PMID- 34746581 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20211110 IS - 2470-1343 (Electronic) IS - 2470-1343 (Linking) VI - 6 IP - 43 DP - 2021 Nov 2 TI - Investigation of Biochar Production from Copyrolysis of Rice Husk and Plastic. PG - 28890-28902 LID - 10.1021/acsomega.1c03874 [doi] AB - Biomass renewable energy has become a major target of the Thailand Alternative Energy Development Plan (AEDP) since the country's economy is largely based on agricultural production. Rice husk (RH) is one of the most common agricultural residues in Thailand. This research aims to investigate yields and properties of biochar produced from copyrolysis of RH and plastic (high-density polyethylene (HDPE)) at different ratios, temperatures, and holding times. For both individual and copyrolysis, the temperature variation generated more pronounced effects than the holding time variation on both biochar yields and properties. For individual pyrolysis of RH, the maximum biochar yield of approximately 54 wt % was obtained at 400 degrees C. A shift in temperature from 400 to 600 degrees C resulted in RH biochars with higher fixed carbon (FC) and carbon (C) contents by approximately 1.11-1.28 and 1.06-1.22 times, respectively, while undetectable changes in higher heating values (HHVs) were noticed. For copyrolysis, obvious negative synergistic effects were observed due to the radical interaction between the rich H content of HDPE and RH biochars, which resulted in lower biochar yields as compared to the theoretical estimation based on individual pyrolysis values. However, the addition of HDPE positively impacted the FC and C contents, especially when 10 and 20 wt % HDPE were added to the feedstock. Besides, higher HDPE blending ratios resulted in biochars with improved HHVs, and >1.5 times improvement in HHV was reported in the biochar with 50 wt % HDPE addition in comparison with RH biochar obtained under the same conditions. In summary, biochars generated in this study have the potential to be utilized as a solid fuel or soil amendment. CI - (c) 2021 The Authors. Published by American Chemical Society. FAU - Wantaneeyakul, Nichakorn AU - Wantaneeyakul N AUID- ORCID: 0000-0001-7414-6991 AD - Department of Environmental Engineering, King Mongkut's University of Technology Thonburi (KMUTT), 126 Pracha Uthit Road, Bang Mot, Thung Khru, Bangkok 10140, Thailand. FAU - Kositkanawuth, Ketwalee AU - Kositkanawuth K AD - Department of Environmental Engineering, King Mongkut's University of Technology Thonburi (KMUTT), 126 Pracha Uthit Road, Bang Mot, Thung Khru, Bangkok 10140, Thailand. FAU - Turn, Scott Q AU - Turn SQ AD - Hawaii Natural Energy Institute, University of Hawaii at Manoa, Honolulu, Hawaii 96822, United States. FAU - Fu, Jinxia AU - Fu J AUID- ORCID: 0000-0001-9881-3699 AD - Hawaii Natural Energy Institute, University of Hawaii at Manoa, Honolulu, Hawaii 96822, United States. LA - eng PT - Journal Article DEP - 20211020 PL - United States TA - ACS Omega JT - ACS omega JID - 101691658 PMC - PMC8567375 COIS- The authors declare no competing financial interest. EDAT- 2021/11/09 06:00 MHDA- 2021/11/09 06:01 PMCR- 2021/10/20 CRDT- 2021/11/08 06:54 PHST- 2021/07/21 00:00 [received] PHST- 2021/10/07 00:00 [accepted] PHST- 2021/11/08 06:54 [entrez] PHST- 2021/11/09 06:00 [pubmed] PHST- 2021/11/09 06:01 [medline] PHST- 2021/10/20 00:00 [pmc-release] AID - 10.1021/acsomega.1c03874 [doi] PST - epublish SO - ACS Omega. 2021 Oct 20;6(43):28890-28902. doi: 10.1021/acsomega.1c03874. eCollection 2021 Nov 2.