PMID- 34771247 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20211118 IS - 2073-4360 (Electronic) IS - 2073-4360 (Linking) VI - 13 IP - 21 DP - 2021 Oct 26 TI - Effect of Eco-Friendly Peanut Shell Powder on the Chemical Resistance, Physical, Thermal, and Thermomechanical Properties of Unsaturated Polyester Resin Composites. LID - 10.3390/polym13213690 [doi] LID - 3690 AB - The paper investigates the synthesis of eco-friendly composites and their properties before and after immersion in solvents of different chemical natures. For their preparation, unsaturated polyester resin (UPR) based on recycled poly (ethylene terephthalate) (PET) and peanut shell powder (PSP) were used. Polymerization was carried out in the presence of environmentally friendly polymeric cobalt. Distilled water, acetone, 10% hydrochloric acid, 40% sodium hydroxide, toluene, and 2% sodium carbonate were used as solvents in the chemical resistance test. Changes in the structure, properties, and appearance (morphology) of composites after 140 days of immersion in solvents were investigated. The results show that both the resin and its composites show resistance towards 10% HCl and toluene. The immersion in water has no significant effect on the resin, but for PSP composites, the plasticizing effect of water was observed. In acetone, after only one day, the resin and its composite with 10% PSP shrink and fall into pieces. However, the most destructive is an alkaline environment. After the immersion test, a huge increase in mass and a deterioration of gloss and thermomechanical properties were observed. The destructive influence of the 40% NaOH environment mainly concerned the resin. FAU - Paczkowski, Przemyslaw AU - Paczkowski P AUID- ORCID: 0000-0002-1704-1648 AD - Department of Polymer Chemistry, Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Sklodowska University in Lublin, Gliniana 33, 20-614 Lublin, Poland. FAU - Puszka, Andrzej AU - Puszka A AUID- ORCID: 0000-0002-3604-7703 AD - Department of Polymer Chemistry, Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Sklodowska University in Lublin, Gliniana 33, 20-614 Lublin, Poland. FAU - Gawdzik, Barbara AU - Gawdzik B AUID- ORCID: 0000-0003-4856-0309 AD - Department of Polymer Chemistry, Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Sklodowska University in Lublin, Gliniana 33, 20-614 Lublin, Poland. LA - eng PT - Journal Article DEP - 20211026 PL - Switzerland TA - Polymers (Basel) JT - Polymers JID - 101545357 PMC - PMC8588497 OTO - NOTNLM OT - biofiller OT - chemical resistance OT - composites OT - eco-friendly OT - immersion test OT - lignocellulosic biomass OT - peanut shell OT - unsaturated polyester resin COIS- The authors declare no conflict of interest. EDAT- 2021/11/14 06:00 MHDA- 2021/11/14 06:01 PMCR- 2021/10/26 CRDT- 2021/11/13 01:13 PHST- 2021/09/30 00:00 [received] PHST- 2021/10/14 00:00 [revised] PHST- 2021/10/25 00:00 [accepted] PHST- 2021/11/13 01:13 [entrez] PHST- 2021/11/14 06:00 [pubmed] PHST- 2021/11/14 06:01 [medline] PHST- 2021/10/26 00:00 [pmc-release] AID - polym13213690 [pii] AID - polymers-13-03690 [pii] AID - 10.3390/polym13213690 [doi] PST - epublish SO - Polymers (Basel). 2021 Oct 26;13(21):3690. doi: 10.3390/polym13213690.