PMID- 34693147 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20211026 IS - 2470-1343 (Electronic) IS - 2470-1343 (Linking) VI - 6 IP - 41 DP - 2021 Oct 19 TI - Recyclable Ag-Deposited TiO(2) SERS Substrate for Ultrasensitive Malachite Green Detection. PG - 27271-27278 LID - 10.1021/acsomega.1c04082 [doi] AB - An ultrasensitive Ag-deposited TiO(2) flower-like nanomaterial (FLNM) surface-enhanced Raman scattering (SERS)-active substrate is synthesized via a hydrothermal method, and Ag nanoparticles (NPs) are deposited through electron beam evaporation. Malachite green (MG), which is widely used in aquaculture, is employed to assess the surface-enhanced Raman scattering (SERS) properties of TiO(2)/Ag FLNMs. They exhibit ultrasensitivity (limit of detection (LOD) of MG reaches 4.47 x 10(-16) M) and high reproducibility (relative standard deviations (RSDs) are less than 13%); more importantly, the TiO(2)/Ag FLNMs are recyclable, as enabled by their self-cleaning function due to TiO(2) photocatalytic degradation. Their recyclability is achieved after three cycles and their potential application is examined in the actual system. Finite difference time domain (FDTD) simulations and the charge-transfer (CT) mechanism further prove that the excellent SERS properties originate from localized surface plasmon resonance (LSPR) of Ag NPs and the coupling field between Ag and TiO(2) FLNMs. Therefore, TiO(2)/Ag FLNMs show promising application in aquaculture. CI - (c) 2021 The Authors. Published by American Chemical Society. FAU - Yang, Weiye AU - Yang W AUID- ORCID: 0000-0001-5685-5727 AD - Yunnan Key Laboratory of Opto-Electronic Information Technology, Yunnan Normal University, Kunming 650500, China. AD - Institute of Physics and Electronic Information, Yunnan Normal University, Kunming 650500, China. AD - Key Laboratory of Advanced Technique & Preparation for Renewable Energy Materials, Ministry of Education, Yunnan Normal University, Kunming 650500, China. FAU - Tang, Junqi AU - Tang J AD - Yunnan Key Laboratory of Opto-Electronic Information Technology, Yunnan Normal University, Kunming 650500, China. AD - Institute of Physics and Electronic Information, Yunnan Normal University, Kunming 650500, China. AD - Key Laboratory of Advanced Technique & Preparation for Renewable Energy Materials, Ministry of Education, Yunnan Normal University, Kunming 650500, China. FAU - Ou, Quanhong AU - Ou Q AD - Yunnan Key Laboratory of Opto-Electronic Information Technology, Yunnan Normal University, Kunming 650500, China. AD - Institute of Physics and Electronic Information, Yunnan Normal University, Kunming 650500, China. AD - Key Laboratory of Advanced Technique & Preparation for Renewable Energy Materials, Ministry of Education, Yunnan Normal University, Kunming 650500, China. FAU - Yan, Xueqian AU - Yan X AD - Yunnan Key Laboratory of Opto-Electronic Information Technology, Yunnan Normal University, Kunming 650500, China. AD - Institute of Physics and Electronic Information, Yunnan Normal University, Kunming 650500, China. AD - Key Laboratory of Advanced Technique & Preparation for Renewable Energy Materials, Ministry of Education, Yunnan Normal University, Kunming 650500, China. FAU - Liu, Lei AU - Liu L AD - Yunnan Key Laboratory of Opto-Electronic Information Technology, Yunnan Normal University, Kunming 650500, China. AD - Institute of Physics and Electronic Information, Yunnan Normal University, Kunming 650500, China. AD - Key Laboratory of Advanced Technique & Preparation for Renewable Energy Materials, Ministry of Education, Yunnan Normal University, Kunming 650500, China. FAU - Liu, Yingkai AU - Liu Y AD - Yunnan Key Laboratory of Opto-Electronic Information Technology, Yunnan Normal University, Kunming 650500, China. AD - Institute of Physics and Electronic Information, Yunnan Normal University, Kunming 650500, China. AD - Key Laboratory of Advanced Technique & Preparation for Renewable Energy Materials, Ministry of Education, Yunnan Normal University, Kunming 650500, China. LA - eng PT - Journal Article DEP - 20211011 PL - United States TA - ACS Omega JT - ACS omega JID - 101691658 PMC - PMC8529650 COIS- The authors declare no competing financial interest. EDAT- 2021/10/26 06:00 MHDA- 2021/10/26 06:01 PMCR- 2021/10/11 CRDT- 2021/10/25 06:44 PHST- 2021/07/31 00:00 [received] PHST- 2021/09/30 00:00 [accepted] PHST- 2021/10/25 06:44 [entrez] PHST- 2021/10/26 06:00 [pubmed] PHST- 2021/10/26 06:01 [medline] PHST- 2021/10/11 00:00 [pmc-release] AID - 10.1021/acsomega.1c04082 [doi] PST - epublish SO - ACS Omega. 2021 Oct 11;6(41):27271-27278. doi: 10.1021/acsomega.1c04082. eCollection 2021 Oct 19.