PHST- 2021/09/05 00:00 [received] PHST- 2021/09/23 00:00 [revised] PHST- 2021/09/27 00:00 [accepted] PHST- 2021/10/13 01:13 [entrez] PHST- 2021/10/14 06:00 [pubmed] PHST- 2021/10/14 06:01 [medline] PHST- 2021/09/29 00:00 [pmc-release] AID - polym13193346 [pii] AID - polymers-13-03346 [pii] AID - 10.3390/polym13193346 [doi] PST - epublish SO - Polymers (Basel). 2021 Sep 29;13(19):3346. doi: 10.3390/polym13193346.